Welcome to LookChem.com Sign In|Join Free

CAS

  • or

75-09-2

Post Buying Request

75-09-2 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

75-09-2 Usage

Chemical Description

Different sources of media describe the Chemical Description of 75-09-2 differently. You can refer to the following data:
1. Dichloromethane, N,N-dimethylformamide (DMF), toluene, tetrahydrofuran (THF), diethyl ether, and 1,4-dioxane are used as solvents for the reactions.
2. Dichloromethane is a colorless, volatile liquid that is used as a solvent.
3. Dichloromethane and ether are organic solvents.
4. Dichloromethane and methanol are solvents used in the purification of Compound 38 and Compound 39.
5. Dichloromethane, also known as methylene chloride, is a colorless, volatile liquid with a sweet aroma.
6. Dichloromethane is a colorless liquid used as a solvent in various chemical reactions.
7. Dichloromethane is another solvent used in the purification of compounds.
8. Dichloromethane is a colorless, volatile liquid used as a solvent.
9. Dichloromethane is used as an extractant in the synthesis of derivatives 6 and 7.
10. Dichloromethane is a common solvent used in organic chemistry.
11. Dichloromethane, also known as methylene chloride, is a colorless, volatile liquid used as a solvent.
12. Dichloromethane is a solvent used in the synthesis of the organosulfonium azides.
13. Dichloromethane is a colorless, volatile liquid that is commonly used as a solvent.
14. Dichloromethane is a solvent used in the experiments.
15. Dichloromethane is a colorless liquid used as a solvent.
16. Dichloromethane and acetonitrile are solvents used in the reaction.
17. Dichloromethane and ethyl acetate are used as solvents for extraction, and C-amido-calix[3]indoles are the final products of the reaction.
18. Dichloromethane is a colorless, volatile liquid used as a solvent in various chemical reactions.
19. Dichloromethane is the solvent used in both UV/Vis and titration experiments.
20. Dichloromethane is a halogenated solvent that is often used as a reaction medium.
21. Dichloromethane is a colorless, volatile liquid commonly used as a solvent.
22. Dichloromethane is a colorless, volatile liquid with a sweet aroma, commonly used as a solvent.
23. Dichloromethane is a solvent used in the extraction process.
24. Dichloromethane, acetonitrile, and methanol are solvents used in the synthesis.
25. Dichloromethane is used for distillation.
26. Dichloromethane and acetonitrile are both solvents commonly used in organic chemistry.
27. Dichloromethane is a solvent commonly used in organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 75-09-2 includes 5 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 2 digits, 7 and 5 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 75-09:
(4*7)+(3*5)+(2*0)+(1*9)=52
52 % 10 = 2
So 75-09-2 is a valid CAS Registry Number.
InChI:InChI=1/CH2Cl2/c2-1-3/h1H2

75-09-2 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (39116)  Dichloromethane, ACS, 99.5+%, stab. with amylene   

  • 75-09-2

  • 500ml

  • 214.0CNY

  • Detail
  • Alfa Aesar

  • (39116)  Dichloromethane, ACS, 99.5+%, stab. with amylene   

  • 75-09-2

  • 1L

  • 422.0CNY

  • Detail
  • Alfa Aesar

  • (39116)  Dichloromethane, ACS, 99.5+%, stab. with amylene   

  • 75-09-2

  • 2.5L

  • 646.0CNY

  • Detail
  • Alfa Aesar

  • (39116)  Dichloromethane, ACS, 99.5+%, stab. with amylene   

  • 75-09-2

  • *4x1L

  • 982.0CNY

  • Detail
  • Alfa Aesar

  • (39116)  Dichloromethane, ACS, 99.5+%, stab. with amylene   

  • 75-09-2

  • 4L

  • 1002.0CNY

  • Detail
  • Alfa Aesar

  • (41835)  Dichloromethane, anhydrous, 99.7+%, packaged under Argon in resealable ChemSeal? bottles, stab. with amylene   

  • 75-09-2

  • 250ml

  • 279.0CNY

  • Detail
  • Alfa Aesar

  • (41835)  Dichloromethane, anhydrous, 99.7+%, packaged under Argon in resealable ChemSeal? bottles, stab. with amylene   

  • 75-09-2

  • 1L

  • 575.0CNY

  • Detail
  • Alfa Aesar

  • (41835)  Dichloromethane, anhydrous, 99.7+%, packaged under Argon in resealable ChemSeal? bottles, stab. with amylene   

  • 75-09-2

  • *4x1L

  • 1729.0CNY

  • Detail
  • Alfa Aesar

  • (42006)  Dichloromethane, Environmental Grade, 99.8+%, stab. with amylene   

  • 75-09-2

  • 1L

  • 379.0CNY

  • Detail
  • Alfa Aesar

  • (42006)  Dichloromethane, Environmental Grade, 99.8+%, stab. with amylene   

  • 75-09-2

  • 4L

  • 909.0CNY

  • Detail
  • Alfa Aesar

  • (42006)  Dichloromethane, Environmental Grade, 99.8+%, stab. with amylene   

  • 75-09-2

  • *4x1L

  • 1215.0CNY

  • Detail
  • Alfa Aesar

  • (42006)  Dichloromethane, Environmental Grade, 99.8+%, stab. with amylene   

  • 75-09-2

  • *4x4L

  • 3194.0CNY

  • Detail

75-09-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name dichloromethane

1.2 Other means of identification

Product number -
Other names Methane,dichloro

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Pesticides (chemicals used for killing pests, such as rodents, insects, or plants)
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:75-09-2 SDS

