1056884-50-4Relevant academic research and scientific papers
Moebius antiaromatic bisphosphorus complexes of [30]hexaphyrins
Higashino, Tomohiro,Lim, Jong Min,Miura, Takahiro,Saito, Shohei,Shin, Jae-Yoon,Kim, Dongho,Osuka, Atsuhiro
, p. 4950 - 4954 (2010)
Aromaticity with a twist: The reversal of Moebius aromaticity occurs by changing the number of π electrons between [4n + 2] and [4n] in monophosphorus complexes of [28]hexaphyrins and bisphosphorus complexes of [30]hexaphyrins. The 30π Moebius antiaromatic bisphosporus[30]hexaphyrins (see picture) were determined to be the first structurally characterized Moebius antiaromatic systems, which are rigid, neutral, and stable. (Figure Presented)
