1056475-69-4Relevant academic research and scientific papers
Facile Aerobic Alkylation of Rhodium Porphyrins with Alkyl Halides
Yang, Wu,Zuo, Huiping,Lai, Wai Yan,Feng, Shiyu,Pang, Yat Sing,Hung, Kai En,Yu, Chu Yi,Lau, Yin Fan,Tsoi, Ho Yin,Chan, Kin Shing
, p. 4051 - 4057 (2015/09/01)
Alkylation of rhodium porphyrins was achieved in moderate to high yields in the presence of air and water. With this facile alkylation method, various alkyl RhIII(por) species, including those with tertiary alkyl, were synthesized. Mechanistic
Base-promoted carbon-hydrogen bond activation of alkanes with rhodium(III) porphyrin complexes
Chan, Yun Wai,Chan, Kin Shing
, p. 4625 - 4635 (2009/02/07)
Base-promoted carbon-hydrogen bond activation of alkanes was achieved in the reactions of alkanes with rhodium(III) porphyrin chlorides (Rh(por)Cl) at 120°C to give rhodium porphyrin alkyls in moderate yields. This carbon-hydrogen activation (CHA) of alkane provided a facile synthesis of Rh(por)R. Mechanistic investigation of CHA suggested that Rh(por)H and [Rh(por)]2 were key intermediates for the CHA step.
