105560-21-2

Upstream product

• 103902-93-8 (CO)3[(C₆H₅)2PCH₂CH₂P(C₆H₅)2]Mn[CCC(CH₃)3] 
• 56-93-9 benzyltrimethylammonium chloride 

Downstream Products

• 105560-20-1 [(CO)3(((C₆H₅)2PCH₂)2)Mn(CCC(CH₃)3)]Cu[P(C₆H₄CH₃)3]⁽¹⁺⁾*PF₆^(1-)=[((CO)3(((C₆H₅)2PCH₂)2)Mn(C₆H₉))Cu(PC₂₁H₂₁)]PF₆ 
• 105560-20-1 [MnCu(C₂C(CH₃)3)(CO)3((CH₂P(C₆H₅)2)2)(P(C₆H₄CH₃)3)]⁽¹⁺⁾*PF₆^(1-)=[MnCu(C₂C(CH₃)3)(CO)3((CH₂P(C₆H₅)2)2)(P(C₆H₄CH₃)3)]PF₆ 

Relevant academic research and scientific papers

?-Alkynyl Complexes of Manganese(I) as η2-Bonding Ligands for Group 1B Metal-Ligand Fragments. X-Ray Crystal Structure of t)2(CO)6(dppe)2>PF6*0.5CH2Cl2

Several compounds of the types (n=1; M=Cu, Ag, or Au); R=CH2OMe, But, or Ph; dppe=Ph2PCH2CH2PPh2> and have been prepared from the alkynyl complexes fac- and the appropriate reagents to generate the metal-ligand fragments Ml.The salt has been characterized by X-ray diffraction. several equilibri in solution involving the cationic species with free ?-alkynyl complex and P(C6H4Me-2)3 have been observed and their reactions with Cl(1-) have been examined.

?-ALKYNYL COMPLEXES OF MANGANESE(I) AS LIGANDS. SYNTHESIS AND X-RAY STRUCTURE OF 2-ButC2Mn(CO)3(dppe)>2Cu>(PF6)

The syntheses of complexes of the Group IB metals with η2-bonded ?-alkynyl compounds of manganese(I) are described.The structre of the salt 2-ButC2Mn(CO)3(dppe)>2Cu>(PF6)*1/2Cl2CH2 (dppe = 1,2-bis(diphenylphosphino)etha