1058705-40-0 Usage
Uses
Used in Organic Synthesis:
Vinyl N,N-diisopropylcarbamate is used as a key intermediate in the synthesis of alkyne-containing molecules for various applications in organic chemistry. Its high enantiospecificity allows for the selective formation of desired enantiomers, which is crucial in the development of chiral compounds with specific biological activities.
Used in Pharmaceutical Industry:
Vinyl N,N-diisopropylcarbamate is used as a building block for the development of pharmaceutical compounds with potential therapeutic applications. The ability to selectively form enantiomers can lead to the discovery of new drugs with improved efficacy and reduced side effects.
Used in Materials Science:
Vinyl N,N-diisopropylcarbamate can be used in the synthesis of novel materials with unique properties, such as chiral polymers or self-assembling systems. These materials can have potential applications in various fields, including sensors, catalysts, and drug delivery systems.
Used in Chemical Research:
Vinyl N,N-diisopropylcarbamate serves as a valuable research tool for studying the mechanisms of enantioselective reactions and the development of new synthetic methodologies. Its unique reactivity and selectivity can provide insights into the fundamental principles of organic chemistry and catalysis.
Check Digit Verification of cas no
The CAS Registry Mumber 1058705-40-0 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,5,8,7,0 and 5 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1058705-40:
(9*1)+(8*0)+(7*5)+(6*8)+(5*7)+(4*0)+(3*5)+(2*4)+(1*0)=150
150 % 10 = 0
So 1058705-40-0 is a valid CAS Registry Number.
1058705-40-0Relevant articles and documents
Rhodium(III)-catalyzed C-H activation/annulation with vinyl esters as an acetylene equivalent
Webb, Nicola J.,Marsden, Stephen P.,Raw, Steven A.
supporting information, p. 4718 - 4721 (2015/04/27)
The behavior of electron-rich alkenes in rhodium-catalyzed C-H activation/annulation reactions is investigated. Vinyl acetate emerges as a convenient acetylene equivalent, facilitating the synthesis of sixteen 3,4-unsubstituted isoquinolones, as well as select heteroaryl-fused pyridones. The complementary regiochemical preferences of enol ethers versus enol esters/enamides is discussed.
Asymmetric synthesis of 3,4-annulated cyclopentenones from cycloalkenyl ketones and vinyl carbamates by diastereoselective carbonyl addition/conrotatory 4π ring closure
Siemer, Michael,Froehlich, Roland,Hoppe, Dieter
experimental part, p. 2264 - 2270 (2009/04/07)
1-Lithiated O-vinyl carbamates add with high induced diastereoselectivity onto enantiomerically pure cycloalk-1-enyl (1-dibenzylamino)alkyl ketones. Subsequent O-carbamoyl migration, followed by a torquoselective, antarafacial 4π ring closure, leads to ho
α-Metalated Tertiary Enol Carbamates. New Acyl Anion Equivalents
Sengupta, Saumitra,Snieckus, Victor
, p. 5680 - 5683 (2007/10/02)
α-Metalated enol carbamate 1g constitutes a new, conveniently generated (sec-BuLi/TMEDA/THF/-78 deg C), and well-behaved acyl anion equivalent.The utility and scope of this synthon for the preparation of a variety of useful synthetic building blocks (4, 6
