REACTIVITY OF A NOVEL AMBIDENT DIANION FORMED BY DOUBLE DEPROTONATION OF β-THIOSUBSTITUTED DITHIOPROPANOATES : A LITHIO-ACRYLATE EQUIVALENT.

DOI: 10.1016/S0040-4039(00)84348-8

Source and publish data:

Tetrahedron Letters p. 1687 - 1690 (1986)

Update date:2022-07-30

Topics:

Authors:

Beslin, Pierre

Dlubala, Alain

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Article abstract of DOI:10.1016/S0040-4039(00)84348-8

A novel lithium allyl dianion has been generated by double deprotonation of β-alkyl (aryl) thio-dithioester.Reactions of this dianion with alkyl iodide, trimethylsilyl chloride and epoxyde occur at the γ-site.The regiochemistry of its addition to carbonyl

Full text of DOI:10.1016/S0040-4039(00)84348-8

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