Tetrahedron Letters p. 1473 - 1476 (1986)
Update date:2022-08-16
Topics:
Seyfert, Dietmar
Hui, Richard C.
Acylcuprates obtained by carbonylation of R(CN)CuLi cuprates (R=t-Bu, sec-Bu) at low temperature are effective in the direct nucleophilic 1,4-acylation of α,β-unsaturated ketones and aldehydes.The R=t-Bu reagent is sufficiently stable so that it can be us
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