75-09-2Synthetic route

tris(cyclopentadienyl)hafnium hydride
84101-40-6

tris(cyclopentadienyl)hafnium hydride

A

dichloromethane
75-09-2

dichloromethane

B

((C5H5)2HfCl)2O*C4H8O

((C5H5)2HfCl)2O*C4H8O

Conditions
ConditionsYield
With chloroform In toluene under Ar; stirred at 20°C for 5 h; stored overnight at 0-5°C; evaporated, extracted (THF); elem. anal.;A 57%
B 88%
1,2-Dichloroethylene
540-59-0

1,2-Dichloroethylene

A

dichloromethane
75-09-2

dichloromethane

B

1,2-bis(trichlorosilyl)ethane
2504-64-5

1,2-bis(trichlorosilyl)ethane

C

1,2-bis(trichlorosilyl)ethene
692-52-4

1,2-bis(trichlorosilyl)ethene

D

1,1,1,3,3,3-hexachloro-1,3-disilapropane
4142-85-2

1,1,1,3,3,3-hexachloro-1,3-disilapropane

Conditions
ConditionsYield
With hexachlorodisilane at 550℃; for 0.00833333h;A n/a
B n/a
C 83%
D n/a
1,3-bis-dichloromethyl-1,1,3,3-tetramethyl-disiloxane
2943-70-6

1,3-bis-dichloromethyl-1,1,3,3-tetramethyl-disiloxane

dichloromethane
75-09-2

dichloromethane

Conditions
ConditionsYield
With KOH In water; butan-1-ol heating of (CH3)2(CHCl2)SiOSi(CH3)2(CHCl2) and 10% KOH in n-butanol/H2O at 45°C under reduced pressure;;78%
With KOH In potassium hydroxide aq. KOH; (CH3)2(CHCl2)SiOSi(CH3)2(CHCl2) and 40% aq. KOH;;
With potassium hydroxide In potassium hydroxide (CH3)2(CHCl2)SiOSi(CH3)2(CHCl2) and 40% aq. KOH;;
tris(cyclopentadienyl)zirconiumhydride

tris(cyclopentadienyl)zirconiumhydride

A

dichloromethane
75-09-2

dichloromethane

B

((C5H5)2ZrCl)2O*2C4H8O

((C5H5)2ZrCl)2O*2C4H8O

Conditions
ConditionsYield
With chloroform In toluene under Ar; excess of CHCl3 added to suspension of Cp3ZrH in PhMe; stirred at about 20°C for 5 h; stored overnight at 0-5°C; evaporated, extracted (THF), filtered; filtrate evapd.; elem. anal.;A 70%
B 42%
methane
34557-54-5

methane

A

dichloromethane
75-09-2

dichloromethane

B

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

Conditions
ConditionsYield
With sulfur dioxide; chlorine at 25℃; under 2250.23 Torr; for 1h; Concentration; Wavelength; Irradiation;A n/a
B 69%
Schwartz's reagent

Schwartz's reagent

A

zirconocene dichloride
1291-32-3

zirconocene dichloride

B

dichloromethane
75-09-2

dichloromethane

Conditions
ConditionsYield
With chloroform In toluene under Ar; elem. anal.;A 67%
B 43%
methane
34557-54-5

methane

A

tetrachloromethane
56-23-5

tetrachloromethane

B

methylene chloride
74-87-3

methylene chloride

C

dichloromethane
75-09-2

dichloromethane

D

chloroform
67-66-3

chloroform

E

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

Conditions
ConditionsYield
With hydrogenchloride; sulfur dioxide; chlorine at 63 - 67℃; under 6750.68 Torr; Photolysis;A n/a
B n/a
C n/a
D n/a
E 55%
methane
34557-54-5

methane

A

dichloromethane
75-09-2

dichloromethane

B

chloroform
67-66-3

chloroform

C

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

Conditions
ConditionsYield
With sulfur dioxide; chlorine at 65℃; under 2250.23 Torr; for 1h; Temperature; Irradiation;A n/a
B n/a
C 54.9%
tetrachloromethane
56-23-5

tetrachloromethane

A

dichloromethane
75-09-2

dichloromethane

B

chloroform
67-66-3

chloroform

Conditions
ConditionsYield
With tetra-n-butylphosphonium formate In water at -20 - 22℃; for 1.33333h; Reagent/catalyst;A 26%
B 52%
With [RuCl(1-butyl-3-methyl-imidazole)(1,3,5-triaza-7-phosphatricyclo[3.3.1.1]3,7decane)(η6-p-cymene)]Cl; hydrogen; sodium formate In water at 80℃; under 7500.75 Torr; for 2h; Schlenk technique; Sealed tube;A 12.9%
B 29%
With isopropyl alcohol; dimanganese decacarbonyl at 120℃; Product distribution; catalyst and temperature effects;
diiodomethane
75-11-6

diiodomethane

A

dichloromethane
75-09-2

dichloromethane

B

Chloroiodomethane
593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With iodine trichloride Product distribution; further iodoalkanes;A 34%
B 50%
Dichlorofluoromethane
75-43-4

