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13463-40-6 Usage

Health Hazard

Toxicity of Ironpentacarbonyl is high via all routes of entry. Cyanosis (bluish discoloration of skin) and circulatory collapse may occur after exposure. Death may result. Pneumonitis and injury to the kidneys, liver, and central nervous system may also occur.

Reactivity Profile

Organometallics, such as Ironpentacarbonyl, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. A brown pyrophoric powder is produced by the combination of the carbonyl with acetic acid containing greater than 5% of water.

Chemical Properties

yellow-orange to brown liquid which

General Description

A yellow to dark red liquid. Insoluble in water and denser than water. Very toxic by inhalation, ingestion, and skin absorption. Flash point 5°F. Used to make other chemicals.

Uses

To make finely divided iron, so-called carbonyl iron, which is used in the manufacture of powdered iron cores for high frequency coils used in the radio and television industry; as antiknock agent in motor fuels; as catalyst and reagent in organic reactions.

Air & Water Reactions

Highly flammable. Ironpentacarbonyl is spontaneously flammable in air, [R. Kamo, IIT Progs. Rept. 1, p. 23(1962)]. Insoluble in water.

Fire Hazard

Ironpentacarbonyl may be ignited by heat, sparks, or flames. Vapors may travel to ignition source and flash back. Containers may explode in the heat of fire. Evolution of carbon monoxide may create a poison hazard. Ironpentacarbonyl presents a vapor explosion and poison hazard indoors, outdoors, or in sewers. Evolves carbon monoxide on exposure to air or to light. Emits carbon monoxide when heated to decomposition. Avoid acetic acid, water, nitrogen oxide, transition metal halides, and zinc and Ironpentacarbonyl burns in air. Decomposes in acids and alkalies. Protect from light and air.

Purification Methods

It is a pale yellow viscous liquid which is PYROPHORIC and readily absorbed by the skin. HIGHLY TOXIC (protect from light and air). It should be purified in a vacuum line by distilling and collecting in a trap at -96o (toluene-Dry ice slush). It has been distilled at atmospheric pressure (use a very efficient fume cupboard). At 180o/atmospheric pressure it decomposes to give Fe and CO. In UV light in pet ether it forms Fe2(CO)9 (see previous entry). [Hagen et al. Inorg Chem 17 1369 1978, Ewens et al. Trans Faraday Soc 35 6811 1939.]
InChI:InChI=1/5CO.Fe/c5*1-2;/rC5FeO5/c7-1-6(2-8,3-9,4-10)5-11

13463-40-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name pentacarbonyliron

1.2 Other means of identification

Product number -
Other names iron prntacarbonyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13463-40-6 SDS

13463-40-6Synthetic route

diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

Os{PCO(CF3)}(CO)2(P(C6H5)3)2
103932-33-8

Os{PCO(CF3)}(CO)2(P(C6H5)3)2

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

Os{P{Fe(CO)4}CO(CF3)}(CO)2(P(C6H5)3)2

Os{P{Fe(CO)4}CO(CF3)}(CO)2(P(C6H5)3)2

Conditions
ConditionsYield
In tetrahydrofuran educts suspended in THF; after 1 h solvent removed in vacuo;; residue left under vacuum for 1 h; dissolved in CH2Cl2; addn. of ethanol; concentration; filtration; washed with ethanol and n-hexane; elem. anal.;A n/a
B 100%
triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

Conditions
ConditionsYield
With carbon monoxide In n-heptane Irradiation (UV/VIS); soln. of Fe3(CO)12 in n-heptane is irradiated for 30 min in slow streamof CO;98%
In n-heptane Irradiation (UV/VIS); soln. of Fe3(CO)12 in n-heptane is irradiated at 293 K for 75 min in slow stream N2;96%
With carbon monoxide In N,N-dimethyl-formamide decompn. in presence of CO (1 atm) betwwen 0 and 25°C; intermediates observed;; not isolated; detn. by ESR;
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

((t-Bu)4(Me)2azasilagermane)
124686-70-0

((t-Bu)4(Me)2azasilagermane)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

((t-Bu)4(Me)2azasilagermane)iron tetracarbonyl
124686-68-6

((t-Bu)4(Me)2azasilagermane)iron tetracarbonyl

Conditions
ConditionsYield
In benzene To a soln. of Ge compd. in benzene is added the carbonyl compd., suspn. is stirred for 12 h.; Recrystn. from toluene, NMR.;A n/a
B 97%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

1,3-bis(diphenylstibino)propane
38611-86-8

1,3-bis(diphenylstibino)propane

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

[(Fe(CO)4)2((C6H5)2Sb(CH2)3Sb(C6H5)2)]

[(Fe(CO)4)2((C6H5)2Sb(CH2)3Sb(C6H5)2)]

