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2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
Cas No: 657408-07-6
No Data No Data Metric Ton/Day Beijing Greenchem Technology Co.,Ltd.(Qingdao Greenchem international Trading Co.,Ltd) Contact Supplier
Large qty in stock SPhos CAS No. 657408-07-6 National Research Platform ISO 9001
Cas No: 657408-07-6
No Data 1 Kilogram 200 Kilogram/Month Zhengzhou Kingorgchem Chemical Technology Co., Ltd. Contact Supplier
2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl 99% Sphos
Cas No: 657408-07-6
No Data 1 Gram 100 Kilogram/Month Shanghai Siwei Chemical Co., Ltd Contact Supplier
Manufacturer Top Supplier SPhos CAS No. 657408-07-6 high quality good price
Cas No: 657408-07-6
No Data 1 Kilogram Metric Ton/Day Nantong XinHe Biotech Co., Ltd Contact Supplier
2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
Cas No: 657408-07-6
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
Cas No: 657408-07-6
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
2-Dicyclohexylphosphino-2,6-dimethoxybiphenyl
Cas No: 657408-07-6
USD $ 2.0-2.0 / Kilogram 1 Kilogram 100 Kilogram/Month GIHI CHEMICALS CO.,LIMITED Contact Supplier
2-dicyclohexylPhosphino-2',6'-dimethoxybiphenyl
Cas No: 657408-07-6
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
Cas No: 657408-07-6
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
CHemwill -- 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
Cas No: 657408-07-6
USD $ 1.0-1.0 / Metric Ton 1 Metric Ton 5 Metric Ton/Day Chemwill Asia Co., Ltd. Contact Supplier

657408-07-6 Usage

Chemical Properties

White solid

Reactions

  1. Ligand/palladium catalyst for general Suzuki-Miyaura cross-coupling reactions.
  2. Ligand/palladium catalyst for the Suzuki-Miyaura coupling of aryltrifluoroborates with aryl chlorides.
  3. Ligand/palladium catalyst for the Suzuki-Miyaura reaction of heteroaryl halides and heteroaryl boronic acids and esters.
  4. Ligand/palladium catalyst for the Kumada-Corriu cross-coupling reaction.
  5. Ligand/palladium catalyst for the borylation of aryl halides with pinacol borane.
  6. Suzuki couplings involving amino acids. Synthesis of biaryl derivatives of 4-hydroxyphenyl glycine, tyrosine and tryptophan.
  7. Synthesis of substituted adamantylzinc reagents using Mg-insertion in the presence of zinc chloride.
  8. Highly efficient catalyst for the palladium-catalyzed Suzuki-Miyura reaction of heteroaryl halides and heteroaryl boronic acids
  9. and esters.

Uses

suzuki reaction

657408-07-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (638072)  SPhos  97% 657408-07-6 638072-500G 66,149.46CNY Detail
Aldrich (638072)  SPhos  97% 657408-07-6 638072-100G 43,199.91CNY Detail
Aldrich (638072)  SPhos  97% 657408-07-6 638072-25G 13,364.91CNY Detail
Aldrich (638072)  SPhos  97% 657408-07-6 638072-5G 4,015.44CNY Detail
Aldrich (638072)  SPhos  97% 657408-07-6 638072-1G 898.56CNY Detail
Aldrich (685585)  S-Phos,ChemDosetablets  Loading: 2μmol per tablet 657408-07-6 685585-100TAB 6,382.35CNY Detail
Aldrich (685585)  S-Phos,ChemDosetablets  Loading: 2μmol per tablet 657408-07-6 685585-10TAB 1,071.72CNY Detail

657408-07-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Dicyclohexylphosphino-2’,6’-dimethoxybiphenyl

1.2 Other means of identification

Product number -
Other names dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:657408-07-6 SDS

657408-07-6Synthetic route

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

2'-bromo-2,6-dimethoxybiphenyl
755017-61-9

2'-bromo-2,6-dimethoxybiphenyl

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Stage #1: 2'-bromo-2,6-dimethoxybiphenyl With n-butyllithium In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere; Cooling with acetone-dry ice;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran at 20 - 45℃; Inert atmosphere;
88%
Stage #1: 2'-bromo-2,6-dimethoxybiphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at -78 - 20℃;
3.32 g
2-bromo-1-chlorobenzene
694-80-4

