75-09-2

Basic information

• Product Name: Dichloromethane
• Synonyms: Dichloromethane [UN1593] [Poison];methane, dichloro-;Methylene chloride (NF);Aerothene MM;Methylene Chloride
• CAS NO: 75-09-2
• Molecular Formula: CH₂Cl₂
• Molecular Weight: 84.93258
• EINECS: 200-838-9
• Mol File: 75-09-2.mol
• Article Data: 291

Chemical Properties

• Melting Point: -97℃
• Boiling Point: 39.6 °C at 760 mmHg
• Flash Point: 39-40 °C
• Appearance: colorless liquid
• Density: 1.252 g/cm³
• Refractive Index: 1.4242
• Water Solubility: 20 g/L (20℃)
• CAS DataBase Reference: Dichloromethane(CAS DataBase Reference)
• NIST Chemistry Reference: Dichloromethane(75-09-2)
• EPA Substance Registry System: Dichloromethane(75-09-2)

Safety Data

• Hazard Codes: Xn:Harmful
• Statements: R40:
• Safety Statements: S23:; S24/25:; S36/37:
• RIDADR: 1593
• HazardClass: 6.1
• PackingGroup: III
• Hazardous Substances Data: 75-09-2(Hazardous Substances Data)

Usage

InChI:InChI=1/CH2Cl2/c2-1-3/h1H2

Synthetic route

tris(cyclopentadienyl)hafnium hydride (84101-40-6) → dichloromethane (75-09-2) + ((C5H5)2HfCl)2O*C4H8O

Conditions	Yield
With chloroform In toluene under Ar; stirred at 20°C for 5 h; stored overnight at 0-5°C; evaporated, extracted (THF); elem. anal.;	A 57% B 88%

1,2-Dichloroethylene (540-59-0) → dichloromethane (75-09-2) + 1,2-bis(trichlorosilyl)ethane (2504-64-5) + 1,2-bis(trichlorosilyl)ethene (692-52-4) + 1,1,1,3,3,3-hexachloro-1,3-disilapropane (4142-85-2)

Conditions	Yield
With hexachlorodisilane at 550℃; for 0.00833333h;	A n/a B n/a C 83% D n/a

1,3-bis-dichloromethyl-1,1,3,3-tetramethyl-disiloxane (2943-70-6) → dichloromethane (75-09-2)

Conditions	Yield
With KOH In water; butan-1-ol heating of (CH3)2(CHCl2)SiOSi(CH3)2(CHCl2) and 10% KOH in n-butanol/H2O at 45°C under reduced pressure;;	78%
With KOH In potassium hydroxide aq. KOH; (CH3)2(CHCl2)SiOSi(CH3)2(CHCl2) and 40% aq. KOH;;
With potassium hydroxide In potassium hydroxide (CH3)2(CHCl2)SiOSi(CH3)2(CHCl2) and 40% aq. KOH;;

tris(cyclopentadienyl)zirconiumhydride → dichloromethane (75-09-2) + ((C5H5)2ZrCl)2O*2C4H8O

Conditions	Yield
With chloroform In toluene under Ar; excess of CHCl3 added to suspension of Cp3ZrH in PhMe; stirred at about 20°C for 5 h; stored overnight at 0-5°C; evaporated, extracted (THF), filtered; filtrate evapd.; elem. anal.;	A 70% B 42%

methane (34557-54-5) → dichloromethane (75-09-2) + methanesulfonyl chloride (124-63-0)

Conditions	Yield
With sulfur dioxide; chlorine at 25℃; under 2250.23 Torr; for 1h; Concentration; Wavelength; Irradiation;	A n/a B 69%

Schwartz's reagent → zirconocene dichloride (1291-32-3) + dichloromethane (75-09-2)

Conditions	Yield
With chloroform In toluene under Ar; elem. anal.;	A 67% B 43%

methane (34557-54-5) → tetrachloromethane (56-23-5) + methylene chloride (74-87-3) + dichloromethane (75-09-2) + chloroform (67-66-3) + methanesulfonyl chloride (124-63-0)

Conditions	Yield
With hydrogenchloride; sulfur dioxide; chlorine at 63 - 67℃; under 6750.68 Torr; Photolysis;	A n/a B n/a C n/a D n/a E 55%

methane (34557-54-5) → dichloromethane (75-09-2) + chloroform (67-66-3) + methanesulfonyl chloride (124-63-0)