Conditions
ConditionsYield
In tetrahydrofuran (N2); soln. of Fe complex (2 equiv.) and Sb ligand in THF was stirred atroom temp. for 2 d; filtered; volatiles removed (vac.);A n/a
B 97%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

1,1-dimethoxy-1-silacyclobutane
33446-84-3

1,1-dimethoxy-1-silacyclobutane

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

2,2,2,2-tetracarbonyl-1,1-dimethoxy-1-sila-2-ferracyclopentane
68046-55-9

2,2,2,2-tetracarbonyl-1,1-dimethoxy-1-sila-2-ferracyclopentane

Conditions
ConditionsYield
In benzene addn. of 2 equiv. of Si-compd. to Fe-complex suspn. (held above freezingpoint), warming to 21°C, stirring (12 h); removal of Fe(CO)5 and solvent (vac.), distn. (1E-2 Torr, 30°C); elem. anal.;A n/a
B 96%
With carbon monoxide In not given N2-atmosphere;
disodium tetracarbonylferrate

disodium tetracarbonylferrate

carbon dioxide
124-38-9

carbon dioxide

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

sodium carbonate
497-19-8

sodium carbonate

Conditions
ConditionsYield
In tetrahydrofuran reductive disproportionation, mechanism discussed;; IR; iron carbonyl not isolated;;A 82%
B 94%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

Fe(CO)4CCC(C4H9)2

Fe(CO)4CCC(C4H9)2

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

μ-(Di-tert-butylallenyliden)-bis(tetracarbonyleisen)(Fe-Fe)

μ-(Di-tert-butylallenyliden)-bis(tetracarbonyleisen)(Fe-Fe)

Conditions
ConditionsYield
In petroleum ether addn. of Fe2(CO)9 to soln. of Fe org. complex, stirring for 30 min at 40°C; filtering, chromy., recrystn. from petroleum ether;A n/a
B 92%
N(C6H4OCH3)C(O)(C(COOCH3))2C(CH3)C(CH3)N(C6H4OCH3)Fe(CO)3
122190-26-5

N(C6H4OCH3)C(O)(C(COOCH3))2C(CH3)C(CH3)N(C6H4OCH3)Fe(CO)3

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

1-(4-methoxyphenyl)-3,4-dicarbomethoxy-5-methyl-5(1-{N-(4-methoxyphenyl)imino}ethyl)-1,5-dihydropyrrol-2-one

1-(4-methoxyphenyl)-3,4-dicarbomethoxy-5-methyl-5(1-{N-(4-methoxyphenyl)imino}ethyl)-1,5-dihydropyrrol-2-one

Conditions
ConditionsYield
In acetone in a steel autoclave with glass insert, keeping at 75-90 °C, 4 d, under 180 bar of CO pressure; evapn. of the solvent and Fe(CO)5;A n/a
B 90%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

Cr(C(C6H3Me2-2,6))(CO)2(η-C5H5)

Cr(C(C6H3Me2-2,6))(CO)2(η-C5H5)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

C

CrFe(μ-C(C6H4Me2-2,6))(CO)5(η-C5H5)

CrFe(μ-C(C6H4Me2-2,6))(CO)5(η-C5H5)

Conditions
ConditionsYield
In tetrahydrofuran N2, stirring for 6 h at room temp.;; evapd., dissolved in CH2Cl2/light petroleum 1/1, chromd. (alumina, CH2Cl2/light petroleum 1/1), evapd., elem. anal.;A n/a
B n/a
C 88%
1,1-dimethylsilacyclobutane
2295-12-7

1,1-dimethylsilacyclobutane

diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

C

2,2,2,2-tetracarbonyl-1,1-dimethyl-1-sila-2-ferracyclopentane
39114-08-4

2,2,2,2-tetracarbonyl-1,1-dimethyl-1-sila-2-ferracyclopentane

Conditions
ConditionsYield
In benzene addn. of 2 equiv. of Si-compd. to Fe-complex suspn. (held above freezingpoint), warming to 21°C, stirring (24 h); removal of Fe(CO)5 and solvent (vac.), dissoln. in hexane, crystn. (-30°C, several days), filtration off of Fe3(CO)12, evapn. of filtrate(vac., low temp.), sublimation (1E-3 Torr, 0°C); elem. anal.;A n/a
B n/a
C 86%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

Mo(C(C6H4NMe2-4))(CO)2(η-C5H5)

Mo(C(C6H4NMe2-4))(CO)2(η-C5H5)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

MoFe(μ-CC6H4NMe2-4)(CO)6(η-C5H5)

MoFe(μ-CC6H4NMe2-4)(CO)6(η-C5H5)

