1054598-83-2Relevant academic research and scientific papers
Highly diastereoselective sulfonium ylide rearrangements to quaternary substituted indolines
Boyarskikh, Vyacheslav,Nyong, Abijah,Rainier, Jon D.
supporting information; experimental part, p. 5374 - 5377 (2009/03/12)
(Chemical Equation Presented) Quat. centers: Sulfonium ylide intermediates generated from halogenated vinyl diazoacetates and 2-thioindoles in the presence of a RhII complex undergo highly diastereoselective [3,3] rearrangements to indolines having an asymmetric quaternary carbon center with an adjacent halogenated stereocenter (see scheme).