Conditions	Yield
With sulfur dioxide; chlorine at 65℃; under 2250.23 Torr; for 1h; Temperature; Irradiation;	A n/a B n/a C 54.9%

tetrachloromethane (56-23-5) → dichloromethane (75-09-2) + chloroform (67-66-3)

Conditions	Yield
With tetra-n-butylphosphonium formate In water at -20 - 22℃; for 1.33333h; Reagent/catalyst;	A 26% B 52%
With [RuCl(1-butyl-3-methyl-imidazole)(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]3,7decane)(η6-p-cymene)]Cl; hydrogen; sodium formate In water at 80℃; under 7500.75 Torr; for 2h; Schlenk technique; Sealed tube;	A 12.9% B 29%
With isopropyl alcohol; dimanganese decacarbonyl at 120℃; Product distribution; catalyst and temperature effects;

diiodomethane (75-11-6) → dichloromethane (75-09-2) + Chloroiodomethane (593-71-5)

Conditions	Yield
With iodine trichloride Product distribution; further iodoalkanes;	A 34% B 50%

Dichlorofluoromethane (75-43-4) + benzene-d6 (1076-43-3) + Triethylgerman (1188-14-3) → R32 (593-70-4) + dichloromethane (75-09-2) + bis-pentadeuteriophenyl-methane (35782-14-0) + triethylchlorogermane (994-28-5)

Conditions	Yield
With ACF. Et3GeH In benzene-d6 at 70℃; for 216h; Schlenk technique; Inert atmosphere;	A 50% B 11% C 39% D n/a

chloro-trimethyl-silane (75-77-4) + chloroform (67-66-3) → dichloromethane (75-09-2) + trichloromethyltrimethylsilane (5936-98-1)

Conditions	Yield
With hexaethylphosphoric triamide In acetonitrile at 20℃; for 144h;	A n/a B 47%

chloroform (67-66-3) → dichloromethane (75-09-2) + (dichlorosilylmethyl)trichlorosilane (18171-02-3) + 1,1,1,3,3,3-hexachloro-1,3-disilapropane (4142-85-2)

Conditions	Yield
With trichlorosilane at 100℃; for 8h;	A 42% B 5% C 42%

Chlorodifluoromethane (75-45-6) + Triethylgerman (1188-14-3) → methylene chloride (74-87-3) + dichloromethane (75-09-2) + trifluoromethan (75-46-7) + triethylchlorogermane (994-28-5)

Conditions	Yield
With ACF. Et3GeH at 25℃; for 72h; Schlenk technique; Inert atmosphere;	A 41% B 32% C 27% D n/a

chloroform (67-66-3) + aniline (62-53-3) → dichloromethane (75-09-2) + phenyl isocyanate (1197040-29-1) + Azobenzene (1227476-15-4) + N-phenylphenylene-1,4-diamine (101-54-2) + N-phenyl-1,2-benzenediamine (534-85-0) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 15℃; for 24h; Product distribution; Mechanism; Irradiation;	A n/a B 30.2% C 12.5% D 10.5% E 18.4% F n/a

chloroform (67-66-3) + Triethylgerman (1188-14-3) → methylene chloride (74-87-3) + dichloromethane (75-09-2) + triethylchlorogermane (994-28-5)

Conditions	Yield
With ACF. Et3GeH at 70℃; Schlenk technique; Glovebox;	A 22% B n/a C n/a

Dichlorofluoromethane (75-43-4) + Triethylgerman (1188-14-3) → Difluoromethane (75-10-5) + dichloromethane (75-09-2) + trifluoromethan (75-46-7) + Chlorodifluoromethane (75-45-6) + triethylchlorogermane (994-28-5)

Conditions	Yield
With ACF. Et3GeH at 25℃; for 72h; Schlenk technique; Inert atmosphere;	A n/a B n/a C 22% D 16% E n/a

methylenesulfurtetrafluoride (66793-25-7) → dichloromethane (75-09-2) + Methylschwefelpentafluorid (753-79-7) + cis-Methylschwefelchloridtetrafluorid (72161-32-1, 119616-12-5) + cis-(Chlormethyl)schwefelchloridtetrafluorid (72161-34-3) + SF4

Conditions	Yield
With chlorine In trichlorofluoromethane at -78℃;	A n/a B n/a C n/a D 20% E n/a

chloroform (67-66-3) + benzene-d6 (1076-43-3) + Triethylgerman (1188-14-3) → dichloromethane (75-09-2) + bis-pentadeuteriophenyl-methane (35782-14-0) + triethylchlorogermane (994-28-5)