2-bromo-1-chlorobenzene

1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Stage #1: 1,3-Dimethoxybenzene With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 3.5h;
Stage #2: 2-bromo-1-chlorobenzene In tetrahydrofuran at 0℃; for 0.5h;
Stage #3: chlorodicyclohexylphosphane
36%
(2’,6’-dimethoxy-[1,1’-biphenyl]-2-yl)dicyclohexylphosphine oxide

(2’,6’-dimethoxy-[1,1’-biphenyl]-2-yl)dicyclohexylphosphine oxide

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
With 1,3-diphenyl-disiloxane In toluene at 110℃; Sealed tube; chemoselective reaction;87%
2'-chloro-2,6-dimethoxy-1,1'-biphenyl
1380028-15-8

2'-chloro-2,6-dimethoxy-1,1'-biphenyl

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Stage #1: 2'-chloro-2,6-dimethoxy-1,1'-biphenyl With sec.-butyllithium In diethyl ether; cyclohexane at -78 - -45℃; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In diethyl ether; cyclohexane at -78℃; Inert atmosphere;
48%
2-bromo-1-chlorobenzene
694-80-4

2-bromo-1-chlorobenzene

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran; hexane / 5 h / 0 - 20 °C
1.2: 81 percent / tetrahydrofuran; hexane / 0.25 h / 0 °C
2.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C
2.2: 3.32 g / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

4-methoxy-trans(?)-cinnamic acid

4-methoxy-trans(?)-cinnamic acid

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran; hexane / 5 h / 0 - 20 °C
1.2: 81 percent / tetrahydrofuran; hexane / 0.25 h / 0 °C
2.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C
2.2: 3.32 g / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
potassium phosphate

potassium phosphate

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(2,6-dimethoxyphenyl)boronic acid
23112-96-1

(2,6-dimethoxyphenyl)boronic acid

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane / toluene / 70 °C / Inert atmosphere
2.1: sec.-butyllithium / diethyl ether; cyclohexane / -78 - -45 °C / Inert atmosphere
2.2: -78 °C / Inert atmosphere
View Scheme
1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 2,2,6,6-tetramethylpiperidinyl-lithium / diethyl ether; tetrahydrofuran / 36 h / -45 °C / Inert atmosphere; Sealed tube
2: diethyl ether / -78 °C / Inert atmosphere; Sealed tube
View Scheme
chlorobenzene
108-90-7

chlorobenzene

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 2,2,6,6-tetramethylpiperidinyl-lithium / diethyl ether; tetrahydrofuran / 36 h / -45 °C / Inert atmosphere; Sealed tube
2: diethyl ether / -78 °C / Inert atmosphere; Sealed tube
View Scheme
2,6-dimethoxybiphenyl
13732-86-0

2,6-dimethoxybiphenyl

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
In diethyl ether at -78℃; Inert atmosphere; Sealed tube;1.3 g
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(tetrahydrothiophene)gold(I) chloride
39929-21-0

(tetrahydrothiophene)gold(I) chloride

chloro(dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine)gold(I)
854045-95-7

chloro(dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine)gold(I)

Conditions
ConditionsYield
In dichloromethane for 1.75h;100%
In dichloromethane at 20℃; for 1h; Darkness;
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate

sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate

Conditions
ConditionsYield
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane With sulfuric acid In dichloromethane at 0 - 40℃; for 24h;
Stage #2: With sodium hydroxide In dichloromethane; water at 0℃; pH=~ 7.0; Cooling with ice;
99%
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane With sulfuric acid In dichloromethane at 20℃; for 1h; Sealed tube;
Stage #2: With sodium hydroxide In dichloromethane; water at 20℃; for 0.25h; pH=14; Sealed tube; Cooling with ice; regioselective reaction;
85%
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane With sulfuric acid In dichloromethane at 0 - 40℃; for 24.7h; Inert atmosphere;
Stage #2: With sodium hydroxide In dichloromethane; water at 0℃; pH=13;
62%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

Pd(π-cinnamyl)(SPhos)Cl

Pd(π-cinnamyl)(SPhos)Cl

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Schlenk technique; Inert atmosphere;99%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

[Pd(μ-Cl)(Cl)(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)]2

[Pd(μ-Cl)(Cl)(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)]2

[PdCl2(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(PCy2-(2',6'-oMe2-2-byphenyl))]