C

Mo2Fe(μ-C2(C6H4NMe2-4))2(CO)6(η-C5H5)2

Mo2Fe(μ-C2(C6H4NMe2-4))2(CO)6(η-C5H5)2

Conditions
ConditionsYield
In diethyl ether N2, stirring for 5 h at ambient temp.; evapd., dissolved in CH2Cl2/light petroleum 1/2, separation by chromy. (Kieselgel, water-cooled, CH2Cl2/light petroleum 1/2, then CH2Cl2/thf 1/1), evapd., elem. anal.;A n/a
B 85%
C n/a
cis-(methyloxalyl)(methoxycarbonyl)tetracarbonyliron

cis-(methyloxalyl)(methoxycarbonyl)tetracarbonyliron

A

Dimethyl oxalate
553-90-2

Dimethyl oxalate

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

C

bis(methoxycarbonyl)tetracarbonyliron

bis(methoxycarbonyl)tetracarbonyliron

Conditions
ConditionsYield
In dichloromethane-d2 byproducts: CO; introducing a soln. of Fe-complex in CD2Cl2 into NMR tube, maintaining temp. at 28°C under N2; monitoring by (13)C-NMR and gas chromatography;A 15%
B n/a
C 85%
With carbon monoxide In dichloromethane-d2 introducing a soln. of Fe-complex in CH2Cl2 into an autoclave thermostated at 34°C, stirring for 2.5 h under CO pressure; monitoring by (13)C-NMR and gas chromatography, cooling, removal of solvent under vacuum, redissolution in CD2Cl2, monitoring by (13)C-NMR;
dicarbonyl{O-4-η-((E)-4-phenylbut-3-en-2-one)}(triphenylphosphine)iron

dicarbonyl{O-4-η-((E)-4-phenylbut-3-en-2-one)}(triphenylphosphine)iron

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

tetracarbonyl(triphenylphosphine)iron
35679-07-3, 14649-69-5

tetracarbonyl(triphenylphosphine)iron

tricarbonyl(benzylideneacetone)iron

tricarbonyl(benzylideneacetone)iron

Conditions
ConditionsYield
With carbon monoxide In Petroleum ether thermal decompn. in petroleum ether at 70°C under 1 atm of CO; analyzed by IR;A 0%
B 0%
C 80%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

hexaborane(10)

hexaborane(10)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

-.u.-Fe(CO)B6H10

-.u.-Fe(CO)B6H10

Conditions
ConditionsYield
A n/a
B 77%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

Mo(CC6H4OCH3-2)(CO)2(η5-C5H5)

Mo(CC6H4OCH3-2)(CO)2(η5-C5H5)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

C

MoFe(μ-CC6H4OMe-2)(CO)6(η-C5H5)

MoFe(μ-CC6H4OMe-2)(CO)6(η-C5H5)

Conditions
ConditionsYield
In diethyl ether N2, stirring for 4 h at ambient temp.; evapd., dissolved in CH2Cl2/light petroleum 1/5, chromd. (Kieselgel, water-cooled, CH2Cl2/light petroleum 1/5, then 1/1), evapd., recrystd. from light petroleum at -78°C, elem. anal.;A n/a
B n/a
C 76%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

selenium

selenium

Mo(C(C6H3Me2-2,6))(CO)2(η-C5H5)

Mo(C(C6H3Me2-2,6))(CO)2(η-C5H5)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

MoFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

MoFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

Conditions
ConditionsYield
In diethyl ether N2 atmosphere; stirring suspn. of W-copmd. and Fe-compd. in Et2O (15 h), removal of Fe(CO)5, addn. of Se and Et2O, stirring (15 h); removal of volatiles (vac.), extn. (CH2Cl2 and petroleum ether), chromy. (Kieselgel, CH2Cl2/petroleum ether), concn. (vac.), cooling (-78°C); elem. anal.;A n/a
B 76%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

μ3-arsenic-hexacarbonyltris(η5-cyclopentadienyl)trimolybdenum (3 Mo-Mo)
93923-00-3

μ3-arsenic-hexacarbonyltris(η5-cyclopentadienyl)trimolybdenum (3 Mo-Mo)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

cyclopentadienylmolybdenum tricarbonyl dimer

cyclopentadienylmolybdenum tricarbonyl dimer

C

μ4-arsenic-μ-carbonyl-diμ(Fe, Mo)-carbonyl-dicarbonylbis(η5-cyclopentadienyl)(dicarbonyliron){tricarbonyl(η5-cyclopentadienyl)molybdenum}dimolybdenum (2 Fe-Mo, Mo-Mo)
111769-94-9

μ4-arsenic-μ-carbonyl-diμ(Fe, Mo)-carbonyl-dicarbonylbis(η5-cyclopentadienyl)(dicarbonyliron){tricarbonyl(η5-cyclopentadienyl)molybdenum}dimolybdenum (2 Fe-Mo, Mo-Mo)