Conditions	Yield
With ACF. Et3GeH at 70℃; Schlenk technique; Glovebox;	A n/a B 18% C n/a

methane (34557-54-5) → tetrachloromethane (56-23-5) + methylene chloride (74-87-3) + dichloromethane (75-09-2) + chloroform (67-66-3)

Conditions	Yield
With chlorine for 4h; Product distribution; Ambient temperature; var. catalysts and times;	A 4.8% B 6.5% C 15% D 14%
With molybdenum(V) chloride at 699.9℃; Product distribution; Mechanism; var. time, temp., and transition-metal chlorides; var. methane and argon flow rates;
With copper dichloride In melt at 449.9℃; Kinetics; Product distribution; further temperatures and concentrations;

tetrachloromethane (56-23-5) + Triethylgerman (1188-14-3) → dichloromethane (75-09-2) + chloroform (67-66-3) + triethylchlorogermane (994-28-5)

Conditions	Yield
With ACF. Et3GeH at 70℃; Schlenk technique; Glovebox;	A 8% B n/a C n/a

tetrachloromethane (56-23-5) + benzene-d6 (1076-43-3) + Triethylgerman (1188-14-3) → dichloromethane (75-09-2) + chloroform (67-66-3) + bis-pentadeuteriophenyl-methane (35782-14-0) + triethylchlorogermane (994-28-5)

Conditions	Yield
With ACF. Et3GeH at 70℃; Schlenk technique; Glovebox;	A 7% B n/a C 6% D n/a

pentacarbonyl(methoxyphenylmethylene)tungsten(0) (37823-96-4) → 1,1,2,2-tetrachloroethylene (127-18-4) + methylene chloride (74-87-3) + dichloromethane (75-09-2) + chloroform (67-66-3)

Conditions	Yield
In tetrachloromethane byproducts: HCl, Cl2; further products; N2; stirred; gas-chromy., MAS; elem. anal.;	A 6.8% B 2% C 0.2% D 3.6%

tetrachloromethane (56-23-5) → dichloromethane (75-09-2)

Conditions	Yield
With isopropyl alcohol In acetonitrile at 20℃; Reagent/catalyst;
With sodium hydroxide; iron(II) sulfate

1H-imidazole (288-32-4) + dichloromethane (75-09-2) → 1,1'-bis(imidazolyl)methane (84661-56-3)

Conditions	Yield
With potassium hydroxide; tetrabutylammomium bromide for 13h; Ambient temperature;	100%
With sodium hydroxide; phase transfer catalysis by tetraethylammonium bromide for 16h; Ambient temperature;	96%
With tetrabutylammomium bromide; sodium hydroxide Inert atmosphere; Reflux;	87%

acetophenone oxime (613-91-2) + dichloromethane (75-09-2) → 1-Phenyl-ethanone O-[1-phenyl-eth-(E)-ylideneaminooxymethyl]-oxime (71516-53-5)

Conditions	Yield
With 18-crown-6 ether; potassium carbonate	100%
With 1-butyl-3-methylimidazolium Tetrafluoroborate; sodium hydroxide at 20℃; for 0.5h;	96%
With sodium hydroxide In water for 17.5h;	95%
With sodium hydroxide; trialkyl-methyl-ammonium chloride

3-benzoylpyrrole (7126-41-2) + dichloromethane (75-09-2) → [1-(2-Benzoyl-pyrrol-1-ylmethyl)-1H-pyrrol-2-yl]-phenyl-methanone (98258-78-7)

Conditions	Yield
With sodium hydroxide; tetra-(n-butyl)ammonium iodide In dichloromethane for 4h;	100%

dichloromethane (75-09-2) + 4-chloro-phenol (106-48-9) → bis(p-chlorophenoxy)methane (555-89-5)

Conditions	Yield
With potassium hydroxide; benzyltrimethylammonium chloride In water at 40℃; for 72h;	100%
With potassium hydroxide; benzyltrimethylammonium chloride In dichloromethane at 40℃; for 72h;	100%
Stage #1: 4-chloro-phenol With sodium hydride In 1-methyl-pyrrolidin-2-one Stage #2: dichloromethane In 1-methyl-pyrrolidin-2-one at 40℃; for 9h;	98%
With 1-methyl-pyrrolidin-2-one; sodium hydride at 40℃; for 9h;	98%
With sodium hydroxide; Amberlite IRA-400 (Cl-) 2.) reflux, 15 h; Yield given. Multistep reaction;

dichloromethane (75-09-2) + phenol (108-95-2) → diphenoxymethane (4442-41-5)

