105486-20-2Relevant academic research and scientific papers
ASYMMETRIC SYNTHESIS OF CHIRAL SYNTHONS BEARING ALKYNYL GROUP VIA ORGANOALUMINUM-PROMOTED PINACOL-TYPE REARRANGEMENT
Suzuki, Keisuke,Ohkuma, Takeshi,Miyazawa, Mayumi,Tsuchihashi, Gen-ichi
, p. 373 - 376 (1986)
A method is described for the synthesis of chiral alkynyl ketones and alkynols via trimethylaluminum-promoted pinacol-type rearrangement where alkynyl groups behave as "the staying group", followed by stereoselective reduction leading to the latter.
