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626-62-0

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626-62-0 Usage

Chemical Properties

CLEAR LIGHT BROWN LIQUID

Uses

Iodocyclohexane has been employed as reagent in demethylation of aryl methyl ethers in DMF under reflux condition.

Synthesis Reference(s)

Journal of the American Chemical Society, 90, p. 808, 1968 DOI: 10.1021/ja01005a056The Journal of Organic Chemistry, 46, p. 2582, 1981 DOI: 10.1021/jo00325a030Tetrahedron Letters, 31, p. 4973, 1990 DOI: 10.1016/S0040-4039(00)97781-5

General Description

The photodissociation dynamics of iodocyclohexane has been studied using velocity map imaging. Nickel catalyzed coupling of iodocyclohexane with 1-octyne has been investigated.

Check Digit Verification of cas no

The CAS Registry Mumber 626-62-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,2 and 6 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 626-62:
(5*6)+(4*2)+(3*6)+(2*6)+(1*2)=70
70 % 10 = 0
So 626-62-0 is a valid CAS Registry Number.
InChI:InChI=1/C6H11I/c7-6-4-2-1-3-5-6/h6H,1-5H2

626-62-0 Well-known Company Product Price

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  • (Code)Product description
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  • Packaging
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  • Alfa Aesar

  • (B24840)  Iodocyclohexane, 98%, stab. with copper   

  • 626-62-0

  • 25g

  • 394.0CNY

  • Detail
  • Alfa Aesar

  • (B24840)  Iodocyclohexane, 98%, stab. with copper   

  • 626-62-0

  • 100g

  • 1058.0CNY

  • Detail
  • Alfa Aesar

  • (B24840)  Iodocyclohexane, 98%, stab. with copper   

  • 626-62-0

  • 500g

  • 4613.0CNY

  • Detail
  • Aldrich

  • (238244)  Iodocyclohexane  98%

  • 626-62-0

  • 238244-25G

  • 813.15CNY

  • Detail
  • Aldrich

  • (238244)  Iodocyclohexane  98%

  • 626-62-0

  • 238244-100G

  • 2,459.34CNY

  • Detail

626-62-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name IODOCYCLOHEXANE

1.2 Other means of identification

Product number -
Other names Cyclohexane, iodo-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:626-62-0 SDS

626-62-0Relevant articles and documents

Visible-light-mediated multicomponent reaction for secondary amine synthesis

Wang, Xiaochen,Zhu, Binbing,Dong, Jianyang,Tian, Hao,Liu, Yuxiu,Song, Hongjian,Wang, Qingmin

supporting information, p. 5028 - 5031 (2021/05/28)

The widespread presence of secondary amines in agrochemicals, pharmaceuticals, natural products, and small-molecule biological probes has inspired efforts to streamline the synthesis of molecules with this functional group. Herein, we report an operationally simple, mild protocol for the synthesis of secondary amines by three-component alkylation reactions of imines (generated in situ by condensation of benzaldehydes and anilines) with unactivated alkyl iodides catalyzed by inexpensive and readily available Mn2(CO)10. This protocol, which is compatible with a wide array of sensitive functional groups and does not require a large excess of the alkylating reagent, is a versatile, flexible tool for the synthesis of secondary amines.

A Metal-Free, Photocatalytic Method for Aerobic Alkane Iodination

Anna, Jessica M.,Goldberg, Karen I.,Hirscher, Nathanael A.,Ohri, Nidhi,Schelter, Eric J.,Yang, Qiaomu,Zhou, Jiawang

supporting information, p. 19262 - 19267 (2021/11/30)

Halogenation is an important alkane functionalization strategy, but O2 is widely considered the most desirable terminal oxidant. Here, the aerobic iodination of alkanes, including methane, was performed using catalytic [nBu4N]Cl and light irradiation (390 nm). Up to 10 turnovers of CH3I were obtained from CH4 and air, using a stop-flow microtubing system. Mechanistic studies using cyclohexane as the substrate revealed important details about the iodination reaction. Iodine (I2) serves multiple roles in the catalysis: (1) as the alkyl radical trap, (2) as a precursor for the light absorber, and (3) as a mediator of aerobic oxidation. The alkane activation is attributed to Cl? derived from photofragmentation of the electron donor-acceptor complex of I2 and Cl-. The kinetic profile of cyclohexane iodination showed that aerobic oxidation of I3- to produce I2 in CH3CN is turnover-limiting.

Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of Iodoalkanes

Zeng, Chaoyuan,Shen, Guoli,Yang, Fan,Chen, Jingchao,Zhang, Xuexin,Gu, Cuiping,Zhou, Yongyun,Fan, Baomin

supporting information, p. 6859 - 6862 (2018/10/25)

The preparation of anhydrous hydrogen iodide directly from molecular hydrogen and iodine using a rhodium catalyst is reported for the first time. The anhydrous hydrogen iodide generated was proven to be highly active in the transformations of alkenes, phenyl aldehydes, alcohols, and cyclic ethers to the corresponding iodoalkanes. Therefore, the present methodology not only has provided convenient access to anhydrous hydrogen iodide but also offers a practical preparation method for various iodoalkanes in excellent atom economy.

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