Conditions	Yield
With potassium hydroxide; octopus-type calixarene at 40℃; for 24h; Product distribution; also with substituted phenols; effect of catalysts poly(ethylene glycol)diethyl ether, poly(ethylene glycol), benzyltrimethylammonium chloride, none; also with water solvent;	100%
With potassium hydroxide; octopus-type calixarene at 40℃; for 24h;	100%
With potassium hydroxide; 5,11,17,23,29,35-Hexa-p-tert-butyl-37,38,39,40,41,42-hexakis-(3,6,9-trioxadecyloxy)calix<6>arene In dichloromethane at 40℃; for 24h;	100%

dichloromethane (75-09-2) + (2R,3R)-3-(methylamino)-3-phenyl-1,2-propanediol (313640-98-1) → (4R,5R)-3-methyl-4-phenyl-1,3-oxazinan-5-ol

Conditions	Yield
at 100℃; for 28h; Cyclization;	100%

dichloromethane (75-09-2) + benzotriazol-1-ol (2592-95-2) → 1-chloromethoxy-1H-benzotriazole (3912-23-0)

Conditions	Yield
at 55℃;	100%

dichloromethane (75-09-2) + diethylamine (109-89-7) + 2,2-dimethyl-2H-1-benzopyran-6-sulfonyl chloride (185316-64-7) → N,N-diethyl-2,2-dimethyl-2H-1-benzopyran-6-sulfonamide (186181-08-8)

Conditions	Yield
In water	100%

dichloromethane (75-09-2) + 1-(bromomethyl)-4-methyl-2-(phenylmethoxy)benzene (117571-35-4) → <4-methyl-2-(phenylmethoxy)phenyl>acetonitrile (117571-36-5)

Conditions	Yield
With NaCN; tetrabutylammomium bromide In water	100%

Nα -Boc-L-ornithine + dichloromethane (75-09-2) + 2-fluorobenzonitrile (394-47-8) → (2S)-2-amino-5-(2-cyanophenylamino)pentanoic acid (159877-02-8)

Conditions	Yield
With hydrogenchloride; sodium hydroxide; acetic acid In ethanol; water	100%

dichloromethane (75-09-2) + 5-Chlorovaleroyl chloride (1575-61-7) + 1,4-dihydro-4-(3-aminophenyl)-2,6-dimethyl-3,5-pyridinedicarboxylic acid,dimethyl ester (21835-63-2) → 1,4-Dihydro-4-[3-[[5-chloro-1-oxo-1-pentyl]amino]phenyl]-2,6-dimethyl-3,5-pyridinedicarboxylic acid, dimethyl ester

Conditions	Yield
In tetrahydrofuran; water; ethyl acetate	100%
In tetrahydrofuran; water; ethyl acetate	100%
In tetrahydrofuran; water; ethyl acetate	100%

(CH3)2 AlNH2 + dichloromethane (75-09-2) + 2-bromo-5-methoxy-1-(phenylmethyl)-1H-indole-3-acetic acid phenylmethyl ester (163734-89-2) → 2-bromo-5-methoxy-1-(phenylmethyl)-1H-indole-3-acetamide (164083-06-1)

Conditions	Yield
With hydrogenchloride; aluminium In benzene	100%

CH3 I + 2-carboxy-4-chloroquinoline (15733-82-1) + dichloromethane (75-09-2) + water (7732-18-5) → Methyl-4-chloroquinaldate (114935-92-1)

Conditions	Yield
With NaH In N,N-dimethyl-formamide	100%

dichloromethane (75-09-2) + tert-butylamine (75-64-9) + 3,4-diethoxy-3-cyclobuten-1,2-dione (5231-87-8) → 3-(1,1-dimethylethylamino)-4-ethoxy-3-cyclobutene-1,2-dione (186184-26-9)

Conditions	Yield
In tetrahydrofuran; methanol	100%

dichloromethane (75-09-2) + di-tert-butyl dicarbonate (24424-99-5) → 6-(tert-butyloxycarbonylamino)-1-diethylamino-2-hydroxyhexane

