10556-98-6Relevant articles and documents
Notiz zur Darstellung des N-Methylisopropylamins
Al Shaik, Mohammed,Oelschlaeger, Herbert,Rothley, Dietrich
, p. 644 - 646 (1981)
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Dickinson,Graymore
, p. 1368 (1937)
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Synthesis and Crystal Structure of Dipotassium Salts of N-Alkyl-N-{[O-alkoxy(hydroxy)phosphoryl]methyl}ditiocarbamic Acids
Garifzyanov, A. R.,Islamov, D. R.,Mirzayanov, I. I.,Shtyrlin, V. G.
, p. 381 - 384 (2020/04/27)
Abstract: A one-pot method for the synthesis of dipotassium salts of N-alkyl-N-{[O-alkoxy(hydroxy)phosphoryl]methyl}dithiocarbamic acids has been elaborated. Dipotassium salts of N-isopropyl-, N-butyl-, and N-cyclohexyl-N-{[hydroxy(O-ethoxy)phosphoryl]methyl}dithiocarbamic acids as well as N-{[O-butoxy(hydroxy)phosphoryl]methyl}-N-(2-methoxyethyl)dithiocarbamic acid have been synthesized and isolated. Crystal and molecular structure of the latter compound have been elucidated.
Facile Access to 3-Unsubstituted Tetrahydroisoquinolonic Acids via the Castagnoli-Cushman Reaction
Guranova, Natalia,Dar'In, Dmitry,Krasavin, Mikhail
, p. 2001 - 2008 (2018/03/06)
Hitherto undescribed 3-unsubstituted tetrahydroisoquinolonic acids (isolated as their respective methyl esters) were accessed for the first time by the uncatalyzed, thermally promoted Castagnoli-Cushman reaction (CCR) of homophthalic anhydride (HPA) and a series of 1,3,5-triazinanes. The moderate yields observed in some cases are most likely associated with a persistent impurity also formed in these reactions. The new scaffold is expected to find novel medicinal utility (compared to the traditional CCR adducts) because it lacks a substituent at the 3-position.