105379-81-5Relevant articles and documents
REACTION OF α-GEM-TRICHLOROCARBONYL COMPOUNDS WITH CONJUGATED ALKADIENES
Startsev, V. V.,Zubritskii, L. M.,Gorbunkov, V. D.,Petrov, A. A.
, p. 2094 - 2097 (2007/10/02)
Chloral and gem-trichloroacetone add to 1,3-alkadienes in the presence of copper(I) chloride with the formation of the corresponding γ,δ-unsaturated α,α,ε-trichlorocarbonyl compounds as mixtures of the E and Z isomers in a ratio in the order of 85:15.The reaction takes place under mild conditions and gives a high yield of the final products.