Conditions	Yield
	100%

5-METHOXY-2-((3,5-DIMETHYL-4-NITRO-2-PYRIDINYL-N-OXIDE)-METHYLTHIO)-1H-BENZIMIDAZOLE (142885-90-3) + dichloromethane (75-09-2) → 5-methoxy-2-[[(4-methoxy-3,5-dimethylpyridin-2-yl-1-oxide)methyl]sulfanyl]-1H-benzimidazole (142885-92-5)

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; sodium methylate In methanol; water	100%

diazomethane (186581-53-3, 908094-01-9) + methyl α-tert-butoxycarbonylamino-p-carboxymethylphenylacetate (174487-79-7) + dichloromethane (75-09-2) → Methyl α-tert-butoxycarbonylamino-p-methoxycarbonylmethylphenylacetate (174487-81-1)

Conditions	Yield
	100%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + dichloromethane (75-09-2) + triphenylantimony (603-36-1) → Rh(C8H12)(Sb(C6H5)3)2Cl*0.5CH2Cl2

Conditions	Yield
In ethanol (under Ar, Schlenk); Rh-complex added to refluxing soln. of Sb(C6H5)3 inEtOH; ppt. filtered, washed with CH2Cl2/hexane, dried in vacuo; elem. anal.;	100%

dichloromethane (75-09-2) + PdCl((OCH3)2C6H3CHNC6H10NCHC6H2(OCH3)2) + silver perchlorate + 4-nitro-aniline (100-01-6) → Pd(NH2C6H4NO2)((OCH3)2C6H3CHNC6H10NCHC6H2(OCH3)2)(1+)*ClO4(1-)*0.6CH2Cl2=C30H35N4O6PdClO4*0.6CH2Cl2

Conditions	Yield
In acetone byproducts: AgCl; soln. of palladium complex treated with AgClO4 in absence of light; 30 min stirred at room temp.; added to soln. of p-nitroaniline; soln. stirred at room temp. for 30 min; solvent evapd.; oil treated with Et2O; solid pptd.; elem. anal.;	100%

dichloromethane (75-09-2) + hh-[(p-tolyl)Pt(μ-2-diphenylphosphinopyridine)2PtMe2](trifluoroacetate)*0.7(methylene chloride) → ht-[(p-tolyl)Pt(μ-2-diphenylphosphinopyridine)2PtMe2](trifluoroacetate)*0.5(methylene chloride)

Conditions	Yield
In dichloromethane soln. of Pt complex in CH2Cl2 stored at room temp. for 10 d; solvent evapd.; washed with hexane; elem. anal.;	100%

sodium tetrafluoroborate (13755-29-8) + dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer + dichloromethane (75-09-2) + (C6F5)(C6H5)PC6H4SCH3 (486403-20-7) → [(η5-C5(CH3)5RhCl(C6F5)PhPC6H4SMe-2]BF4

Conditions	Yield
In not given Atherton, M. J.; Fawcett, J.; Holloway, J. H.; Hope, E. G.; Karacar, A.;Russell, D. R.; Saunders, G. C. J. Chem. Soc., Dalton Trans. 1996, 321 5; elem. anal.;	100%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + dichloromethane (75-09-2) + (bromodifluoromethyl)diphenylphosphine (681435-29-0) → cis-[PtCl2(κ1-Ph2PCF2Br)2]*(dichloromethane)

Conditions	Yield
In dichloromethane by a react. of Ph2PCF2Br with Pt-contg. compd. at 20°C for 0.2 h; elem. anal.;	100%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + dichloromethane (75-09-2) + n-butyl isonitrile (2769-64-4) + 3,5-bis[bis-(4,5-diphenyl-1-methylimidazol-2-yl)methoxymethyl]pyrazole (1032544-28-7) → [(3,5-bis[bis-(4,5-diphenyl-1-methylimidazol-2-yl)methoxymethyl]pyrazole-H)Cu2(n-BuNC)]2(PF6)2*3.8CH2Cl2

Conditions	Yield
With KOC(CH3)3 In tetrahydrofuran; acetonitrile (N2, glove box) a soln. of Cu-complex in CH3CN was added to a soln. of pyrazole-compound and KOC(CH3)3 in THF, stirred for 15 min, n-butylisocyanide was added, stirred for 20 min; the solvent was removed in vac., the solid was dissolved in CH2Cl2 and filtered; elem. anal.;	100%

trichlorotris(tetrahydrofuran)chromium(III) (10170-68-0, 16997-54-9) + dichloromethane (75-09-2) + 2,6-bis(1-methylimidazol-2-ylidene)pyridine (1046479-99-5) → [2,6-bis(1-methylimidazol-2-ylidene)pyridine chromium trichloride]*CH2Cl2

