105897-94-7

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 79646-63-2 methyl 2,3,4-trideoxy-2,3-di-C-methyl-6-O-trityl-α-D-ribo-hexopyranoside 
• 89254-42-2 (2S,3S,5R)-5-[1,3]Dithian-2-yl-3-methyl-hexane-1,2-diol 
• 68880-93-3 (2R,5R,6S)-6-Methoxy-5-methyl-2-trityloxymethyl-dihydro-pyran-3-one 
• 105897-93-6 (2S,3R,6S)-2-Methoxy-3-methyl-5-methylene-6-trityloxymethyl-tetrahydro-pyran 
• 68880-92-2 (2R,3S,5R,6S)-6-Methoxy-5-methyl-2-trityloxymethyl-tetrahydro-pyran-3-ol 
• 101978-79-4 Methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-allopyranoside 
• 105930-42-5 (2R,4aR,6S,7R,8aS)-6-Methoxy-7-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 98-59-9 p-toluenesulfonyl chloride 
• 73679-58-0 methyl 2,3,4-trideoxy-2,4-di-C-methyl-6-O-(triphenylmethyl)-α-D-arabino-hexopyranoside 
• 68880-96-6 (2'S,4'R,5'S)-2-(2',4'-dimethyl-5',6'-dihydroxyhex-2'-yl)-1,3-dithiane 

Relevant academic research and scientific papers

STEREOSELECTIVE TOTAL SYNTHESIS AND STEREOCHEMISTRY OF DIPLODIATOXIN, A MYCOTOXIN FROM DIPLODIA MAYDIS

The stereochemistry of diplodiatoxin has been deduced, and the assumed stereostructure has been confirmed by the synthesis using highly stereocontrolled strategy, in which the intramolecular Diels-Alder reaction of a(E, E, E)-triene is involved.