105881-07-0Relevant articles and documents
The synthesis of ionic iridium(III) carbene complexes of the type Cl(OSO2CF3)(CO)(PPh3)2>+-
Booth, B.L.,Wickens, A.C.
, p. 283 - 286 (1993)
The title compounds in which R = C6H5, 4-MeC6H4, 4-EtC6H4 and CH3 have been prepared in moderate to good yield by the reaction between and the corresponding N-methylnitrilium triflate salts NMe>+-/s
Hydridoiridium(III) Complexes with Terminal and Bridging Thio- and Selenocyanate
Olgemoeller, Bernhard,Beck, Wolfgang
, p. 2360 - 2364 (2007/10/02)
The thio- and selenocyanato complexes (Ph3P)2(CO)(Cl)(H)IrX 1 (X = SCN) and 2 (X = SeCN) have been prepared from the corresponding tetrafluoroborato- and trifluoromethanesulfonato-compounds (X = BF4, CF3SO3).The SCN ligand in 1 is S-bonded. 2 was obtained as a mixture of linkage isomers.The reaction of 2 with the tetrafluoroborato-complex (Ph3P)2(CO)(Cl)(H)IrFBF3 gives the salt +BF4- which contains the selenocyanate-bridged cation as a mixture of stereoisomers.