1052183-73-9Relevant articles and documents
Highly Enantioselective Michael Addition of Nitroalkanes to Enones and Its Application in Syntheses of (R)-Baclofen and (R)-Phenibut
Guo, Xing-Tao,Shen, Jie,Sha, Feng,Wu, Xin-Yan
, p. 2063 - 2072 (2015)
A highly enantioselective Michael addition of nitroalkanes to α,β-unsaturated ketones was developed. In the presence of a chiral primary amine-thiourea catalyst based on dehydroabietic amine, γ-nitro ketones were obtained with excellent enantioselectiviti
Asymmetric Conjugate Addition of Nitroalkanes to Enones Using a Sulfonamide-Thiourea Organocatalyst
Kawada, Masahiro,Nakashima, Kosuke,Hirashima, Shin-Ichi,Yoshida, Akihiro,Koseki, Yuji,Miura, Tsuyoshi
, p. 6986 - 6991 (2017)
The asymmetric conjugate addition of nitroalkanes to α,β-unsaturated ketones in the presence of a catalytic amount of a novel sulfonamide-thiourea organocatalyst resulted in the corresponding γ-nitro carbonyl products in high yields with excellent enantio
C3-symmetric proline-functionalized organocatalysts: Enantioselective michael addition reactions
Moorthy, Jarugu Narasimha,Saha, Satyajit
experimental part, p. 6359 - 6365 (2011/03/17)
C3-Symmetric, tripodal catalyst 4 based on 1,3,5- triethylbenzene, which incorporates the features of a molecular receptor, is shown to catalyze Michael addition reactions ofcarbonyl compounds to β-nitrostyrenes in a high stereoselectivity (up to 99:1a dr and up to 98%ee). Copyright