Dichlorofluoromethane

benzene-d6
1076-43-3

benzene-d6

Triethylgerman
1188-14-3

Triethylgerman

A

R32
593-70-4

R32

B

dichloromethane
75-09-2

dichloromethane

C

bis-pentadeuteriophenyl-methane
35782-14-0

bis-pentadeuteriophenyl-methane

D

triethylchlorogermane
994-28-5

triethylchlorogermane

Conditions
ConditionsYield
With ACF. Et3GeH In benzene-d6 at 70℃; for 216h; Schlenk technique; Inert atmosphere;A 50%
B 11%
C 39%
D n/a
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

chloroform
67-66-3

chloroform

A

dichloromethane
75-09-2

dichloromethane

B

trichloromethyltrimethylsilane
5936-98-1

trichloromethyltrimethylsilane

Conditions
ConditionsYield
With hexaethylphosphoric triamide In acetonitrile at 20℃; for 144h;A n/a
B 47%
chloroform
67-66-3

chloroform

A

dichloromethane
75-09-2

dichloromethane

B

(dichlorosilylmethyl)trichlorosilane
18171-02-3

(dichlorosilylmethyl)trichlorosilane

C

1,1,1,3,3,3-hexachloro-1,3-disilapropane
4142-85-2

1,1,1,3,3,3-hexachloro-1,3-disilapropane

Conditions
ConditionsYield
With trichlorosilane at 100℃; for 8h;A 42%
B 5%
C 42%
Chlorodifluoromethane
75-45-6

Chlorodifluoromethane

Triethylgerman
1188-14-3

Triethylgerman

A

methylene chloride
74-87-3

methylene chloride

B

dichloromethane
75-09-2

dichloromethane

C

trifluoromethan
75-46-7

trifluoromethan

D

triethylchlorogermane
994-28-5

triethylchlorogermane

Conditions
ConditionsYield
With ACF. Et3GeH at 25℃; for 72h; Schlenk technique; Inert atmosphere;A 41%
B 32%
C 27%
D n/a
chloroform
67-66-3

chloroform

aniline
62-53-3

aniline

A

dichloromethane
75-09-2

dichloromethane

B

phenyl isocyanate
1197040-29-1

phenyl isocyanate

C

Azobenzene
1227476-15-4

Azobenzene

D

N-phenylphenylene-1,4-diamine
101-54-2

N-phenylphenylene-1,4-diamine

E

N-phenyl-1,2-benzenediamine
534-85-0

N-phenyl-1,2-benzenediamine

F

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 15℃; for 24h; Product distribution; Mechanism; Irradiation;A n/a
B 30.2%
C 12.5%
D 10.5%
E 18.4%
F n/a
chloroform
67-66-3

chloroform

Triethylgerman
1188-14-3

Triethylgerman

A

methylene chloride
74-87-3

methylene chloride

B

dichloromethane
75-09-2

dichloromethane

C

triethylchlorogermane
994-28-5

triethylchlorogermane

Conditions
ConditionsYield
With ACF. Et3GeH at 70℃; Schlenk technique; Glovebox;A 22%
B n/a
C n/a
Dichlorofluoromethane
75-43-4

Dichlorofluoromethane

Triethylgerman
1188-14-3

Triethylgerman

A

Difluoromethane
75-10-5

Difluoromethane

B

dichloromethane
75-09-2

dichloromethane

C

trifluoromethan
75-46-7

trifluoromethan

D

Chlorodifluoromethane
75-45-6

Chlorodifluoromethane

E

triethylchlorogermane
994-28-5

triethylchlorogermane

Conditions
ConditionsYield
With ACF. Et3GeH at 25℃; for 72h; Schlenk technique; Inert atmosphere;A n/a
B n/a
C 22%
D 16%
E n/a
methylenesulfurtetrafluoride
66793-25-7

methylenesulfurtetrafluoride

A

dichloromethane
75-09-2

dichloromethane

B

Methylschwefelpentafluorid
753-79-7

Methylschwefelpentafluorid

C

cis-Methylschwefelchloridtetrafluorid
72161-32-1, 119616-12-5

cis-Methylschwefelchloridtetrafluorid

D

cis-(Chlormethyl)schwefelchloridtetrafluorid
72161-34-3

cis-(Chlormethyl)schwefelchloridtetrafluorid

E

SF4

SF4

Conditions
ConditionsYield
With chlorine In trichlorofluoromethane at -78℃;A n/a
B n/a
C n/a
D 20%
E n/a
chloroform
67-66-3

chloroform

benzene-d6
1076-43-3

benzene-d6

Triethylgerman
1188-14-3

Triethylgerman

A

dichloromethane
75-09-2

dichloromethane

B

bis-pentadeuteriophenyl-methane
35782-14-0

bis-pentadeuteriophenyl-methane

C

triethylchlorogermane
994-28-5

triethylchlorogermane

Conditions
ConditionsYield
With ACF. Et3GeH at 70℃; Schlenk technique; Glovebox;A n/a
B 18%
C n/a
methane
34557-54-5

