105952-20-3Relevant academic research and scientific papers
Stereoselective Synthesis of Ethyl (2E,4E)-Alkadienoates from Ethyl Sulfolane-2-carboxylate
Saigo, Kazuhiko,Kudo, Kazuaki,Hashimoto, Yukihiko,Kihara, Nobuhiro,Hasegawa, Masaki
, p. 1203 - 1206 (2007/10/02)
α,β,γ,δ-Unsaturated esters were conveniently synthesized from ethyl sulfolane-2-carboxylate through alkylation and oxidation followed by the retro Diels-Alder reaction of the resulting 3-sulfolene derivatives.The reaction proceeded with high E,E-selectivity.
