1052174-83-0Relevant academic research and scientific papers
Synthesis of (benzenesulfonyl)difluoromethyl thioethers from ((difluoromethyl)sulfonyl)benzene and organothiocyanates generatedin situ
Dai, Jianjun,Shen, Xiao,Wu, Cheng,Xu, Huajian,Xu, Jun
supporting information, p. 7607 - 7610 (2021/09/22)
Easily available aryl and alkyl thiocyanates were converted into the corresponding (benzenesulfonyl)difluoromethyl thioethersviathe direct nucleophilic substitution of ((difluoromethyl)-sulfonyl)benzene under transition metal free conditions. Combined wit
Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)-CF2SO2Ph reagent
Zhang, Wei,Zhu, Jieming,Hu, Jinbo
, p. 5006 - 5008 (2008/12/21)
A hypervalent iodine(III)-CF2SO2Ph compound (3) has been successfully prepared with selective nucleophilic reaction using PhSO2CF2SiMe3 reagent, and this previously unkown compound 3 was found to act as a new electrophilic (phenylsulfonyl)difluoromethylation reagent for a variety of S-nucleophiles under very mild reaction conditions.