[PdCl2(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(PCy2-(2',6'-oMe2-2-byphenyl))]

Conditions
ConditionsYield
In tetrahydrofuran for 3h; Schlenk technique; Inert atmosphere; Glovebox;98%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis(η3-allyl-μ-chloropalladium(II))

bis(η3-allyl-μ-chloropalladium(II))

Pd(π-allyl)(SPhos)Cl

Pd(π-allyl)(SPhos)Cl

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h; Schlenk technique; Inert atmosphere;98%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis(acetonitrile)(acetylacetonate)palladium(II) tetrafluoroborate

bis(acetonitrile)(acetylacetonate)palladium(II) tetrafluoroborate

(acetylacetonate-κ2O,O')(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl-κP)palladium(II) tetrafluoroborate

(acetylacetonate-κ2O,O')(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl-κP)palladium(II) tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;97.3%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

hydrogen tetrachloroaurate(III) tetrahydrate

hydrogen tetrachloroaurate(III) tetrahydrate

chloro(dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine)gold(I)
854045-95-7

chloro(dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine)gold(I)

Conditions
ConditionsYield
Stage #1: hydrogen tetrachloroaurate(III) tetrahydrate With propyl sulfide In ethanol at 40℃; for 0.166667h;
Stage #2: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane In ethanol at 40℃; for 1h;
97%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C12H10ClNPd

C12H10ClNPd

2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl

2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Conditions
ConditionsYield
In acetone at 25℃;96%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

4-chloro-2-(dibenzo[b,d]furan-4-yl)pyridine
1429471-42-0

4-chloro-2-(dibenzo[b,d]furan-4-yl)pyridine

2-isopropenyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
126726-62-3

2-isopropenyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

2-(dibenzo[b,d]furan-4-yl)-4-(prop-1-en-2-yl)pyridine
1421361-86-5

2-(dibenzo[b,d]furan-4-yl)-4-(prop-1-en-2-yl)pyridine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In water; ethyl acetate; toluene96%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

dihydrogen tetrachloropalladate(II)

dihydrogen tetrachloropalladate(II)

lithium bromide
7550-35-8

lithium bromide

[HSPhos]2[Pd2Br6]

[HSPhos]2[Pd2Br6]

Conditions
ConditionsYield
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; dihydrogen tetrachloropalladate(II) In acetone at 18 - 27℃; for 0.5h;
Stage #2: lithium bromide In water; acetone
96%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C26H35O8PS2

C26H35O8PS2

Conditions
ConditionsYield
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane With sulfuric acid In dichloromethane for 1.5h; Sealed tube;
Stage #2: With fuming sulphuric acid In dichloromethane at 0 - 20℃; for 0.533333h; Sealed tube; regioselective reaction;
96%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Dihydroxy-isobutyl-boran
84110-40-7

Dihydroxy-isobutyl-boran

5,7-dichloro isoquinoline
73075-58-8

5,7-dichloro isoquinoline

5,7-diisobutylisoquinoline
1443013-08-8

5,7-diisobutylisoquinoline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In hexane; water; toluene95%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

2-bromo-3-methylaniline
54879-20-8

2-bromo-3-methylaniline

1-methylphenanthridin-6-amine
1859-17-2

1-methylphenanthridin-6-amine

Conditions
ConditionsYield
With nitrogen In tetrahydrofuran; methanol; dichloromethane95%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

2-(2-chlorophenyl)ethanamine
13078-80-3

2-(2-chlorophenyl)ethanamine

chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)
1028206-58-7

chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)

Conditions
ConditionsYield
In further solvent(s) treatment of palladium compd. with chlorobenzene deriv. and phosphine deriv. in methyl tert-butyl ether at 55°C; recrystn.;94%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis(1,5-cyclooctadiene)diiridium(I) dichloride
12112-67-3

bis(1,5-cyclooctadiene)diiridium(I) dichloride

[IrCl(COD)(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)]
1268489-06-0

[IrCl(COD)(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)]

Conditions
ConditionsYield
In toluene under Ar atm. using Schlenk techniques; mixt. of Ir complex and ligand in dry toluene was stirred at room temp. for 3 h; solvent evapd.; cold hexane added; suspn. filtered; washed (cold hexane); elem. anal.;94%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