methane

A

tetrachloromethane
56-23-5

tetrachloromethane

B

methylene chloride
74-87-3

methylene chloride

C

dichloromethane
75-09-2

dichloromethane

D

chloroform
67-66-3

chloroform

Conditions
ConditionsYield
With chlorine for 4h; Product distribution; Ambient temperature; var. catalysts and times;A 4.8%
B 6.5%
C 15%
D 14%
With molybdenum(V) chloride at 699.9℃; Product distribution; Mechanism; var. time, temp., and transition-metal chlorides; var. methane and argon flow rates;
With copper dichloride In melt at 449.9℃; Kinetics; Product distribution; further temperatures and concentrations;
tetrachloromethane
56-23-5

tetrachloromethane

Triethylgerman
1188-14-3

Triethylgerman

A

dichloromethane
75-09-2

dichloromethane

B

chloroform
67-66-3

chloroform

C

triethylchlorogermane
994-28-5

triethylchlorogermane

Conditions
ConditionsYield
With ACF. Et3GeH at 70℃; Schlenk technique; Glovebox;A 8%
B n/a
C n/a
tetrachloromethane
56-23-5

tetrachloromethane

benzene-d6
1076-43-3

benzene-d6

Triethylgerman
1188-14-3

Triethylgerman

A

dichloromethane
75-09-2

dichloromethane

B

chloroform
67-66-3

chloroform

C

bis-pentadeuteriophenyl-methane
35782-14-0

bis-pentadeuteriophenyl-methane

D

triethylchlorogermane
994-28-5

triethylchlorogermane

Conditions
ConditionsYield
With ACF. Et3GeH at 70℃; Schlenk technique; Glovebox;A 7%
B n/a
C 6%
D n/a
pentacarbonyl(methoxyphenylmethylene)tungsten(0)
37823-96-4

pentacarbonyl(methoxyphenylmethylene)tungsten(0)

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

methylene chloride
74-87-3

methylene chloride

C

dichloromethane
75-09-2

dichloromethane

D

chloroform
67-66-3

chloroform

Conditions
ConditionsYield
In tetrachloromethane byproducts: HCl, Cl2; further products; N2; stirred; gas-chromy., MAS; elem. anal.;A 6.8%
B 2%
C 0.2%
D 3.6%
tetrachloromethane
56-23-5

tetrachloromethane

dichloromethane
75-09-2

dichloromethane

Conditions
ConditionsYield
With isopropyl alcohol In acetonitrile at 20℃; Reagent/catalyst;
With sodium hydroxide; iron(II) sulfate
1H-imidazole
288-32-4

1H-imidazole

dichloromethane
75-09-2

dichloromethane

1,1'-bis(imidazolyl)methane
84661-56-3

1,1'-bis(imidazolyl)methane

Conditions
ConditionsYield
With potassium hydroxide; tetrabutylammomium bromide for 13h; Ambient temperature;100%
With sodium hydroxide; phase transfer catalysis by tetraethylammonium bromide for 16h; Ambient temperature;96%
With tetrabutylammomium bromide; sodium hydroxide Inert atmosphere; Reflux;87%
acetophenone oxime
613-91-2

acetophenone oxime

dichloromethane
75-09-2

dichloromethane

1-Phenyl-ethanone O-[1-phenyl-eth-(E)-ylideneaminooxymethyl]-oxime
71516-53-5

1-Phenyl-ethanone O-[1-phenyl-eth-(E)-ylideneaminooxymethyl]-oxime

Conditions
ConditionsYield
With 18-crown-6 ether; potassium carbonate100%
With 1-butyl-3-methylimidazolium Tetrafluoroborate; sodium hydroxide at 20℃; for 0.5h;96%
With sodium hydroxide In water for 17.5h;95%
With sodium hydroxide; trialkyl-methyl-ammonium chloride
3-benzoylpyrrole
7126-41-2

3-benzoylpyrrole

dichloromethane
75-09-2

dichloromethane

[1-(2-Benzoyl-pyrrol-1-ylmethyl)-1H-pyrrol-2-yl]-phenyl-methanone
98258-78-7

[1-(2-Benzoyl-pyrrol-1-ylmethyl)-1H-pyrrol-2-yl]-phenyl-methanone

Conditions
ConditionsYield
With sodium hydroxide; tetra-(n-butyl)ammonium iodide In dichloromethane for 4h;100%
dichloromethane
75-09-2

dichloromethane

4-chloro-phenol
106-48-9

4-chloro-phenol

bis(p-chlorophenoxy)methane
555-89-5

bis(p-chlorophenoxy)methane

Conditions
ConditionsYield
With potassium hydroxide; benzyltrimethylammonium chloride In water at 40℃; for 72h;100%
With potassium hydroxide; benzyltrimethylammonium chloride In dichloromethane at 40℃; for 72h;100%
Stage #1: 4-chloro-phenol With sodium hydride In 1-methyl-pyrrolidin-2-one
Stage #2: dichloromethane In 1-methyl-pyrrolidin-2-one at 40℃; for 9h;
98%
With 1-methyl-pyrrolidin-2-one; sodium hydride at 40℃; for 9h;98%
With sodium hydroxide; Amberlite IRA-400 (Cl-) 2.) reflux, 15 h; Yield given. Multistep reaction;
dichloromethane
75-09-2

