157590-41-5

Downstream Products

• 1119944-29-4 Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine) 
• 1056475-42-3 diphenyl(2,6-dimesitylphenylthio)bismuthine 
• 1234175-91-7 Fe2(mesityl)2(μ-S-2,6-dimesitylphenyl)(μ-mesityl) 
• 1256639-70-9 Ph₂PC₆H₄-2-C(O)SC₆H₃-2,6-(C₆H₂-2,4,6-Me₃)2 
• 1420299-78-0 [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido(trimethylphosphine)ruthenium(II) 
• 1170310-03-8 [2,6-η6:η1-Bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido(triethylphosphine)ruthenium(II) 
• 1420299-84-8 [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II) 
• 1170310-30-1 [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido(triphenylphosphine)ruthenium(II) 
• 1420299-81-5 [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido(diphenylmethylphosphine)ruthenium(II) 

Relevant academic research and scientific papers

Synthesis of coordinatively unsaturated mesityliron thiolate complexes and their reactions with elemental sulfur

The reactions of Fe2Mes4 (1; Mes = mesityl) with bulky thiols, namely, HSDmp (Dmp = 2,6-dimesitylphenyl), HSDxp (Dxp = 2,6-dixylylphenyl), and HSBtip [Btip = 2,6-(2,4,6-iPr 3C6H2)2C6H3], provided a series of iron(II) mesityl complexes bearing bulky thiolate ligands. These iron complexes are the thiolate-bridged dinuclear complexes Fe 2Mes2(μ-SAr)(μ-Mes) (2a, Ar = Dmp; 2b, Ar = Dxp), the 1,2-dimethoxyethane (DME) adducts (DME)Fe(SAr)(Mes) (3a, Ar = Dmp; 3b, Ar = Dxp), the mixed-valence FeI?FeII dinuclear complexes (Mes)Fe(μ-SAr)(μ-SAr)Fe (4a, Ar = Dmp; 4b, Ar = Dxp), and a low-coordinate mononuclear complex (BtipS)Fe(Mes) (5). An [Fe8S7] cluster [Fe4S3(SDmp)]2(μ-SDmp) 2(μ-SMes)(μ6-S) (6), the core structure of which is topologically relevant to that of the FeMo-cofactor of nitrogenase, was obtained from the reaction of 3a or 4a with S8. The μ-SMes ligand in 6 is formed via insertion of a sulfur atom into the Fe?C(Mes) bond. The formation of cluster 6 from 3a or 4a demonstrates that organoiron complexes are applicable as precursors for iron?sulfur clusters.