105592-08-3Relevant academic research and scientific papers
A STABLE 1:1 LITHIUM ACYLCYANOCUPRATE. DEPENDENCE OF THE STABILITY OF ACYLCYANOCUPRATES ON THE NATURE OF THE ALKYL SUBSTITUENT.
Seyfert, Dietmar,Hui, Richard C.
, p. 1473 - 1476 (1986)
Acylcuprates obtained by carbonylation of R(CN)CuLi cuprates (R=t-Bu, sec-Bu) at low temperature are effective in the direct nucleophilic 1,4-acylation of α,β-unsaturated ketones and aldehydes.The R=t-Bu reagent is sufficiently stable so that it can be us
One-Step Synthesis of 1,4-Diketones by Nucleophilic Reaction to Tricarbonyl Complexes of α,β-Unsaturated Ketones
Kitahara, Haruo,Tozawa, Yasuyuki,Fujita, Seikou,Tajiri, Akio,Morita, Noboru,Asao, Toyonobu
, p. 3362 - 3364 (2007/10/02)
Tricarbonyliron complexes of 3-buten-2-one, 3-penten-2-one, and 4-phenyl-3-buten-2-one reacted with organolithium and Grignard reagents to afford 1,4-diketones in one step, some of the products are amenable to convertion to natural products.
