1057653-82-3Relevant articles and documents
Stereoselective synthesis of C-ketosides by sequential intramolecular hydrogen atom transfer-intermolecular allylation reaction
Martín, Angeles,Pérez-Martín, Inés,Quintanal, Luis M.,Suárez, Ernesto
, p. 5179 - 5181 (2008)
A tandem 1,5 or 1,6 hydrogen atom transfer (HAT)-radical allylation using carbohydrate models is described. The HAT reaction generated a C-glycos-1-yl radical intermediate, which added to allyltri-n-butyltin with high diastereoselectivity, to give C-ketosides with the quaternary carbon carrying two differently functionalized tethers.