Conditions
ConditionsYield
In toluene refluxing for 1.5 h; solvent and Fe(CO)5 removed in vac., residue dissolved in toluene; chromy. (silica gel) with hexane/toluene (1:1) yields Cp2Mo2(CO)6, then with toluene PhMe(MoCp(CO)2)2(AsMoCp(CO)3)Fe(CO)5 which is crystd. from CH2Cl2/hexane at -18°C; elem. anal.;A n/a
B n/a
C 75%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

selenium

selenium

Cr(C(C6H3Me2-2,6))(CO)2(η-C5H5)

Cr(C(C6H3Me2-2,6))(CO)2(η-C5H5)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

CrFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

CrFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

Conditions
ConditionsYield
In diethyl ether N2 atmosphere; stirring suspn. of W-copmd. and Fe-compd. in Et2O (15 h), removal of Fe(CO)5, addn. of Se and Et2O, stirring (15 h); removal of volatiles (vac.), extn. (CH2Cl2 and petroleum ether), chromy. (Kieselgel, CH2Cl2/petroleum ether), concn. (vac.), cooling (-78°C);A n/a
B 75%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

selenium

selenium

{W(CC6H3Me2-2,6)(CO)2(η5-C5H5)

{W(CC6H3Me2-2,6)(CO)2(η5-C5H5)

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

WFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

WFe(μ-η2-SeCC6H3Me2-2,6)(CO)5(η5-C5H5)

Conditions
ConditionsYield
In diethyl ether N2 atmosphere; stirring suspn. of W-copmd. and Fe-compd. in Et2O (15 h), removal of Fe(CO)5, addn. of Se and Et2O, stirring (15 h); removal of volatiles (vac.), extn. (CH2Cl2 and petroleum ether), chromy. (Kieselgel, CH2Cl2/petroleum ether), concn. (vac.), cooling (-78°C); elem. anal.;A n/a
B 74%
bis(μ,η2-decanoyl)hexacarbonyldiiron

bis(μ,η2-decanoyl)hexacarbonyldiiron

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

10-Nonadecanon
504-57-4

10-Nonadecanon

Conditions
ConditionsYield
With methyl iodide In cyclohexane byproducts: n-nonyl iodide, n-decane, CH3COC9H19; (N2); added n-tridecane, methyl iodide and cyclohexane to Fe-complex; stirred at room temp. for 3 h; cooled to -78°C; IR, GLPC, HPLC;A 46%
B 73%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

(trifluoroethenyl)ferrocene

(trifluoroethenyl)ferrocene

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

[Fe(CO)4(η2-trifluorovinylferrocene)]

[Fe(CO)4(η2-trifluorovinylferrocene)]

Conditions
ConditionsYield
In dichloromethane at 20℃; for 8h; Inert atmosphere; Schlenk technique;A n/a
B 72%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

1,1,2-Trimethyl-1-silacyclobutane
30681-90-4

1,1,2-Trimethyl-1-silacyclobutane

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

C

2,2,2,2-tetracarbonyl-1,1,5-trimethyl-1-sila-2-ferracyclopentane
60104-88-3

2,2,2,2-tetracarbonyl-1,1,5-trimethyl-1-sila-2-ferracyclopentane

Conditions
ConditionsYield
In benzene N2-atmosphere; slight excess of Si-compd., stirring (21°C, 24 h); evapn. (vac., cooling to just above freezing), dissoln. in hexane, standing at -30°C for several d, filtration off of Fe3(CO)12 (-30°C), evapn. of filtrate (low temp., vac.), distn. (0.001 Torr, probe at 0°C); elem. anal.;A n/a
B n/a
C 71%
Dichlorophenylphosphine
644-97-3

Dichlorophenylphosphine

diiron nonacarbonyl

diiron nonacarbonyl

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

[Fe(CO)4(PPhCl2)]
85539-24-8

[Fe(CO)4(PPhCl2)]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 16h; Schlenk technique; Darkness; Inert atmosphere;A n/a
B 71%
cis-(ethyloxalyl)(ethoxycarbonyl)tetracarbonyliron

cis-(ethyloxalyl)(ethoxycarbonyl)tetracarbonyliron

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

bis(ethoxycarbonyl)tetracarbonyliron

bis(ethoxycarbonyl)tetracarbonyliron

C

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

Conditions
ConditionsYield
In dichloromethane-d2 byproducts: CO; introducing a soln. of Fe-complex in CD2Cl2 into NMR tube, maintaining temp. at 28°C under N2; monitoring by (13)C-NMR and gas chromatography;A n/a
B 70%
C 30%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

