105954-74-3Relevant academic research and scientific papers
Syntheses of Iron-containing Heterometallic Complexes using Tridentate Phosphine Ligands; the Crystal Structure of Ru3(CO)9>
Dolby, P. Ann,Harding, Marjorie M.,Newar, Nagwa,Smith, Anthony K.
, p. 2939 - 2942 (2007/10/02)
Treatment of with PPh2H gives the addition product > 1.The unco-ordinated phosphine group of complex 1 reacts with 2> to give Rh
BIMETALLIC SYSTEMS. PART 22. MOLYBDENUM(0)-AND MANGANESE(I)-IRON(0) CARBONYL COMPLEXES CONTAINING ONE BRIDGING Ph2PCH2PPh2 LIGAND, INCLUDING THE REVERSIBLE UPTAKE OF CARBON MONOXIDE: CRYSTAL STRUCTURE OF -0.5 C6H5Cl
Jacobsen, Grant B.,Shaw, Bernard L.,Thornton-Pett, Mark
, p. 1509 - 1514 (2007/10/02)
Treatment of with dppm (Ph2PCH2PPh2) in tetrahydrofuran gave and other products.Treatment of with gave in 58percent yield.This bimetallic complex reacted reversibly with carbon monoxide, breaking the metal-metal bond to give .Treatment of with = norbornadiene (bicyclohepta-2,5-diene)> gave in 47percent yield.This bimetallic complex reacts with carbon monoxide to give a complex, formulated as , which was not isolated.Analogous reactions with the diphosphine CH2=C(PPh2)2 are described.Crystals of are tetragonal, space group/41cd (no. 110), with a = 1 853.1(4), c = 4 106.8(9) p0m, and Z = 16; final R = 0.0633 for 3 357 observed reflections.The structure shows that there is a metal-metal bond formulated as a donor acceptor bond, viz.FeMo.
REACTIONS OF METAL CARBONYL CLUSTER COMPLEXES WITH MULTIDENTATE PHOSPHINE LIGANDS; PREPARATION OF 1,1-BIS(DIPHENYLPHOSPHINO)ETHENE DERIVATIVES, AND THE X-RAY CRYSTAL STRUCTURES OF Fe(CO)3(dppee) AND Os3(CO)10(dppee) (dppee=Ph2PC(=CH2)PPh2)
Clucas, Jennifer A.,Dawson, Richard H.,Dolby, P. Ann,Harding, Marjorie M.,Pearson, Keith,Smith, Anthony K.
, p. 153 - 162 (2007/10/02)
A number of metal cluster carbonyl complexes containing the 1,1-bis(diphenylphosphino)ethene (dppee) ligand have been prepared and characterised, as have the mononuclear iron complexes Fe(CO)4(dppee) and Fe(CO)3(dppee).The crystal structures of Fe(CO)3(dppee) and Os3(CO)10(dppee) have been determined.
