1056451-68-3Relevant academic research and scientific papers
Red phosphorescent compound, and organic electroluminescent device using same
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Paragraph 0061-0063, (2019/11/29)
The invention discloses a red phosphorescent compound, and an organic electroluminescence device using the same. The organic electroluminescent device comprises an anode, a hole injection layer, a hole transporting layer, a luminescent layer, an electron
Red light metal complex, preparation method and application thereof
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Paragraph 0103-0105, (2019/01/15)
The invention belongs to the field of organic electroluminescence materials, and discloses a red light metal complex formed by using an alkyl-substituted phenylisoquinoline derivative as a main ligand, a preparation method and an application thereof. Different alkyl substituents are introduced on the main ligand, purification and sublimation yields of a material are remarkably improved, so using cost of the material is effectively reduced, and it is extremely beneficial to industrial production. In addition, because of the steric-hindrance effect of an increased alkyl chain, steric hindrance of molecules is enhanced, so a luminescence quenching situation is relieved, and luminous efficiency is improved.
Novel Organic Light Emitting Materials
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Page/Page column, (2013/06/27)
Novel phosphorescent metal complexes containing 2-phenylisoquinoline ligands with at least two substituents on the isoquinoline ring are provided. The disclosed compounds have low sublimation temperatures that allow for ease of purification and fabrication into a variety of OLED devices.
TMEDA-assisted effective direct ortho arylation of electron-deficient N -heteroarenes with aromatic grignard reagents
Zhuo, Fang-Fang,Xie, Wen-Wen,Yang, Yong-Xin,Zhang, Lei,Wang, Pei,Yuan, Rui,Da, Chao-Shan
, p. 3243 - 3249 (2013/06/26)
In the addition of TMEDA in toluene, aryl Grignards could effectively and site-specifically ortho-arylate electron-deficient heteroarenes under mild conditions. This endeavor successfully changed the old low-yielding reaction, aryl Grignard addition to N-heteroarenes, into an efficient procedure for heterobiaryls. The combination of the inexpensive aryl Grignards, TMEDA, the cost-free air, no use of any transition-metal catalyst, the mild reaction conditions, and the high-yielding gram-scale results enables this new procedure to be cost-effective and potentially utilizable in industry.
