105752-50-9Relevant academic research and scientific papers
THE INFLUENCE OF HYDROGEN BONDING ON THE SOLVOLYTIC REACTIVITY OF NICOTINATES IN FLUORINATED ALCOHOLS
Jursic, Branko,Sunko, Dionis E.,Ladika, Mladen
, p. 4367 - 4376 (2007/10/02)
A systematic investigation of solvolytic reactivities of allylic and benzylic nicotinates and their N-methylated derivatives in 80percent EtOH, 97percent TFE and 97percent HFIP was undertaken.The nicotinates in 97percent HFIP are slightly more reactive th
SOLVOLYSIS OF 2-(ω-ALKOXYALKYL)-3-METHYL-2-CYCLOHEXENYL p-NITROBENZOATES. SEARCH FOR NEIGHBORING OXYGEN PARTICIPATION
Ladika, Mladen,Jursic, Branko,Sunko, Dionis E.
, p. 179 - 190 (2007/10/02)
The degree of alkoxy group participation in the solvolysis of allylic p-nitrobenzoates with an ω-alkoxyalkyl side-chain at C-2 center was studied.In 80 percent EtOH the solvolysis rates, secondary α-deuterium isotope effects, and the product composition s
SOLVOLYSIS OF 2-(2-METHOXYETHYL)-3-METHYL-2-CYCLOHEXENYL p-NITROBENZOATE. A CASE OF NON-PARTICIPATION OF METHOXY GROUP
Jursic, Branko,Ladika, Mladen,Sunko, Dionis E.
, p. 911 - 916 (2007/10/02)
In an attempt to study possible n-participation in allyl derivatives, 2-(2-methoxyethyl)-3-methyl-2-cyclohexenyl p-nitrobenzoate 4 was solvolyzed in various solvents including fluorinated alcohols.Its solvolysis rate is slower than that of the 2-butyl ana