Methyl-bis-dimethylarsino-amin
50964-61-9

Methyl-bis-dimethylarsino-amin

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

bis(dimethylarsino)methylaminoirontetracarbonyl
101482-34-2

bis(dimethylarsino)methylaminoirontetracarbonyl

Conditions
ConditionsYield
In diethyl ether (N2); arsenic-compd. in 40% excess; react. at 25°C for 16 h;; filtn., solvent is removed, destillation, elem. anal.;;A n/a
B 69%
3,4-bis(2',2,'6',6'-tetramethylpiperidino)-1,2-diphospha-3,4-dibora[1.1.0]bicyclobutane
122501-48-8

3,4-bis(2',2,'6',6'-tetramethylpiperidino)-1,2-diphospha-3,4-dibora[1.1.0]bicyclobutane

diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

B

2,4-bis(2',2',6',6'-tetramethylpiperidino)-1,3,2,4-diphosphadiborabicyclo{1.1.0}-butan-bis(tetracarbonyleisen)
122575-20-6

2,4-bis(2',2',6',6'-tetramethylpiperidino)-1,3,2,4-diphosphadiborabicyclo{1.1.0}-butan-bis(tetracarbonyleisen)

Conditions
ConditionsYield
In toluene stirring at room temp. under N2 for 1 day; evapn. (vac.) and recrystn. from Et2O; elem. anal.;A n/a
B 68%
diiron nonacarbonyl
15321-51-4

diiron nonacarbonyl

1,3,5-triphenylpent-2-en-1,5-dione
23800-57-9

1,3,5-triphenylpent-2-en-1,5-dione

iron pentacarbonyl
13463-40-6

iron pentacarbonyl

C6H5COCH2C(C6H5)CHC(C6H5)OFe(CO)3

C6H5COCH2C(C6H5)CHC(C6H5)OFe(CO)3

Conditions
ConditionsYield
In benzene at 15-25 °C,for 4-20 h;A n/a
B 65%
In toluene at 15-25 °C,for 4-20 h;A n/a
B 65%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

tetraethylammonium chloride
56-34-8

tetraethylammonium chloride

Fe5RhC(CO)16(1-)*(C2H5)4N(1+)={Fe5RhC(CO)16}((C2H5)4N)

Fe5RhC(CO)16(1-)*(C2H5)4N(1+)={Fe5RhC(CO)16}((C2H5)4N)

Conditions
ConditionsYield
With sodium amalgam In diethylene glycol Ar, soln. of Fe(CO)5 treated with Na#Hg, Fe(CO)5 added, stirred and heated to 150-160°C, continued for 3-4 h at 130-140°C, cooledto about 20°C, Rh-compound added, stirred for 30-40 min, filtered, 3-fold excess hexane added; decanted; ppt. washed (hexane); extd. (water); Et4NCl in H2O added; pptfiltered; washed (water); dried (vac., 20°C); recrystd. (CH2Cl2); elem. anal.;100%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

iron(III) oxide

iron(III) oxide

Conditions
ConditionsYield
In water Kinetics; Irradiation (UV/VIS); React. occurs at room temp.;99%
In water; acetone Kinetics; Irradiation (UV/VIS); React. occurs at room temp.;99%
In further solvent(s) Kinetics; Irradiation (UV/VIS); React. occurs at room temp. in perfluorodecaline or perfluoropolyether.;99%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

triphenyl-arsane
603-32-7

triphenyl-arsane

Fe(CO)4(As(C6H5)3)
14375-84-9, 35644-25-8

Fe(CO)4(As(C6H5)3)

Conditions
ConditionsYield
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 0.5 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;99%
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;94%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 3 h; evapd. in vac., chromd., recrystd.;88%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

triphenylphosphine
603-35-0

triphenylphosphine

tetracarbonyl(triphenylphosphine)iron
35679-07-3, 14649-69-5

tetracarbonyl(triphenylphosphine)iron

Conditions
ConditionsYield
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 0.5 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;99%
CoBr2*3H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1.25 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;98%
cobalt(II) chloride dihydrate In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 2 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;83%
With trimethylamine-N-oxide In ethanol; hexane Kinetics; byproducts: CO2, (CH3)3N; mixing of a soln. of (CH3)3NO in C2H5OH and a soln. of PPh3 in n-C6H14 (at least 10 fold excess) with a soln. of Ru(CO)5 in n-C6H14 (compn. of mixed solvent: 1/2(v/v) C2H5OH/n-hexane) at different temp. in the range 11.3-33.9°C, vigorous shaking; detn. by IR;
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

