105847-59-4

Basic information

• Product Name: 8-HYDROXYJULOLIDINE-9-ALDEHYDE
• Synonyms: 8-HYDROXYJULOLIDINE-9-CARBOXALDEHYDE;8-HYDROXY-2,3,6,7-TETRAHYDRO-1H,5H-BENZO[I,J]QUINOLIZINE-9-CARBOXALDEHYDE;8-HYDROXY-2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3,2,1-IJ]QUINOLINE-9-CARBALDEHYDE;2,3,6,7-tetrahydro-8-hydroxy-1H,5H-benzo-(ij)quin;2 3 6 7-TETRAHYDRO-8-HYDROXY-1H 5H-BENZ&;tetrahydrohydroxy-1H,5H-benzo[ij]quinolizinecarboxaldehyde;2,3,6,7-TETRAHYDRO-8-HYDROXY-1H,5H-BENZO[IJ]QUINOLIZINE-9-CARBALDEHYDE;AKOS NCG-0055
• CAS NO: 105847-59-4
• Molecular Formula: C13H15NO2
• Molecular Weight: 217.26
• EINECS: 263-966-4
• Mol File: 105847-59-4.mol

Chemical Properties

• Melting Point: 71-74°C
• Boiling Point: 417.3°Cat760mmHg
• Flash Point: 206.2°C
• Appearance: /
• Density: 1.3g/cm³
• Vapor Pressure: 1.47E-07mmHg at 25°C
• Refractive Index: 1.648
• PKA: 14.05±0.20(Predicted)
• CAS DataBase Reference: 8-HYDROXYJULOLIDINE-9-ALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 8-HYDROXYJULOLIDINE-9-ALDEHYDE(105847-59-4)
• EPA Substance Registry System: 8-HYDROXYJULOLIDINE-9-ALDEHYDE(105847-59-4)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 105847-59-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H15NO2/c15-8-10-7-9-3-1-5-14-6-2-4-11(12(9)14)13(10)16/h7-8,16H,1-6H2

Upstream product

• 19343-78-3 4-methyl-1,2,3,4-tetrahydroquinoline 
• 92020-81-0 1-(β-chloropropionyl)-4-methyl-1,2,3,4-tetrahydroquinoline 
• 491-35-0 C₆H₄NCH₂CHCCH₂ 
• 105847-57-2 1-methyl-1,2,6,7-tetrahydropyrido<3,2,1-i,j>quinoline-5(3H)-one 

Relevant articles and documents

Microbiological Transformations, Part 9. Microbiological Transformations of 1,2,5,6-Tetrahydropyrroloquinolin-4-one and of Derivatives of 1,2,3,5,6,7-Hexahydropyridoquinoline with the Fungus Cunninghamella elegans

Incubation of 1,2,6,7-tetrahydropyridoquinolin-3(5H)-one with C. elegans resulted in oxidation at the C-7 benzylic position, whereas 1-methyl-1,2,6,7-tetrahydropyridoquinolin-5(3H)-one gave products resulting from oxidation at both benzylic positions. cis- and trans-1-Hydroxy-3-methyl-1,2,6,7-tetrahydropyridoquinolin-5(3H)-ones were produced on incubation of 5-methyl-1,2,6,7-tetrahydropyridoquinolin-3(5H)-one with C. elegans, in addition to trans-1-hydroxy-5-methyl-1,2,6,7-tetrahydropyridoquinolin-3(5H)-one.Incubation of 1,2,5,6-tetrahydropyrroloquinolin-4-one with C. elegans resulted in dehydrogenation to 1,2-dihydropyrroloquinolin-4-one.Incubation of 2,3,6,7-tetrahydropyridoquinolin-1(5H)-one with C. elegans resulted in benzylic attack at C-7.