105949-46-0Relevant academic research and scientific papers
Scandium triflate-catalyzed nucleophilic additions to indolylmethyl Meldrum's acid derivatives via a gramine-type fragmentation: Synthesis of substituted indolemethanes
Armstrong, Erin L.,Grover, Huck K.,Kerr, Michael A.
, p. 10534 - 10540 (2013)
Treatment of indolylmethyl Meldrum's acids with catalytic scandium triflate and a variety of nucleophiles results in the nucleophilic displacement of the Meldrum's acid moiety via a gramine-type fragmentation. The reaction is useful for the generation of
SYNTHESIS OF 3-SUBSTITUTED INDOLES VIA N-ACYLINDOLIUM IONS
Comins, Daniel L.,Stroud, Eric D.
, p. 1869 - 1872 (2007/10/02)
3-Substituted N-(N'N'-diethylcarbamyl)indoles are prepared from indole-3-carboxaldehyde in good overall yield via N-acylindolium ion intermediates.