(cyclohexa-1,3-diene)iron tricarbonyl
12152-72-6

(cyclohexa-1,3-diene)iron tricarbonyl

Conditions
ConditionsYield
With catalyst: PhCH=CH-CH=N-C6H4(OMe-4) In 1,4-dioxane Ar-atmosphere; refluxing soln. of Fe-complex, catalyst and cyclohexadiene (excess) for 45 h; evapn., chromy. (SiO2, pentane);99%
With catalyst: PhCH=CH-CH=N-C6H4(OMe-4) In 1,4-dioxane Ar-atmosphere; refluxing soln. of Fe-complex, catalyst and cyclohexadiene (excess) for 45 h, addn. of new portion of catalyst and diene, refluxing for 24 h; evapn., dissoln. (pentane), filtration (Celite), evapn.;89%
In hexane Irradiation (UV/VIS); Ar atmosphere;77%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

2,7,12,17-tetra-n-propylporphycene

2,7,12,17-tetra-n-propylporphycene

μ-oxodi[iron(III)(2,7,12,17-tetra-n-propylporphycenato)]

μ-oxodi[iron(III)(2,7,12,17-tetra-n-propylporphycenato)]

Conditions
ConditionsYield
With iodine In toluene Fe(CO)5 soln. added to ligand soln., I2 added, refluxed for 5 h; cooled, filtered, evapd.; solid residue after filtration extd. (CHCl3) mixed with previously obtained solid, soln. stirred with aq. NaOH for 4 h, org. layer evapd., dissolved in CH2Cl2, chromd. (Al2O3, hexane/CH2Cl2, CH2Cl2);99%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

(CH3)2PCH2CH2(CH3)SiCH2CH2Si(CH3)CH2CH2P(CH3)2
344310-48-1

(CH3)2PCH2CH2(CH3)SiCH2CH2Si(CH3)CH2CH2P(CH3)2

(CH3)2PCH2CH2(CH3)SiCH2CH2Si(CH3)CH2CH2P(CH3)2[Fe(CO)4]2
84180-96-1

(CH3)2PCH2CH2(CH3)SiCH2CH2Si(CH3)CH2CH2P(CH3)2[Fe(CO)4]2

Conditions
ConditionsYield
In neat (no solvent) byproducts: CO; (N2 or vac.); 5 h; 150°C; dissolving in benzene; removal of insol. compounds; removal of solvent in vac.; elem. anal.;99%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

((CH3)2PCH2CH2)(C6H5)SiCH2CH2Si(C6H5)(CH2CH2P(CH3)2)
345652-78-0

((CH3)2PCH2CH2)(C6H5)SiCH2CH2Si(C6H5)(CH2CH2P(CH3)2)

A

(CH3)2PCH2CH2(C6H5)SiCH2CH2Si(C6H5)CH2CH2P(CH3)2[Fe(CO)4]2
84180-98-3

(CH3)2PCH2CH2(C6H5)SiCH2CH2Si(C6H5)CH2CH2P(CH3)2[Fe(CO)4]2

B

Fe*2(CH3)2PC2H4(C6H5)SiC2H4Si(C6H5)C2H4P(CH3)2*3CO = ((CH3)2PCH2CH2(C6H5)SiCH2CH2Si(C6H5)CH2CH2P(CH3)2)2Fe(CO)3

Fe*2(CH3)2PC2H4(C6H5)SiC2H4Si(C6H5)C2H4P(CH3)2*3CO = ((CH3)2PCH2CH2(C6H5)SiCH2CH2Si(C6H5)CH2CH2P(CH3)2)2Fe(CO)3

Conditions
ConditionsYield
In neat (no solvent) byproducts: CO; (N2 or vac.); 5 h; 150°C; dissolving in benzene; removal of insol. compounds; removal of solvent in vac.; elem. anal.;A 99%
B n/a
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

2,7,12,17-tetra-n-propylporphycene-d4

2,7,12,17-tetra-n-propylporphycene-d4

(μ-oxo)diiron(III) 2,7,12,17-tetra-n-propylporphycene-d4

(μ-oxo)diiron(III) 2,7,12,17-tetra-n-propylporphycene-d4

Conditions
ConditionsYield
With iodine In toluene Fe(CO)5 soln. added to ligand soln., I2 added, refluxed for 5 h; cooled, filtered, evapd.; solid residue after filtration extd. (CHCl3) mixed with previously obtained solid, soln. stirred with aq. NaOH for 4 h, org. layer evapd., dissolved in CH2Cl2, chromd. (Al2O3, hexane/CH2Cl2, CH2Cl2);99%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

(SeSi(C(CH3)3)3)2
852716-21-3

(SeSi(C(CH3)3)3)2

[Fe(CO)3(μ-SeSi(t-Bu)3)]2

[Fe(CO)3(μ-SeSi(t-Bu)3)]2

Conditions
ConditionsYield
In benzene-d6 Irradiation (UV/VIS); dry N2 or Ar; soln. of disulfide and Fe compd. (1:2 molar ratio) irradiated for 14 d, NMR control; crystd. on slow evapn., elem. anal.;99%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