4-dibenzothiophene boronic acid
108847-20-7

4-dibenzothiophene boronic acid

3-(dibenzo[b,d]thiophen-4-yl)-9-phenyl-9H-carbazole

3-(dibenzo[b,d]thiophen-4-yl)-9-phenyl-9H-carbazole

Conditions
ConditionsYield
94%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer
1435520-65-2

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer

C26H35O2P*C13H13NO3PdS
1445085-82-4

C26H35O2P*C13H13NO3PdS

Conditions
ConditionsYield
In tetrahydrofuran at 20℃;93%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II)
225931-80-6

bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II)

para-chlorotoluene
106-43-4

para-chlorotoluene

C33H42ClO2PPd

C33H42ClO2PPd

Conditions
ConditionsYield
In cyclohexane at 20℃; for 18h; Inert atmosphere; Glovebox;93%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C16H20I2N2Pd2

C16H20I2N2Pd2

C34H45INO2PPd

C34H45INO2PPd

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h;93%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

dihydrogen tetrachloropalladate(II)

dihydrogen tetrachloropalladate(II)

[HSPhos]2[Pd2Cl6]

[HSPhos]2[Pd2Cl6]

Conditions
ConditionsYield
In acetone at 18 - 27℃; for 1.16667h;93%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

N-phenyl-2-aminobiphenylpalladium methanesulfonate
1599466-80-4

N-phenyl-2-aminobiphenylpalladium methanesulfonate

C45H52NO5PPdS
1599466-88-2

C45H52NO5PPdS

Conditions
ConditionsYield
In dichloromethane at 20℃; for 1h;92%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis(pentafluorophenyl)(1,5-cyclo-octadiene)palladium(II)
105286-78-0

bis(pentafluorophenyl)(1,5-cyclo-octadiene)palladium(II)

C38H35F10O2PPd

C38H35F10O2PPd

Conditions
ConditionsYield
In dichloromethane at 20℃; for 48h; Inert atmosphere;92%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C20H24I2N2O4Pd2

C20H24I2N2O4Pd2

C36H47INO4PPd

C36H47INO4PPd

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h;92%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

[Pd2(CH3CN)6][BF4]2

[Pd2(CH3CN)6][BF4]2

C52H70O4P2Pd2(2+)*2BF4(1-)

C52H70O4P2Pd2(2+)*2BF4(1-)

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.00166667h; Time;91%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(2’,6’-dimethoxy-[1,1’-biphenyl]-2-yl)dicyclohexylphosphine oxide

(2’,6’-dimethoxy-[1,1’-biphenyl]-2-yl)dicyclohexylphosphine oxide

Conditions
ConditionsYield
With dihydrogen peroxide In dichloromethane90%
With oxygen In toluene at 20℃; Product distribution; Further Variations:; Reagents; Temperatures;
With dihydrogen peroxide In diethyl ether at 30℃; for 16h;
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Dihydroxy-isobutyl-boran
84110-40-7

Dihydroxy-isobutyl-boran

4,6-dichloro-1-(3,5-dimethylphenyl)isoquinoline
1443013-16-8

4,6-dichloro-1-(3,5-dimethylphenyl)isoquinoline

1-(3,5-dimethylphenyl)isoquinoline
1056451-68-3

1-(3,5-dimethylphenyl)isoquinoline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In dichloromethane; water; ethyl acetate; toluene90%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C22H18Cl2N4O2Pd2

C22H18Cl2N4O2Pd2

C37H44ClN2O3PPd

C37H44ClN2O3PPd

Conditions
ConditionsYield
In acetone at 20℃; for 0.5h;90%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

ruthenium trichloride

ruthenium trichloride

C53H46CuN4OP2(1+)*BF4(1-)

C53H46CuN4OP2(1+)*BF4(1-)

C105H115Cl2CuN4O5P4Ru(1+)*BF4(1-)

C105H115Cl2CuN4O5P4Ru(1+)*BF4(1-)

Conditions
ConditionsYield
With sodium acetate In ethanol at 80℃; for 30h; Inert atmosphere;89%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)2Cl2
848652-20-0

Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)2Cl2

Conditions
ConditionsYield
In dichloromethane mixt. ligand and (CH3CN)2PdCl2 in CH2Cl2 was stirred; flash chromy. on silica;88%

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