dichloromethane

phenol
108-95-2

phenol

diphenoxymethane
4442-41-5

diphenoxymethane

Conditions
ConditionsYield
With potassium hydroxide; octopus-type calixarene at 40℃; for 24h; Product distribution; also with substituted phenols; effect of catalysts poly(ethylene glycol)diethyl ether, poly(ethylene glycol), benzyltrimethylammonium chloride, none; also with water solvent;100%
With potassium hydroxide; octopus-type calixarene at 40℃; for 24h;100%
With potassium hydroxide; 5,11,17,23,29,35-Hexa-p-tert-butyl-37,38,39,40,41,42-hexakis-(3,6,9-trioxadecyloxy)calix<6>arene In dichloromethane at 40℃; for 24h;100%
dichloromethane
75-09-2

dichloromethane

(2R,3R)-3-(methylamino)-3-phenyl-1,2-propanediol
313640-98-1

(2R,3R)-3-(methylamino)-3-phenyl-1,2-propanediol

(4R,5R)-3-methyl-4-phenyl-1,3-oxazinan-5-ol

(4R,5R)-3-methyl-4-phenyl-1,3-oxazinan-5-ol

Conditions
ConditionsYield
at 100℃; for 28h; Cyclization;100%
dichloromethane
75-09-2

dichloromethane

benzotriazol-1-ol
2592-95-2

benzotriazol-1-ol

1-chloromethoxy-1H-benzotriazole
3912-23-0

1-chloromethoxy-1H-benzotriazole

Conditions
ConditionsYield
at 55℃;100%
dichloromethane
75-09-2

dichloromethane

diethylamine
109-89-7

diethylamine

2,2-dimethyl-2H-1-benzopyran-6-sulfonyl chloride
185316-64-7

2,2-dimethyl-2H-1-benzopyran-6-sulfonyl chloride

N,N-diethyl-2,2-dimethyl-2H-1-benzopyran-6-sulfonamide
186181-08-8

N,N-diethyl-2,2-dimethyl-2H-1-benzopyran-6-sulfonamide

Conditions
ConditionsYield
In water100%
dichloromethane
75-09-2

dichloromethane

1-(bromomethyl)-4-methyl-2-(phenylmethoxy)benzene
117571-35-4

1-(bromomethyl)-4-methyl-2-(phenylmethoxy)benzene

<4-methyl-2-(phenylmethoxy)phenyl>acetonitrile
117571-36-5

<4-methyl-2-(phenylmethoxy)phenyl>acetonitrile

Conditions
ConditionsYield
With NaCN; tetrabutylammomium bromide In water100%
Nα -Boc-L-ornithine

Nα -Boc-L-ornithine

dichloromethane
75-09-2

dichloromethane

2-fluorobenzonitrile
394-47-8

2-fluorobenzonitrile

(2S)-2-amino-5-(2-cyanophenylamino)pentanoic acid
159877-02-8

(2S)-2-amino-5-(2-cyanophenylamino)pentanoic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide; acetic acid In ethanol; water100%
dichloromethane
75-09-2

dichloromethane

5-Chlorovaleroyl chloride
1575-61-7

5-Chlorovaleroyl chloride

1,4-dihydro-4-(3-aminophenyl)-2,6-dimethyl-3,5-pyridinedicarboxylic acid,dimethyl ester
21835-63-2

1,4-dihydro-4-(3-aminophenyl)-2,6-dimethyl-3,5-pyridinedicarboxylic acid,dimethyl ester

1,4-Dihydro-4-[3-[[5-chloro-1-oxo-1-pentyl]amino]phenyl]-2,6-dimethyl-3,5-pyridinedicarboxylic acid, dimethyl ester

1,4-Dihydro-4-[3-[[5-chloro-1-oxo-1-pentyl]amino]phenyl]-2,6-dimethyl-3,5-pyridinedicarboxylic acid, dimethyl ester

Conditions
ConditionsYield
In tetrahydrofuran; water; ethyl acetate100%
In tetrahydrofuran; water; ethyl acetate100%
In tetrahydrofuran; water; ethyl acetate100%
(CH3)2 AlNH2

(CH3)2 AlNH2

dichloromethane
75-09-2

dichloromethane

2-bromo-5-methoxy-1-(phenylmethyl)-1H-indole-3-acetic acid phenylmethyl ester
163734-89-2

2-bromo-5-methoxy-1-(phenylmethyl)-1H-indole-3-acetic acid phenylmethyl ester

2-bromo-5-methoxy-1-(phenylmethyl)-1H-indole-3-acetamide
164083-06-1

2-bromo-5-methoxy-1-(phenylmethyl)-1H-indole-3-acetamide

Conditions
ConditionsYield
With hydrogenchloride; aluminium In benzene100%
CH3 I

CH3 I

2-carboxy-4-chloroquinoline
15733-82-1

2-carboxy-4-chloroquinoline

dichloromethane
75-09-2

dichloromethane

water
7732-18-5

water

Methyl-4-chloroquinaldate
114935-92-1

Methyl-4-chloroquinaldate

Conditions
ConditionsYield
With NaH In N,N-dimethyl-formamide100%
dichloromethane
75-09-2

