105676-58-2

Upstream product

• 593-60-2 Vinyl bromide 
• 75-24-1 trimethylaluminum 
• 275804-95-0 (3R)-4-iodo-3-methyl-1-butyl tert-butyldiphenylsilyl ether 
• 213740-15-9 (2R)-4-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-methylbutan-1-ol 
• 126822-71-7 1-iodo-2-<(tert-butyldiphenylsilyl)oxy>ethane 
• 913183-55-8 (R)-4-(tert-butyldiphenylsilyloxy)-N-((1S,2S)-1-hydroxy-1-phenylpropan-2-yl)-n,2-dimethylbutanamide 
• 105676-45-7 3-deoxy-3-tris(methylthio)methyl-5-O-tert-butyldiphenylsilyl-D-arabino-1,4-lactone 
• 105676-55-9 Methanesulfonic acid (1R,2R)-4-(tert-butyl-diphenyl-silanyloxy)-1-[(S)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2-methyl-butyl ester 
• 115495-42-6 3-deoxy-3-C-methyl-1-O-(2,4,6-triisopropyl)benzenesulfonyl-D-arabinitol 
• 105676-54-8 3,5,6-dideoxy-1,2-O-isopropylidene-3,5-di-C-methyl-7-O-tert-butyldiphenylsilyl-D-altro-heptitol 
• 105676-56-0 3,4,5,6-tetradeoxy-1,2-O-isopropylidene-3,5-di-C-methyl-7-O-tert-butyldiphenylsilyl-D-arabino-heptitol 
• 115495-41-5 1-O-tert-butyldiphenylsilyl-3-deoxy-4,5-O-isopropylidene-3-C-methyl-D-arabinitol 
• 105676-29-7 3,4,5,6-tetradeoxy-3,5-di-C-methyl-7-O-tert-butyldiphenylsilyl-D-arabino-heptitol 
• 115495-40-4 (2S,3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-pentane-1,2,4-triol 

Downstream Products

• 105676-57-1 (2R,4S)-6-(tert-butyldiphenylsilanyloxy)-2,4-dimethylhexanal 
• 913183-52-5 (2R,4S)-6-(tert-butyldiphenylsilyloxy)-2,4-dimethylhexanoic acid 
• 1314123-75-5 6-((2S,3R,5S)-7-(tert-butyldiphenylsilyloxy)-2-hydroxy-3,5-dimethylheptyl)-2,2-dimethyl-4H-1,3-dioxin-4-one 
• 105676-22-0 Methanesulfonic acid (Z)-(1S,2R,3R,4R,8R,10R)-3,11-bis-benzyloxy-1-(tert-butyl-diphenyl-silanyloxymethyl)-2,4,8,10-tetramethyl-undec-5-enyl ester 
• 105676-21-9 (Z)-(2S,3S,4R,5R,9R,11R)-4,12-Bis-benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-3,5,9,11-tetramethyl-dodec-6-en-2-ol 
• 105676-19-5 (S)-4-((Z)-(1R,2R,3R,7R,9R)-2,10-Bis-benzyloxy-1,3,7,9-tetramethyl-dec-4-enyl)-2,2-dimethyl-[1,3]dioxolane 
• 105676-20-8 (Z)-(2S,3S,4R,5R,9R,11R)-4,12-Bis-benzyloxy-3,5,9,11-tetramethyl-dodec-6-ene-1,2-diol 
• 105676-23-1 (R)-2-((Z)-(1R,2R,3R,7R,9R)-2,10-Bis-benzyloxy-1,3,7,9-tetramethyl-dec-4-enyl)-oxirane 
• 105676-28-6 C₂₁H₂₈O₃S 
• 105676-27-5 C₂₁H₂₈OS 
• 105676-26-4 Methanesulfonic acid (3S,5R)-6-benzyloxy-3,5-dimethyl-hexyl ester 
• 105676-25-3 (3S,5R)-6-Benzyloxy-3,5-dimethyl-hexan-1-ol 

Relevant academic research and scientific papers

Synthesis of (-)-okilactomycin by a prins-type fragment-assembly strategy

All things converge: A highly convergent synthesis of (-)-okilactomycin utilizes a Prins-type Maitland-Japp cyclization for the fragment assembly of two complex intermediates (see scheme). The synthesis also employs a highly diastereoselective Lewis acid promoted Diels-Alder reaction and an olefin ring-closing metathesis to close a strained 11-membered macrocycle.

Synthesis of the C1-C16 fragment of ionomycin using a neutral (η3-allyl)iron complex

Key steps in the synthesis of the C1-C16 polyketide fragment of ionomycin were the nucleophilic addition of an organocuprate to a neutral (η3-allyl)iron complex and the construction of a β-diketone moiety by the Rh-catalysed rearrangement of an

Use of lithium hexafluoroisopropoxide as a mild base for Horner-Wadsworth-Emmons olefination of epimerizable aldehydes

(Chemical Equation Presented) The weak base lithium 1,1,1,3,3,3- hexafluoroisopropoxide (LiHFI) is shown to be highly effective as a reagent for intermolecular Horner-Wadsworth-Emmons (HWE) olefination of epimerizable aldehydes with trimethyl phosphonoace