105556-82-9

Upstream product

• 105556-81-8 (3R)-(E,Z)-1-methoxy-3-methyl-3-p-tolylpenta-1,4-diene 
• 155612-31-0 (2R)-2-methyl-2-p-tolyl-3-butenal 
• 367520-82-9 (R)-2-methyl-2-(p-tolyl)but-3-en-1-ol 
• 156817-47-9 (Z)-2-(p-methylphenyl)-2-buten-1-ol 
• 105556-81-8 (3R)-(E)-1-methoxy-3-methyl-3-p-tolylpenta-1,4-diene 
• 2947-61-7 (4-methylphenyl)acetonitrile 
• 74-88-4 methyl iodide 

Downstream Products

• 65564-92-3 (S)-(-)-3-methyl-3-(4-methylphenyl)cyclopentanone 
• 105556-83-0 (3R)-trimethyl-3-methyl-3-p-tolyl-2,2,3-4-pentanal 
• 105556-84-1 (3R)-(E,Z)-1-methoxy-2,3-dimethyl-3-p-tolyl-1,4-pentadiene 
• 105556-81-8 (3R)-(E,Z)-1-methoxy-3-methyl-3-p-tolylpenta-1,4-diene 
• 105556-87-4 (3S)-5-n-butylthiomethylidene-3-methyl-3-p-tolylcyclopentan-1-one 
• 105556-86-3 (3S)-5-hydroxymethylidene-3-methyl-3-p-tolylcyclopentan-1-one 

Relevant academic research and scientific papers

Regioselective and Stereospecific Rhodium-Catalyzed Allylic Cyanomethylation with an Acetonitrile Equivalent: Construction of Acyclic β-Quaternary Stereogenic Nitriles

A highly regioselective and stereospecific rhodium-catalyzed cyanomethylation of tertiary allylic carbonates for the construction of acyclic β-quaternary stereogenic nitriles is described. This protocol represents the first example of a metal-catalyzed al

Asymmetric total synthesis of (R)-α-cuparenone, (S)-cuparene and formal synthesis of (R)-β-cuparenone through Meinwald rearrangement and ring closing metathesis (RCM) reaction

Asymmetric synthesis of enantiopure cuparenoid sesquiterpenes (R)-α-cuparenone, (S)-cuparene and a formal synthesis of (R)-β-cuparenone was presented in this article. Meinwald rearrangement of an enantiopure trisubstituted 2,3-epoxy alcohol derivative was