dichloromethane

tert-butylamine
75-64-9

tert-butylamine

3,4-diethoxy-3-cyclobuten-1,2-dione
5231-87-8

3,4-diethoxy-3-cyclobuten-1,2-dione

3-(1,1-dimethylethylamino)-4-ethoxy-3-cyclobutene-1,2-dione
186184-26-9

3-(1,1-dimethylethylamino)-4-ethoxy-3-cyclobutene-1,2-dione

Conditions
ConditionsYield
In tetrahydrofuran; methanol100%
dichloromethane
75-09-2

dichloromethane

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

6-(tert-butyloxycarbonylamino)-1-diethylamino-2-hydroxyhexane

6-(tert-butyloxycarbonylamino)-1-diethylamino-2-hydroxyhexane

Conditions
ConditionsYield
100%
5-METHOXY-2-((3,5-DIMETHYL-4-NITRO-2-PYRIDINYL-N-OXIDE)-METHYLTHIO)-1H-BENZIMIDAZOLE
142885-90-3

5-METHOXY-2-((3,5-DIMETHYL-4-NITRO-2-PYRIDINYL-N-OXIDE)-METHYLTHIO)-1H-BENZIMIDAZOLE

dichloromethane
75-09-2

dichloromethane

5-methoxy-2-[[(4-methoxy-3,5-dimethylpyridin-2-yl-1-oxide)methyl]sulfanyl]-1H-benzimidazole
142885-92-5

5-methoxy-2-[[(4-methoxy-3,5-dimethylpyridin-2-yl-1-oxide)methyl]sulfanyl]-1H-benzimidazole

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; sodium methylate In methanol; water100%
methyl α-tert-butoxycarbonylamino-p-carboxymethylphenylacetate
174487-79-7

methyl α-tert-butoxycarbonylamino-p-carboxymethylphenylacetate

dichloromethane
75-09-2

dichloromethane

Methyl α-tert-butoxycarbonylamino-p-methoxycarbonylmethylphenylacetate
174487-81-1

Methyl α-tert-butoxycarbonylamino-p-methoxycarbonylmethylphenylacetate

Conditions
ConditionsYield
100%
chloro(1,5-cyclooctadiene)rhodium(I) dimer

chloro(1,5-cyclooctadiene)rhodium(I) dimer

dichloromethane
75-09-2

dichloromethane

triphenylantimony
603-36-1

triphenylantimony

Rh(C8H12)(Sb(C6H5)3)2Cl*0.5CH2Cl2

Rh(C8H12)(Sb(C6H5)3)2Cl*0.5CH2Cl2

Conditions
ConditionsYield
In ethanol (under Ar, Schlenk); Rh-complex added to refluxing soln. of Sb(C6H5)3 inEtOH; ppt. filtered, washed with CH2Cl2/hexane, dried in vacuo; elem. anal.;100%
dichloromethane
75-09-2

dichloromethane

PdCl((OCH3)2C6H3CHNC6H10NCHC6H2(OCH3)2)

PdCl((OCH3)2C6H3CHNC6H10NCHC6H2(OCH3)2)

silver perchlorate

silver perchlorate

4-nitro-aniline
100-01-6

4-nitro-aniline

Pd(NH2C6H4NO2)((OCH3)2C6H3CHNC6H10NCHC6H2(OCH3)2)(1+)*ClO4(1-)*0.6CH2Cl2=C30H35N4O6PdClO4*0.6CH2Cl2

Pd(NH2C6H4NO2)((OCH3)2C6H3CHNC6H10NCHC6H2(OCH3)2)(1+)*ClO4(1-)*0.6CH2Cl2=C30H35N4O6PdClO4*0.6CH2Cl2

Conditions
ConditionsYield
In acetone byproducts: AgCl; soln. of palladium complex treated with AgClO4 in absence of light; 30 min stirred at room temp.; added to soln. of p-nitroaniline; soln. stirred at room temp. for 30 min; solvent evapd.; oil treated with Et2O; solid pptd.; elem. anal.;100%
dichloromethane
75-09-2

dichloromethane

hh-[(p-tolyl)Pt(μ-2-diphenylphosphinopyridine)2PtMe2](trifluoroacetate)*0.7(methylene chloride)

hh-[(p-tolyl)Pt(μ-2-diphenylphosphinopyridine)2PtMe2](trifluoroacetate)*0.7(methylene chloride)

ht-[(p-tolyl)Pt(μ-2-diphenylphosphinopyridine)2PtMe2](trifluoroacetate)*0.5(methylene chloride)

ht-[(p-tolyl)Pt(μ-2-diphenylphosphinopyridine)2PtMe2](trifluoroacetate)*0.5(methylene chloride)

Conditions
ConditionsYield
In dichloromethane soln. of Pt complex in CH2Cl2 stored at room temp. for 10 d; solvent evapd.; washed with hexane; elem. anal.;100%
sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloromethane
75-09-2

dichloromethane

(C6F5)(C6H5)PC6H4SCH3
486403-20-7

(C6F5)(C6H5)PC6H4SCH3

[(η5-C5(CH3)5RhCl(C6F5)PhPC6H4SMe-2]BF4

[(η5-C5(CH3)5RhCl(C6F5)PhPC6H4SMe-2]BF4

Conditions
ConditionsYield
In not given Atherton, M. J.; Fawcett, J.; Holloway, J. H.; Hope, E. G.; Karacar, A.;Russell, D. R.; Saunders, G. C. J. Chem. Soc., Dalton Trans. 1996, 321 5; elem. anal.;100%
dichloro( 1,5-cyclooctadiene)platinum(ll)
12080-32-9

dichloro( 1,5-cyclooctadiene)platinum(ll)

dichloromethane
75-09-2

dichloromethane

(bromodifluoromethyl)diphenylphosphine
681435-29-0

(bromodifluoromethyl)diphenylphosphine

cis-[PtCl2(κ1-Ph2PCF2Br)2]*(dichloromethane)

cis-[PtCl2(κ1-Ph2PCF2Br)2]*(dichloromethane)