Conditions	Yield
In tetrahydrofuran (N2); std. Schlenk technique; soln. of carbene in THF was slowly added to soln. of Cr complex in THF; stirred for 1 h; filtered; washed (THF, CH2Cl2); dried (vac.); elem. anal.;	100%

dichloromethane (75-09-2) + C39H41N3O4 (1026988-13-5) → C40H43ClN3O4(1+)*Cl(1-) (1026988-19-1)

Conditions	Yield
at 25℃; Kinetics;	100%

dichloromethane (75-09-2) + Ti(N(CH3)2)2(NC4H3CH2PO(C6H5)2)2 → Ti(N(CH3)2)Cl(NC4H3CH2PO(C6H5)2)2

Conditions	Yield
In dichloromethane (N2, Schlenk) a soln. of complex in CH2Cl2 allowed to stand for 2 h; volatiles were removed under vac.; elem. anal.;	100%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + dichloromethane (75-09-2) + 5-diphenylphosphino-17-p-tolyl-25,26,27,28-tetrapropoxycalix[4]arene → dichlorido-(η6-cymene)-[5-diphenylphosphino-17-(p-tolyl)-25,26,27,28-tetrapropoxycalix[4]arene]ruthenium(II)*0.5(dichloromethane)

Conditions	Yield
In dichloromethane (under N2, Schlenk); soln. of Ru-complex in CH2Cl2 added dropwise to soln. of ligand in CH2Cl2, stirred for 1 h; concd., hexane added; elem. anal.;	100%

1-methyl-1H-imidazole (616-47-7) + dichloromethane (75-09-2) → 1,1′-methylenebis(3-methyl-1H-imidazol-3-ium) dichloride

Conditions	Yield
In chloroform at 60℃; under 14251400 Torr; for 24h; Kinetics; Pressure; Temperature; Menshutkin Reaction; High pressure; Autoclave;	100%
for 0.25h; Microwave irradiation; Reflux;	48%
at 75℃; for 24h;	42.6%

dichloromethane (75-09-2) + C30H24O12 (1305346-38-6) + ethylenediamine (107-15-3) → CH2Cl2*C66H54N6O18(6-)*6Na(1+)

Conditions	Yield
With [D]-sodium hydroxide; sodium acetate In water-d2 for 2h; pD >11;	100%

dichloromethane (75-09-2) + trans-bromo(bis(triphenylphosphine))(3-(-)-menthyloxy-3-oxy-1-propinyl)palladium(II) + trimethoxonium tetrafluoroborate (420-37-1) → trans-(acetonitrile)(3-(-)-menthyloxy-3-oxy-1-propinyl)palladium(II) tetrafluoroborate dichloromethane sesquisolvate

Conditions	Yield
In acetonitrile inert atmosphere, Schlenk technique; soln. of Pd-complex in CH3CN treated at -40 °C with (H3C)3OBF4, stirred at -40 °C for 60 min,warmed to room temp., solvent removed (vac.), recrystd. from petroleum ether/CH2Cl2; elem. anal.;	100%

Upstream product

• 67-56-1 Methanol 

Downstream Products

• 64491-68-5 (S)-(+)-Methyl glycidyl ether 
• 56651-57-1 4-Methylbenzyl isocyanate 
• 26690-80-2 TERT-BUTYL N-(2-HYDROXYETHYL)CARBAMATE 
• 14592-56-4 Bis(acetonitrile)dichloropalladium(II) 
• 1732-08-7 DIMETHYL PIMELATE 
• 21906-36-5 (4-IODOPHENYL)ACETONE 
• 58930-15-7 dimethyl hexadecyl ammoium butayl sulfate 
• 96989-50-3 DI-2-PYRIDYL THIONOCARBONATE 
• 124-17-4 2-(2-Butoxyethoxy)ethyl acetate 
• 285-67-6 Cyclopentene oxide 
• 60669-69-4 DIBUTYLBORON TRIFLUOROMETHANESULFONATE 
• 14002-51-8 4-Biphenylcarbonyl chloride 
• 6834-42-0 3-METHOXYPHENYLACETYL CHLORIDE 
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• 50-07-7 Mitomycin C 
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• 140-18-1 Benzyl 2-chloroacetate 
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• 2243-83-6 2-Naphthoyl chloride 

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