105891-06-3Relevant articles and documents
Hydrosulfonylation of Unactivated Alkenes by Visible Light Photoredox Catalysis
Wang, Juan-Juan,Yu, Wei
supporting information, p. 9236 - 9240 (2019/11/19)
The anti-Markovnikov hydrosulfonylation of unactivated alkenes with sodium sulfinates was realized via [Ir(dF(CF3)ppy)2(dtbbpy)]PF6-mediated visible light photoredox catalysis. The presence of an acid such as acetic acid is essential for the reaction to take place. A variety of unactivated alkenes can be transformed into sulfones with good yield and high regioselectivity using this reaction, which is proposed to proceed by a radical mechanism.
ELECTRONIC EFFECTS IN ALKYL 4-CHLOROPHENYL SULFONE AND SULFOXIDE MOLECULES ACCORDING TO 35Cl NQR DATA
Feshin, V. P.,Voronkov, M. G.,Dolgushin, G. V.,Romanenko, L. S.,Aliev, I. A.,Mirzoeva, M. A.
, p. 1103 - 1106 (2007/10/02)
Compounds of the 4-ClC6H4S(O)CHn.(CH3)3-n and 4-ClC6H4SO2R series nH and CHn(CH3)3-n> were synthesized and studied by the 35Cl NQR method.It was found that their NQR frequencies change regularly with increase in the number n.