105584-71-2Relevant articles and documents
Synthesis and Chemical Behaviour of Thioacylsilanes (Silyl Thioketones). Part 1. Oxidation to S-Oxides, Conversion into Silylated Thiiranes, Silylated Triarylethylenes, and α-Silylated Sulphides
Barbaro, Gaetano,Battaglia, Arturo,Giorgianni, Patrizia,Maccagnani, Gaetano,Macciantelli, Dante,et al.
, p. 381 - 386 (2007/10/02)
Trimethylsilyl and triphenylsilylaryl thioketones have been synthesized by acid catalysed reaction of the corresponding ketones with hydrogen sulphide.Such silylated thioketones heve been oxidized to give S-oxides and converted with diaryldiazomethanes into triaryl thiiranes; upon treatment with organolithium nucleophiles they undergo thiophilic addition.The ready desulphurization with triphenylphosphine of silylated thiirans to the corresponding silyl triaryl ethylenes is also reported.
Synthesis and Isolation of Aryl Thioaldehyde S-Oxides
Bonini, Bianca F.,Mazzanti, Germana,Zani, Paolo,Maccagnani, Gaetano,Barbaro, Gaetano,et al.
, p. 964 - 965 (2007/10/02)
(E)-Phenyl and (E)-(p-tolyl) trimethylsilyl thioketone S-oxides can be easily and stereospecifically protodesilylated into the corresponding (Z)-aryl thioaldehyde S-oxides; these stable liquid lachrimatory compounds show good reactivity as heterodienophil