105881-07-0

Basic information

• Product Name: C₃₈H₃₁ClF₃IrO₄P₂S
• CAS NO: 105881-07-0
• Molecular Weight: 930.343
• Mol File: 105881-07-0.mol

Chemical Properties

• CAS DataBase Reference: C₃₈H₃₁ClF₃IrO₄P₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₈H₃₁ClF₃IrO₄P₂S(105881-07-0)
• EPA Substance Registry System: C₃₈H₃₁ClF₃IrO₄P₂S(105881-07-0)

Safety Data

• Hazardous Substances Data: 105881-07-0(Hazardous Substances Data)

Upstream product

• 15318-31-7 bis(triphenylphosphine)iridium(I) carbonyl chloride 
• 1493-13-6 trifluorormethanesulfonic acid 

Downstream Products

• 82474-51-9 Carbonylchlorohydridotris(triphenylphosphan)iridium(III)-trifluormethansulfonat 
• 78571-28-5 Carbonylchlorohydrido(thiocyanato-S)bis(triphenylphosphan)iridium(III) 

Relevant articles and documents

The synthesis of ionic iridium(III) carbene complexes of the type Cl(OSO2CF3)(CO)(PPh3)2>+-

The title compounds in which R = C6H5, 4-MeC6H4, 4-EtC6H4 and CH3 have been prepared in moderate to good yield by the reaction between and the corresponding N-methylnitrilium triflate salts NMe>+-/s

Hydridoiridium(III) Complexes with Terminal and Bridging Thio- and Selenocyanate

The thio- and selenocyanato complexes (Ph3P)2(CO)(Cl)(H)IrX 1 (X = SCN) and 2 (X = SeCN) have been prepared from the corresponding tetrafluoroborato- and trifluoromethanesulfonato-compounds (X = BF4, CF3SO3).The SCN ligand in 1 is S-bonded. 2 was obtained as a mixture of linkage isomers.The reaction of 2 with the tetrafluoroborato-complex (Ph3P)2(CO)(Cl)(H)IrFBF3 gives the salt +BF4- which contains the selenocyanate-bridged cation as a mixture of stereoisomers.