Tetrahedron Letters p. 373 - 376 (1986)
Update date:2022-07-29
Topics: Workup and Isolation Analysis and Characterization Further Transformations
Suzuki, Keisuke
Ohkuma, Takeshi
Miyazawa, Mayumi
Tsuchihashi, Gen-ichi
A method is described for the synthesis of chiral alkynyl ketones and alkynols via trimethylaluminum-promoted pinacol-type rearrangement where alkynyl groups behave as "the staying group", followed by stereoselective reduction leading to the latter.
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