925461-73-0

Basic information

• Product Name: carbonic acid allyl ester (Z)-2-(tert-butyl-dimethyl-silanoxy)-1-phenyl-vinyl ester
• Synonyms: carbonic acid allyl ester (Z)-2-(tert-butyl-dimethyl-silanoxy)-1-phenyl-vinyl ester
• CAS NO: 925461-73-0
• Molecular Weight: 334.488
• Mol File: 925461-73-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: carbonic acid allyl ester (Z)-2-(tert-butyl-dimethyl-silanoxy)-1-phenyl-vinyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: carbonic acid allyl ester (Z)-2-(tert-butyl-dimethyl-silanoxy)-1-phenyl-vinyl ester(925461-73-0)
• EPA Substance Registry System: carbonic acid allyl ester (Z)-2-(tert-butyl-dimethyl-silanoxy)-1-phenyl-vinyl ester(925461-73-0)

Safety Data

• Hazardous Substances Data: 925461-73-0(Hazardous Substances Data)

Upstream product

• 103548-04-5 2-(tert-butyldimethylsilanyloxy)-1-phenylethan-1-one 
• 2937-50-0 Allyl chloroformate 
• 925462-31-3 carbonic acid allyl ester 2-oxo-2-phenyl-ethyl ester 
• 120820-40-8 1-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)phenyl)ethanone 

Downstream Products

• 925461-82-1 (S)-(-)-2-(tert-butyldimethylsilyloxy)-2-phenylpent-4-enal 
• 1051945-72-2 2-(tert-butyl-dimethyl-silanyloxy)-1-phenyl-pent-4-en-1-one 
• 1051946-19-0 2-(tert-butyl-dimethyl-silanyloxy)-1-phenyl-pent-4-en-1-one 

Relevant articles and documents

Ligand controlled highly regio- and enantioselective synthesis of α-acyloxyketones by palladium-catalyzed allylic alkylation of 1,2-enediol carbonates

The palladium catalyzed decarboxylative asymmetric allylic alkylation of allyl 1,2-enediol carbonates 1 can decompose to either α-hydroxyketones 3 or α-hydroxyaldehydes 4. The product distribution is largely controlled by the ligand. Using Lnaph/sub