1,8-bis(3,4,5-trimethoxybenzene)octa-1,7-diyne

1,8-bis(3,4,5-trimethoxybenzene)octa-1,7-diyne

C30H30FeO10

C30H30FeO10

Conditions
ConditionsYield
In toluene at 130℃; Sonogashira Cross-Coupling; Sealed tube;98.2%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

tetracarbonyl(triphenylphosphine)iron
35679-07-3, 14649-69-5

tetracarbonyl(triphenylphosphine)iron

Conditions
ConditionsYield
With triphenylphosphine; tetrakis(triphenylphosphine)platinum In benzene byproducts: CO; under N2, refluxing soln. of metal carbonyl, org. compd. and Pt(PPh3)4 in benzene (molar ratio metal carbonyl/org. compd./Pt(PPh3)4 1:2:0.1, 5 h), cooling (room temp.); removal of solvent (vac.), dissoln. (CH2Cl2), chromy. (silica gel, CH2Cl2/hexane 1:1), recrystn. (CH2Cl2/hexane);98%
With triphenylphosphine; pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;97%
With triphenylphosphine; palladium(II) oxide In toluene byproducts: CO; 10 h, toluene under reflux, PdO catalyst;; not sepd., detected by IR-spectra;;96%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

tributylphosphine
998-40-3

tributylphosphine

Fe(CO)4PBu3
18474-82-3

Fe(CO)4PBu3

Conditions
ConditionsYield
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 2.0 h; evapd. in vac., chromd., recrystd.;98%
cyclopentadienyl iron(II) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.0 h; evapd. in vac., chromd., recrystd.;98%
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;93%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

diphenyl(methyl)phosphine
1486-28-8

diphenyl(methyl)phosphine

Conditions
ConditionsYield
cyclopentadienyl iron(II) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.75 h; evapd. in vac., chromd., recrystd.;98%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;98%
cobalt(II) chloride dihydrate In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;98%
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;96%
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1.5 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;78%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

ortho-phenylenebis(dimethylarsine)
13246-32-7

ortho-phenylenebis(dimethylarsine)

A

C6H4(As(CH3)2)2Fe(CO)4
56760-75-9

C6H4(As(CH3)2)2Fe(CO)4

B

(CO)3Fe{(CH3)2AsC6H4As(CH3)2}
15308-59-5, 56760-75-9

(CO)3Fe{(CH3)2AsC6H4As(CH3)2}

Conditions
ConditionsYield
In neat (no solvent) tube was charged with ligand and Fe(CO)5, degassed and sealed under vac. (0.1 mmHg), tube was wrapped in foil and heated in an oil bath at 180°C for 7 h under N2, allowed to stand overnight at room temp., tube was frozen in liq. N2; solid residue was crushed, washed with ether under N2, taken up in CH2Cl2, soln. was filtered under N2, solvent was removed, chromd. under N2 on Florisil, eluted with benzene/hexane;A n/a
B 98%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

tris(1,2-naphthoquinone-1-oximato)iron(III)

tris(1,2-naphthoquinone-1-oximato)iron(III)

bis(1,2-naphthoquinone-2-oximato)iron(II)

bis(1,2-naphthoquinone-2-oximato)iron(II)

Conditions
ConditionsYield
In tetrahydrofuran Fe(CO)5 and tris(1,2-quinone mono-oximato)iron(III) heated under reflux in dry THF under nitrogen for 24 h; product filtered off, washed with THF and dried at 100°C/0.1 mmHg; elem. anal.;98%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

tris(5-methoxybenzo-1-quinone-2-oximato)iron(III)

tris(5-methoxybenzo-1-quinone-2-oximato)iron(III)

bis(5-metoxy-1,2-quinone-2-oximato)iron(II)

bis(5-metoxy-1,2-quinone-2-oximato)iron(II)

Conditions
ConditionsYield
In tetrahydrofuran Fe(CO)5 and tris(1,2-quinone mono-oximato)iron(III) heated under reflux in dry THF under nitrogen for 24 h; product filtered off, washed with THF and dried at 100°C/0.1 mmHg; elem. anal.;98%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

1,2,3-trimethylbicyclo<10.3.0>pentadecadiene

1,2,3-trimethylbicyclo<10.3.0>pentadecadiene

{(C12H20C3(CH3)3)Fe(CO)2}2

{(C12H20C3(CH3)3)Fe(CO)2}2

Conditions
ConditionsYield
In toluene (N2); reflux of mixt. for 3 days (125°C); filtn., residue is washed with toluene and cooled down to -30°C, soln. is decanted, crystals are washed with hexane, elem. anal.;98%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

dimethylphenylarsine
696-26-4

dimethylphenylarsine

Fe(CO)4(As(C6H5)(CH3)2)
83653-44-5

Fe(CO)4(As(C6H5)(CH3)2)

