105230-63-5

Basic information

• Product Name: Benzene, 1-iodo-4-(phenylseleno)-
• CAS NO: 105230-63-5
• Molecular Formula: C12H9ISe
• Molecular Weight: 359.068
• Mol File: 105230-63-5.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1-iodo-4-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-iodo-4-(phenylseleno)-(105230-63-5)
• EPA Substance Registry System: Benzene, 1-iodo-4-(phenylseleno)-(105230-63-5)

Safety Data

• Hazardous Substances Data: 105230-63-5(Hazardous Substances Data)

Upstream product

• 52251-58-8 lithium phenylselenide 
• 105230-51-1 C₁₃H₁₁IN₂O₂S 
• 41924-21-4 phenyl tributylstannyl selenide 
• 645-96-5 Benzeneselenol 
• 1666-13-3 diphenyl diselenide 
• 540-37-4 p-aminoiodobenzene 

Downstream Products

• 71672-72-5 1,4-bis(phenylselenyl)benzene 

Relevant articles and documents

Syntheses of Thioethers and Selenide Ethers from Anilines

In this study, a general procedure was proposed for synthesizing thioethers and selenide ethers from anilines under solvent-free and transition-metal-free conditions. Thioethers were formed when anilines reacted with thiols under blue light-emitting-diode (LED) irradiation at room temperature without a photocatalyst. When reactions were performed using anilines and diselenides, the corresponding selenide ethers were obtained with satisfactory to excellent yields. The reaction was performed under photocatalyst-free and solvent-free conditions without blue LEDs. The advantages of this system include convenient operations, mild reaction conditions, satisfactory functional group tolerance, and late-stage selenylation of drug molecules.

Electrochemical Thiolation and Borylation of Arylazo Sulfones with Thiols and B2pin2

An efficient electrochemical synthesis approach of various unsymmetrical thioethers and arylboronates has been developed. Bench stable arylazo sulfones were used as radical precursors for carbon-heteroatom bond formation under electrochemical conditions. Moreover, the scalability of this approach was evaluated by performing the electrochemical thiolation and borylation of arylazo sulfones with thiols and B2pin2 on a gram scale. This protocol not only avoided the use of stoichiometric oxidants, metal catalysts, activating agents and even added bases, but also exhibited favorable functional group tolerance. (Figure presented.).

Tributyltin aryl selenides as efficient arylselenating agents. Synthesis of diaryl and aryl organyl selenides

Tributyltin aryl selenides are highly efficient arylselenating agents in reactions with aryl iodides and aryl triflates under catalysis with Pd and Ni complexes respectively. They also may be used as efficient source of active arylselenolate anion in the

New approaches to the synthesis of unsymmetrical diaryl selenides

Unsymmetrical diaryl selenides PhSeAr were obtained by the palladium catalysed reactions of aryl (heteroaryl) iodide or triflate with Bu3SnSePh in high yields. The same compounds can be obtained by the non-catalytic reactions of Bu3SnSePh with ArN2BF4 or (ArN2)2ZnCl4.

Aryl Arylazo Sulfones Chemistry. 2. Reactivity toward Alkaline Alkane- and Areneselenolate and Alkane- and Arenetellurolate Anions

Tolyl arylazo sulfones react with various alkyl- and arylseleno reagents to produce substituted alkyl aryl and unsymmetrical diaryl selenides.The corresponding tellurides can also be obtained.Isolated yields in both cases are good.This procedure is an interesting alternative to the classical Sandmeyer reaction.