105198-22-9Relevant academic research and scientific papers
TETRAKIS-SULFOXIDES AS PHASE TRANSFER CATALYSTS
Fujihara, Hisashi,Imaoka, Koji,Furukawa, Naomichi,Oae, Shigeru
, p. 1293 - 1296 (1981)
Tetrakis(alkyl-sulfinylmethyl)methanes serve as highly efficient phase transfer catalysts in SN2 type displacement reactions of n-octyl bromide with a few nucleophiles.
Tetrakis-sulphoxides: a New Type of Phase-transfer Catalyst for Nocleophilic Displacements and Alkylations
Fujihara, Hisashi,Imaoka, Koji,Furukawa, Naomichi,Oae, Shigeru
, p. 333 - 336 (2007/10/02)
Tetrakis(alkylsulphinylmethyl)methanes have been shown to serve as good phase-transfer catalysts which accelerate SN2 type displacements of octyl bromide with various nucleophiles (thiocyanate, cyanide, phenoxide, and thiolate) in solid-liquid two-phase systems.Alkylation of phenylacetonitrile with alkyl halides has also been carried out in liquid-liquid two-phase systems in the presence of the above sulphoxides to afford the corresponding mono-alkylated products in high yields.
