103902-93-8

Upstream product

• 56-93-9 benzyltrimethylammonium chloride 
• 14104-20-2 silver tetrafluoroborate 
• 37523-64-1 fac-[bromo(1,2-bis(diphenylphosphino)ethane)tricarbonylmanganese(I)] 
• 917-92-0 3,3-Dimethylbut-1-yne 

Downstream Products

• 49695-20-7 fac-Mn(CO)3(chloro)(1,2-bis(diphenylphosphino)ethane) 
• 105560-09-6 [MnAu(C₂C(CH₃)3)(CO)3((CH₂P(C₆H₅)2)2)(P(C₆H₄CH₃)3)]⁽¹⁺⁾*PF₆^(1-)=[MnAu(C₂C(CH₃)3)(CO)3((CH₂P(C₆H₅)2)2)(P(C₆H₄CH₃)3)]PF₆ 
• 105560-21-2 [MnCuCl(C₂C(CH₃)3)(CO)3((CH₂P(C₆H₅)2)2)] 
• 105560-21-2 [(CO)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)Mn(CCC(CH₃)3)]CuCl 
• 105560-10-9 [(CO)3(((C₆H₅)2PCH₂)2)Mn(CCC(CH₃)3)]Ag[P(C₆H₄CH₃)3]⁽¹⁺⁾ 
• 105560-08-5 [(CO)3(((C₆H₅)2PCH₂)2)Mn(CCC(CH₃)3)]Au[P(C₆H₄CH₃)3]⁽¹⁺⁾ 
• 116746-44-2 [MnAu(C₆F₅)(C₂C(CH₃)3)(CO)3((CH₂P(C₆H₅)2)2)] 
• 116837-72-0 [MnAg(C₂C(CH₃)3)(CO)3((CH₂P(C₆H₅)2)2)(P(C₆H₄CH₃)3)]⁽¹⁺⁾*BF₄^(1-)=[MnAg(C₂C(CH₃)3)(CO)3((CH₂P(C₆H₅)2)2)(P(C₆H₄CH₃)3)]BF₄ 

Relevant academic research and scientific papers

?-Alkynyl Complexes of Manganese(I) as η2-Bonding Ligands for Group 1B Metal-Ligand Fragments. X-Ray Crystal Structure of t)2(CO)6(dppe)2>PF6*0.5CH2Cl2

Several compounds of the types (n=1; M=Cu, Ag, or Au); R=CH2OMe, But, or Ph; dppe=Ph2PCH2CH2PPh2> and have been prepared from the alkynyl complexes fac- and the appropriate reagents to generate the metal-ligand fragments Ml.The salt has been characterized by X-ray diffraction. several equilibri in solution involving the cationic species with free ?-alkynyl complex and P(C6H4Me-2)3 have been observed and their reactions with Cl(1-) have been examined.

SYNTHESIS OF MANGANESE(I) CARBONYLS WITH ?-BONDED ALKYNYL LIGANDS

A number of ?-alkynylcarbonyl complexes of manganese(I), 5-n(CCR)>, have been obtained from bromocarbonyl complexes 5-nBr> by treatment with silver(I) or copper(I) acetylides, and from perchlorato complexes 5-n(OClO3)> by treatment with 1-alkyne and base.New ?-alkynyl compounds can also be obtained from other alkynyl complexes by reactions involving replacement of CO ligands.