Conditions
ConditionsYield
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;98%
cyclopentadienyl iron(II) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 2.5 h; evapd. in vac., chromd., recrystd.;97%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 2.25 h; evapd. in vac., chromd., recrystd.;95%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

((CH3)2PCH2CH2)2SiCH2CH2CH2
84114-40-9

((CH3)2PCH2CH2)2SiCH2CH2CH2

[Fe(CO)4]2((CH3)2PCH2CH2)2SiCH2CH2CH2
84206-91-7

[Fe(CO)4]2((CH3)2PCH2CH2)2SiCH2CH2CH2

Conditions
ConditionsYield
In neat (no solvent) byproducts: CO; (N2 or vac.); 5 h; 140°C; dissolving in benzene; removal of insol. compounds; removal of solvent in vac.; elem. anal.;98%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

Ga(AmIm)

Ga(AmIm)

Fe(CO)4{Ga(AmIm)}

Fe(CO)4{Ga(AmIm)}

Conditions
ConditionsYield
In toluene at 25℃; for 18h; Inert atmosphere;98%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

C58H72FeN4O4Si2

C58H72FeN4O4Si2

C61H72Fe2N4O7Si2

C61H72Fe2N4O7Si2

Conditions
ConditionsYield
Stage #1: C58H72FeN4O4Si2 In toluene at 20℃; for 0.166667h; Schlenk technique; Inert atmosphere;
Stage #2: iron pentacarbonyl In toluene at 20 - 100℃; Schlenk technique; Inert atmosphere;
97.1%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

triphenylantimony
603-36-1

triphenylantimony

Fe(CO)4(Sb(C6H5)3)
20516-78-3, 35917-16-9

Fe(CO)4(Sb(C6H5)3)

Conditions
ConditionsYield
pentamethylcyclopentadienyliron(III) dicarbonyl dimer In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 1.25 h; evapd. in vac., chromd., recrystd.;97%
cobalt(II)-iodide * 4 H2O In toluene ligand and catalyst added to toluene, stirred soln. brought to reflux, Fe(CO)5 added to this soln., reflux continued for 1 h under N2; catalyst and excess ligand removed by chromy., solvent and excess Fe(CO)5 removed by evapn.;97%
[(η(5)-C5H4Me)Fe(CO)2]2 In toluene to boiling soln. of Fe(CO)5 and catalyst added ligand, heated for 2.0 h; evapd. in vac., chromd., recrystd.;96%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

N-chlorobistrifluoromethylamine
431-94-7

N-chlorobistrifluoromethylamine

Perfluoro-2-azapropen
371-71-1

Perfluoro-2-azapropen

Conditions
ConditionsYield
0°C;97%
0°C;97%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

N-bromobis(trifluoromethyl)amine
758-43-0

N-bromobis(trifluoromethyl)amine

Perfluoro-2-azapropen
371-71-1

Perfluoro-2-azapropen

Conditions
ConditionsYield
0°C;97%
0°C;97%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole
118734-49-9

4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole

A

tricarbonyl(η4-4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole)iron
118772-37-5

tricarbonyl(η4-4,5-diethyl-2,5-dihydro-3-isopropenyl-2,2-dimethyl-1,2,5-selenasilaborole)iron

B

carbon monoxide
201230-82-2

carbon monoxide

Conditions
ConditionsYield
In tetrahydrofuran Irradiation (UV/VIS); Ar atmosphere, photolysis (125-W medium-pressure Hg lamp, 4.5 h); solvent removal (12 Torr), dissoln. (pentane), filtn., evapn., sublimation (70-80°C, 0.001 Torr); elem. anal.;A 73%
B 97%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

tris(1,2-naphthoquinone-2-oximato)iron(III)

tris(1,2-naphthoquinone-2-oximato)iron(III)

bis(1,2-naphthoquinone-1-oximato)iron(II)

bis(1,2-naphthoquinone-1-oximato)iron(II)

Conditions
ConditionsYield
In tetrahydrofuran Fe(CO)5 and tris(1,2-quinone mono-oximato)iron(III) heated ander reflux in dry THF under nitrogen for 24 h; product filtered off, washed with THF and dried at 100°C/0.1 mmHg; elem. anal.;97%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

mercury (II) chloride
7487-94-7

mercury (II) chloride

(CO)5Fe*3HgCl2

(CO)5Fe*3HgCl2

Conditions
ConditionsYield
In pentane under dry nitrogen; stirred 6 h at 0°C; washed with cold pentane, dried in a steam of N2; elem. anal.;97%

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