1054666-78-2

Basic information

• Product Name: (3S,4S,5R)-1,3,4,5-tetrakis(benzyloxy)-7-(dimethyl(phenyl)silyl)heptane-2,6-dione
• Synonyms: (3S,4S,5R)-1,3,4,5-tetrakis(benzyloxy)-7-(dimethyl(phenyl)silyl)heptane-2,6-dione
• CAS NO: 1054666-78-2
• Molecular Weight: 686.92
• Mol File: 1054666-78-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4S,5R)-1,3,4,5-tetrakis(benzyloxy)-7-(dimethyl(phenyl)silyl)heptane-2,6-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S,5R)-1,3,4,5-tetrakis(benzyloxy)-7-(dimethyl(phenyl)silyl)heptane-2,6-dione(1054666-78-2)
• EPA Substance Registry System: (3S,4S,5R)-1,3,4,5-tetrakis(benzyloxy)-7-(dimethyl(phenyl)silyl)heptane-2,6-dione(1054666-78-2)

Safety Data

• Hazardous Substances Data: 1054666-78-2(Hazardous Substances Data)

Upstream product

• 1833-51-8 chloromethyldimethylphenylsilane 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 

Downstream Products

• 110391-10-1 (4R,5S,6R)-4,5,6-tris(benzyloxy)-3-((benzyloxy)methyl)-2-cyclohexen-1-one 
• 140658-59-9 (4S,5R)-2,4-Bis(benzyloxy)-5-hydroxy-5-<(benzyloxy)methyl>-2-cyclohexenone 
• 115250-38-9 (1S)-(1(OH),2,4/1,3)-2,3,4-Tri-O-benzyl-1-C-<(benzyloxy)methyl>-5-oxo-1,2,3,4-cyclohexanetetrol 

Relevant articles and documents

1-Silyl-2,6-diketones: Versatile intermediates for the divergent synthesis of five- and six-membered carbocycles under radical and anionic conditions

1-Silyl-2,6-diketones, readily prepared by addition of (silylmethyl)metal reagents to 1,5-lactols followed by oxidation of the resultant diols, can be efficiently transformed into 3-hydroxycyclohexanones, cyclohex-2-enones, or 1-(silylmethyl)cyclopentane-1,2-diols under nucleophilic, basic, or single electron-transfer reduction conditions, respectively. The latter cyclitols can be further transformed into 2-methylenecyclopentanols or 1-(hydroxymethyl) cyclopentane-1,2-diols by Peterson elimination or Tamao-Fleming oxidation, respectively.