105615-49-4Relevant articles and documents
THE HIGHLY STEREOSELECTIVE SYNTHESIS OF ALL-TRANS AND 13-CIS VITAMIN A VIA DOUBLE ELIMINATION REACTION
Otera, Junzo,Misawa, Hiromitsu,Mandai, Tadakatsu,Onishi, Takashi,Suzuki, Shigeaki,Fujita, Yoshiji
, p. 1883 - 1886 (1985)
Stereocontrolled convergent synthesis of vitamin A was achieved by the double elimination method employing the C10 sulfone and the C10 aldehydes as starting materials.Thus the all-trans and 13-cis isomers were obtained with the stereochemical purity of 95percent and 90percent, respectively.