Conditions
ConditionsYield
In dichloromethane by a react. of Ph2PCF2Br with Pt-contg. compd. at 20°C for 0.2 h; elem. anal.;100%
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

dichloromethane
75-09-2

dichloromethane

n-butyl isonitrile
2769-64-4

n-butyl isonitrile

3,5-bis[bis-(4,5-diphenyl-1-methylimidazol-2-yl)methoxymethyl]pyrazole
1032544-28-7

3,5-bis[bis-(4,5-diphenyl-1-methylimidazol-2-yl)methoxymethyl]pyrazole

[(3,5-bis[bis-(4,5-diphenyl-1-methylimidazol-2-yl)methoxymethyl]pyrazole-H)Cu2(n-BuNC)]2(PF6)2*3.8CH2Cl2

[(3,5-bis[bis-(4,5-diphenyl-1-methylimidazol-2-yl)methoxymethyl]pyrazole-H)Cu2(n-BuNC)]2(PF6)2*3.8CH2Cl2

Conditions
ConditionsYield
With KOC(CH3)3 In tetrahydrofuran; acetonitrile (N2, glove box) a soln. of Cu-complex in CH3CN was added to a soln. of pyrazole-compound and KOC(CH3)3 in THF, stirred for 15 min, n-butylisocyanide was added, stirred for 20 min; the solvent was removed in vac., the solid was dissolved in CH2Cl2 and filtered; elem. anal.;100%
trichlorotris(tetrahydrofuran)chromium(III)
10170-68-0, 16997-54-9

trichlorotris(tetrahydrofuran)chromium(III)

dichloromethane
75-09-2

dichloromethane

2,6-bis(1-methylimidazol-2-ylidene)pyridine
1046479-99-5

2,6-bis(1-methylimidazol-2-ylidene)pyridine

[2,6-bis(1-methylimidazol-2-ylidene)pyridine chromium trichloride]*CH2Cl2

[2,6-bis(1-methylimidazol-2-ylidene)pyridine chromium trichloride]*CH2Cl2

Conditions
ConditionsYield
In tetrahydrofuran (N2); std. Schlenk technique; soln. of carbene in THF was slowly added to soln. of Cr complex in THF; stirred for 1 h; filtered; washed (THF, CH2Cl2); dried (vac.); elem. anal.;100%
dichloromethane
75-09-2

dichloromethane

C39H41N3O4
1026988-13-5

C39H41N3O4

C40H43ClN3O4(1+)*Cl(1-)
1026988-19-1

C40H43ClN3O4(1+)*Cl(1-)

Conditions
ConditionsYield
at 25℃; Kinetics;100%
dichloromethane
75-09-2

dichloromethane

Ti(N(CH3)2)2(NC4H3CH2PO(C6H5)2)2

Ti(N(CH3)2)2(NC4H3CH2PO(C6H5)2)2

Ti(N(CH3)2)Cl(NC4H3CH2PO(C6H5)2)2

Ti(N(CH3)2)Cl(NC4H3CH2PO(C6H5)2)2

Conditions
ConditionsYield
In dichloromethane (N2, Schlenk) a soln. of complex in CH2Cl2 allowed to stand for 2 h; volatiles were removed under vac.; elem. anal.;100%
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2
52462-29-0

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2

dichloromethane
75-09-2

dichloromethane

5-diphenylphosphino-17-p-tolyl-25,26,27,28-tetrapropoxycalix[4]arene

5-diphenylphosphino-17-p-tolyl-25,26,27,28-tetrapropoxycalix[4]arene

dichlorido-(η6-cymene)-[5-diphenylphosphino-17-(p-tolyl)-25,26,27,28-tetrapropoxycalix[4]arene]ruthenium(II)*0.5(dichloromethane)

dichlorido-(η6-cymene)-[5-diphenylphosphino-17-(p-tolyl)-25,26,27,28-tetrapropoxycalix[4]arene]ruthenium(II)*0.5(dichloromethane)

Conditions
ConditionsYield
In dichloromethane (under N2, Schlenk); soln. of Ru-complex in CH2Cl2 added dropwise to soln. of ligand in CH2Cl2, stirred for 1 h; concd., hexane added; elem. anal.;100%
1-methyl-1H-imidazole
616-47-7

1-methyl-1H-imidazole

dichloromethane
75-09-2

dichloromethane

1,1′-methylenebis(3-methyl-1H-imidazol-3-ium) dichloride

1,1′-methylenebis(3-methyl-1H-imidazol-3-ium) dichloride

Conditions
ConditionsYield
In chloroform at 60℃; under 14251400 Torr; for 24h; Kinetics; Pressure; Temperature; Menshutkin Reaction; High pressure; Autoclave;100%
for 0.25h; Microwave irradiation; Reflux;48%
at 75℃; for 24h;42.6%
dichloromethane
75-09-2

dichloromethane

C30H24O12
1305346-38-6

C30H24O12

ethylenediamine
107-15-3

ethylenediamine

CH2Cl2*C66H54N6O18(6-)*6Na(1+)

