105499-66-9

Upstream product

• 105499-63-6 (4aR,5S)-5-Hydroxy-4,4a,5,6-tetrahydro-3H-cyclopenta[c]pyran-7-one 
• 82207-78-1 (1S,6R,7R)-(-)-2-(Benzylthio)-7-hydroxy-3-oxabicyclo<4.3.0>nonan-9-on 
• 74552-31-1 (6R,7R)-(-)-7-Hydroxy-3-oxabicyclo<4.3.0>non-1-en-9-on 
• 100-39-0 benzyl bromide 
• 82207-80-5 (1S,6R,7R,9R)-(-)-2-(Benzylthio)-3-oxabicyclo<4.3.0>nonan-7,9-diol 
• 105448-90-6 (1S,2S,6R,7R,9S)-(-)-2-(Benzylthio)-3-oxabicyclo<4.3.0>nonan-7,9,-diyl-bis(4-methylbenzolsulfonat) 
• 105448-90-6 (1S,2S,6R,7R,9R)-(-)-2-(Benzylthio)-3-oxabicyclo<4.3.0>nonan-7,9,-diyl-bis(4-methylbenzolsulfonat) 
• 85249-06-5 (1S,4aR,5R,7S,7aS)-1-Benzylsulfanyl-octahydro-cyclopenta[c]pyran-5,7-diol 
• 85249-07-6 (1S,4aR,5R,7R,7aS)-1-Benzylsulfanyl-octahydro-cyclopenta[c]pyran-5,7-diol 
• 105500-40-1 (1S,2S,6R,7S,9R)-(-)-2-(Benzylthio)-3-oxabicyclo<4.3.0>nonan-7,9-diol 
• 105499-64-7 (1S,2S,6R,7S)-(-)-2-(Benzylthio)-7-hydroxy-3-oxabicyclo<4.3.0>nonan-9-on 

Downstream Products

• 88365-28-0 (Z)-7-{(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-[(E)-(R)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-hept-5-enoic acid 
• 88365-27-9 (Z)-7-{(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-hept-5-enoic acid 
• 88365-22-4 9,11-Dibenzyl-2-decarboxy-15-dehydro-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-PGF_1β 
• 88424-55-9 9,11-Dibenzyl-2-decarboxy-15-dehydro-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-12-epi-PGF_1β 
• 88391-24-6 9,11-Dibenzyl-2-decarboxy-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-PGF_1β 
• 88391-25-7 9,11-Dibenzyl-2-decarboxy-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-PGF1β 
• 88365-23-5 9,11-Dibenzyl-2-decarboxy-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-12-epi-PGF_1β 
• 88391-23-5 Biphenyl-4-carboxylic acid 2-[(1R,2S,3R,5R)-3,5-bis-benzyloxy-2-((E)-(R)-3-hydroxy-oct-1-enyl)-cyclopentyl]-ethyl ester 
• 88365-29-1 (Z)-7-[(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-((E)-(S)-3-hydroxy-oct-1-enyl)-cyclopentyl]-hept-5-enoic acid 
• 88365-30-4 (15R)-9,11-Dibenzyl-12-epi-PGF_2β 
• 88391-32-6 {(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-[(E)-(R)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-acetaldehyde 
• 88365-26-8 {(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-acetaldehyde 
• 88391-29-1 2-{(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-[(E)-(R)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-ethanol 
• 88365-25-7 2-{(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-ethanol 

Relevant academic research and scientific papers

Chemistry and Stereochemistry of Iridoids, VII. - Enantiomerically Pure Intermediates for the Synthesis of Diastereomeric 12-epi-Prostaglandins

6,3'-epi-Catalpol (8a) is yielded from catalpol (7a) by a four component inversion reaction. 8a subsequently is converted into (1S,2S,6R,7S)-(-)-2-(benzylthio)-7-hydroxy-3-oxabicyclononan-9-on (4).LiAlH4 reduction of 4 affords the diastereomeric 2-