105947-05-5

Basic information

• Product Name: 2-(2-bromo-5-methylphenoxy)aniline
• Synonyms: 2-(2-bromo-5-methylphenoxy)aniline
• CAS NO: 105947-05-5
• Molecular Weight: 278.148
• Mol File: 105947-05-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2-bromo-5-methylphenoxy)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-bromo-5-methylphenoxy)aniline(105947-05-5)
• EPA Substance Registry System: 2-(2-bromo-5-methylphenoxy)aniline(105947-05-5)

Safety Data

• Hazardous Substances Data: 105947-05-5(Hazardous Substances Data)

Upstream product

• 105901-14-2 1-bromo-4-methyl-2-(2-nitrophenoxy)benzene 
• 1493-27-2 ortho-nitrofluorobenzene 
• 14847-51-9 2-bromo-5-methylphenol 

Downstream Products

• 106951-27-3 N-(2-(2-bromo-5-methylphenoxy)phenyl)acetamide 
• 18839-24-2 3-methyl-10,10-diphenyl-10H-phenoxasiline 
• 108667-90-9 benzoic acid-[2-(2-bromo-5-methyl-phenoxy)-anilide] 

Relevant articles and documents

Microwave assisted rapid synthesis of phenoxazines and benzopyridoxazines

A facile protocol for the synthesis of phenoxazines and benzopyridoxazines by Smiles rearrangement have been demonstrated in short reaction time under microwave irradiation. The control experiments suggest that a reaction proceeds through Smiles rearrangement followed SNAr ring closure by in situ cascade process. In our present work, both the electron donating and electron withdrawing groups were tolerant and provided a corresponding phenoxazine/benzopyridoxazine in good to moderate yields.