105643-70-7Relevant academic research and scientific papers
Chemical Deoxygenation of the Trichothecenes Diacetoxyscirpenol and Deoxynivalenol
Cameron, Stuart,Colvin, Ernest W.
, p. 365 - 370 (2007/10/02)
Based on a model study using the bicyclooctane epoxy acetates (14) and (15), an efficient one-step procedure for the selective removal of the 12,13-epoxide ring of the trichothecene mycotoxins diacetoxyscirpenol (1; R=H) and deoxynivalenol (2; R=H) has been devised.The key to success proved to be use of the lower-valent tungsten deoxygenation system of Sharpless et al.
