105590-45-2

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 555-16-8 4-nitrobenzaldehdye 
• 57341-99-8 1-(3,3-dimethylbut-1-ynyl)-4-nitrobenzene 
• 3840-71-9 2-acetoxy-3,3-dimethyl-but-1-ene 
• 100-01-6 4-nitro-aniline 
• 105590-49-6 1-Hydroxy-2,2,4-trimethyl-1-(4-nitro-phenyl)-pentan-3-one 
• 105590-52-1 5-hydroxy-2,2-dimethyl-5-(4-nitrophenyl)pentan-3-one 
• 619-73-8 4-nitrobenzyl chloride 

Relevant academic research and scientific papers

Ring size and nothing else matters: unusual regioselectivity of alkyne hydration by NHC gold(i) complexes

We have investigated the role of ring sizes and substituents in NHC ligands in some (NHC)Au(i) complexes in the hydration of internal alkynes. Despite the fact that using (NHC)Au(i) complexes in the hydration of diarylacetylenes leads to Markovnikov-type products, the precise tuning of ligands allows changing the regioselectivity in arylalkylacetylene hydration to the anti-Markovnikov-type.

Visible-light-mediated α-arylation of enol acetates using aryl diazonium salts

Visible light mediates efficiently the α-arylation of enol acetates by aryl diazonium salts under mild conditions using [Ru(bpy)3]Cl 2 as a photoredox catalyst. The broad scope of the reaction toward various diazonium salts and enol acetates was explored. The application of this reaction in the concise synthesis of 2-substituted indoles was demonstrated

A NOVEL NUCLEOPHILIC SUBSTITUTION OF THE FORMYL GROUP IN p-NITROBENZALDEHYDE WITH SOME CARBANIONS

p-Nitrobenzaldehyde reacts with some active methylene compounds in the presence of a strong base at low temperatures to give p-substituted nitrobenzenes by the two-step course involving the initial formation of the aldol adducts and the subsequent displacement of the carbinol moieties with excess carbanions.