105618-29-9Relevant articles and documents
Constructing a self-assembling C3-symmetric covalently linked (fused) donor-acceptor-type molecule containing a hexaazatriphenylene core
Bhanvadia, Viraj J.,Patel, Arun L.,Zade, Sanjio S.
, p. 17700 - 17707 (2018/11/01)
A C3-symmetric covalently linked (fused) molecule, HAT-IPN, comprising a 13 fused ring system was synthesized by a condensation-cyclisation reaction between hexaazatriphenylenehexacarboxylic acid trisanhydride and 4,5-diamino-1,2-dioctyloxybenzene. This fused system exhibits ambipolar behaviour due to an n-type HAT-core at the center and three outer p-type fused dialkoxybenzimidazole moieties, which is confirmed by cyclic voltammetry. The self-assembling nature of this disc-shaped donor-acceptor type system is evident in13C NMR spectroscopy, dynamic light scattering studies, differential scanning calorimetry and atomic force microscopy (AFM) images, which illustrate the formation of the one-dimensional aggregates both in solution and in the film state; indicating its potential as an active component in organic electronic devices.
Synthesis and Some Reactions of Hexaazatriphenylenehexacarbonitrile, a Hydrogen-Free Polyfunctional Heterocycle with D3h Symmetry
Kanakarajan, K.,Czarnik, Anthony W.
, p. 5241 - 5243 (2007/10/02)
In this paper, we report for the first time the synthesis of hexaazatriphenylenehexacarbonitrile, abbreviated HAT-hexacarbonitrile.This hydrogenless, symmetrically branched compound can be prepared in analytically pure form on a large scale by using commercially available starting materials.The conversions of HAT-hexacarbonitrile to the corresponding hexaamide, hexaacid, hexaester, and trianhydride derivatives were also accomplished.
