105543-47-3Relevant academic research and scientific papers
REACTIVITY OF A NOVEL AMBIDENT DIANION FORMED BY DOUBLE DEPROTONATION OF β-THIOSUBSTITUTED DITHIOPROPANOATES : A LITHIO-ACRYLATE EQUIVALENT.
Beslin, Pierre,Dlubala, Alain
, p. 1687 - 1690 (1986)
A novel lithium allyl dianion has been generated by double deprotonation of β-alkyl (aryl) thio-dithioester.Reactions of this dianion with alkyl iodide, trimethylsilyl chloride and epoxyde occur at the γ-site.The regiochemistry of its addition to carbonyl
