79646-63-2

Upstream product

• 105897-93-6 (2S,3R,6S)-2-Methoxy-3-methyl-5-methylene-6-trityloxymethyl-tetrahydro-pyran 
• 73656-98-1 (2S,5S,6S)-2-Methoxy-5-methyl-3-methylene-6-trityloxymethyl-tetrahydro-pyran 
• 105930-42-5 (2R,4aR,6S,7R,8aS)-6-Methoxy-7-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 101978-79-4 Methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-allopyranoside 
• 79607-38-8 (2S,5S,6S)-2-Methoxy-5-methyl-6-trityloxymethyl-dihydro-pyran-3-one 
• 79607-37-7 methyl 3,4-dideoxy-4-c-methyl-6-o-trityl-α-D-glycero-hex-3-enopyranosid-2-ulose 
• 68880-93-3 (2R,5R,6S)-6-Methoxy-5-methyl-2-trityloxymethyl-dihydro-pyran-3-one 
• 68880-92-2 (2R,3S,5R,6S)-6-Methoxy-5-methyl-2-trityloxymethyl-tetrahydro-pyran-3-ol 
• 109915-01-7 methyl 2,4-dideoxy-2,4-di-C-methyl-6-O-trityl-α-D-arabino-hexopyranosid-3-ulose 
• 109915-02-8 methyl 2,4-dideoxy-2,4-di-C-methyl-6-O-trityl-α-D-lyxopyranosid-3-ulose 
• 109915-00-6 methyl 2,4-dideoxy-2,4-di-C-methyl-6-O-trityl-α-D-altropyranoside 
• 109914-99-0 methyl 2,4-dideoxy-2,4-di-C-methyl-6-O-trityl-α-D-idopyranoside 
• 19465-06-6 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-altropyranoside 
• 2880-96-8 methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside 

Downstream Products

• 105897-94-7 Toluene-4-sulfonic acid (1S,2S,4R)-1-(tert-butyl-dimethyl-silanyloxymethyl)-4-[1,3]dithian-2-yl-2-methyl-pentyl ester 

Relevant academic research and scientific papers

An Approach to the Total Synthesis of the Prelog-Djerassi Lactone

An approach to the synthesis of the Prelog-Djerassi lactone using D-glucose as a starting material is described.The use of Swern oxidation provides an efficient means of preparing carbohydrate ketones.An unusual departure from the normal reaction pathway

STEREOSELECTIVE TOTAL SYNTHESIS AND STEREOCHEMISTRY OF DIPLODIATOXIN, A MYCOTOXIN FROM DIPLODIA MAYDIS

The stereochemistry of diplodiatoxin has been deduced, and the assumed stereostructure has been confirmed by the synthesis using highly stereocontrolled strategy, in which the intramolecular Diels-Alder reaction of a(E, E, E)-triene is involved.

A ROUTE TO PRELOG-DJERASSI LACTONE FROM METHYL α,D-GLUCOPYRANOSIDE

The enone 1 obtainable from methyl α,D-glucopyranoside is converted into the corresponding diene 5 which is hydrogenated to give predominantly the diequatorial dimethyl hexopyranoside 3.C6 of the latter is converted stepwise to the methyl ketone from whic