1056475-42-3Relevant academic research and scientific papers
Development of an arylthiobismuthine cocatalyst in organobismuthine- mediated living radical polymerization: Applications for synthesis of ultrahigh molecular weight polystyrenes and polyacrylates
Kayahara, Eiichi,Yamago, Shigeru
, p. 2508 - 2513 (2009/07/26)
Diphenyl(2,6-dimesitylphenylthio)bismuthine (1a) serves as an excellent cocatalyst in organo-bismuthine-mediated living radical polymerization (BIRP). Both low and high molecular weight polystyrenes and poly(butyl acrylate)s (PBAs) with controlled molecul
LIVING RADICAL POLYMERIZATION PROMOTER
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Page/Page column 15, (2009/12/27)
An organobismuth compound represented by the formula (1) and a method for preparing a living radical polymer using the organobismuth compound. In the formula (1), R1 to R3 each represent a C1-C8 alkyl group, an aryl group, a substituted aryl group, an aromatic heterocyclic group or a group represented by the formula (2) where at least one of R1 to R3 is a group represented by the formula (2), wherein R4 and R5 each represent a C3-C8 alkyl group, an aryl group or a substituted aryl group, and R6 to R8 each represent a hydrogen atom, a C1-C8 alkyl group, an aryl group or a substituted aryl group.