CH2Cl2*C66H54N6O18(6-)*6Na(1+)

Conditions
ConditionsYield
With [D]-sodium hydroxide; sodium acetate In water-d2 for 2h; pD >11;100%
dichloromethane
75-09-2

dichloromethane

trans-bromo(bis(triphenylphosphine))(3-(-)-menthyloxy-3-oxy-1-propinyl)palladium(II)

trans-bromo(bis(triphenylphosphine))(3-(-)-menthyloxy-3-oxy-1-propinyl)palladium(II)

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

trans-(acetonitrile)(3-(-)-menthyloxy-3-oxy-1-propinyl)palladium(II) tetrafluoroborate dichloromethane sesquisolvate

trans-(acetonitrile)(3-(-)-menthyloxy-3-oxy-1-propinyl)palladium(II) tetrafluoroborate dichloromethane sesquisolvate

Conditions
ConditionsYield
In acetonitrile inert atmosphere, Schlenk technique; soln. of Pd-complex in CH3CN treated at -40 °C with (H3C)3OBF4, stirred at -40 °C for 60 min,warmed to room temp., solvent removed (vac.), recrystd. from petroleum ether/CH2Cl2; elem. anal.;100%

75-09-2Relevant articles and documents

Mathai,Le Roy

, p. 189 (1962)

Kinetics and mechanism of the gas phase reaction of atomic chlorine with CH2ICl at 206-432 K

Bilde,Sehested,Nielsen,Wallington,Meagher,McIntosh,Piety,Nicovich,Wine

, p. 8035 - 8041 (1997)

The title reaction was studied using two different experimental techniques: laser flash photolysis with resonance fluorescence detection of Cl atoms and continuous photolysis with FTIR detection of end products. Over the temperature range 206-432 K the rate constant for reaction of Cl atoms with CH2ICl is given (to within ±15%) by the Arrhenius expression k1 = 4.4 × 10-11 exp(195/T) cm3 molecule-1 s-1, which gives k1 = 8.5 × 10-11 cm3 molecule-1 s-1 at 298 K. Variation of the total pressure of N2 diluent over the range 5-700 Torr at 295 K had no discernible (2 the reaction proceeds via iodine transfer to give CH2Cl radicals. As part of this work the rate constant k(CH2Cl+O2+M) was measured at 295 K in the presence of 1-800 Torr of N2 diluent. The results were well described by the Troe expression with a broadening factor Fc of 0.6 and limiting low- and high-pressure rate constants of k0 = (1.8 ± 0.1) × 10-30 cm6 molecule-2 s-1 and k∞ = (3.3 ± 0.3) × 10-12 cm3 molecule-1 s-1. The results are discussed with respect to the available literature for reactions of Cl atoms with halogenated organic compounds and the potential role of the title reaction in atmospheric chemistry.

Chlorodefluorination of Fluoromethanes and Fluoroolefins at a Lewis Acidic Aluminum Fluoride

Braun, Thomas,Pan, Xinzi,Scholz, Gudrun,Talavera, Maria

, (2022/03/27)

Chlorodefluorination reactions of fluoromethanes and fluoroolefins catalysed by the highly Lewis acidic nanoscopic aluminum chlorofluoride (ACF, AlClxF3?x, x≈0.05–0.3) in the presence of ClSiEt3 were studied. Both fluoromethanes and fluoroolefins convert under mild reaction conditions by fluorine-chlorine exchange steps into chlorinated fluoro derivatives. MAS NMR studies provided information on the interaction of silanes and hexafluoropropene with the ACF surface.

Method of Converting a Brominated Hydrocarbon to a Chlorinated Hydrocarbon

-

Paragraph 0183-0186, (2021/02/19)

The present invention provides a method of converting a brominated hydrocarbon to a chlorinated hydrocarbon that involves contacting together the brominated hydrocarbon and a chlorinated ion exchange resin that has a water content of less than or equal to 30 percent by weight, based on the total weight of the chlorinated ion exchange resin and the water. The brominated hydrocarbon includes at least one replaceable bromo group, where each replaceable bromo group is independently covalently bonded to an sp3 hybridized carbon. Contact between the brominated hydrocarbon and the chlorinated ion exchange resin results in replacement of at least one replaceable bromo group of the brominated hydrocarbon with a chloro group, and correspondingly conversion of at least a portion of the brominated hydrocarbon to the chlorinated hydrocarbon.

A process of preparing methyl chloride using multistage reaction

-

Paragraph 0092-0100; 0112; 0120, (2020/06/10)

The present invention relates to a method of producing methyl chloride by multistage reactions. The method of the present invention comprises: a) a chlorination step for sufficiently increasing the conversion rate of methane, which is an initial reactant; and b) a subsequent reaction step for actively utilizing hydrogen chloride (HCl), which is a hazardous byproduct of chlorination, efficiently treating harmful hydrogen chloride, and at the same time, improving the overall production of methyl chloride.COPYRIGHT KIPO 2020

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 75-09-2