1059698-88-2

Basic information

• Product Name: 2'-benzylidene-2-acetylpyridine N-oxide
• Synonyms: 2'-benzylidene-2-acetylpyridine N-oxide
• CAS NO: 1059698-88-2
• Molecular Weight: 225.247
• Mol File: 1059698-88-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2'-benzylidene-2-acetylpyridine N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 2'-benzylidene-2-acetylpyridine N-oxide(1059698-88-2)
• EPA Substance Registry System: 2'-benzylidene-2-acetylpyridine N-oxide(1059698-88-2)

Safety Data

• Hazardous Substances Data: 1059698-88-2(Hazardous Substances Data)

Upstream product

• 7216-40-2 2-pyridinecarboxaldehyde N-oxide 
• 536-74-3 phenylacetylene 
• 2457-50-3 2-acetylpyridine N-oxide 
• 100-52-7 benzaldehyde 
• 1122-62-9 2-acetylpyridine 

Downstream Products

• 1059698-67-7 (R)-2-(3-(1H-indol-3-yl)-3-phenylpropanoyl)pyridine 1-oxide 
• 1059698-73-5 (R)-2-(3-(1-methyl-1H-indol-3-yl)-3-phenylpropanoyl)pyridine-1-oxide 
• 1059698-68-8 (R)-2-(3-(5-fluoro-1H-indol-3-yl)-3-phenylpropanoyl)pyridine 1-oxide 
• 1059698-70-2 (R)-2-(3-(5-bromo-1H-indol-3-yl)-3-phenylpropanoyl)pyridine 1-oxide 
• 1059698-71-3 (R)-2-(3-(5-methoxy-1H-indol-3-yl)-3-phenylpropanoyl)pyridine 1-oxide 
• 1059698-72-4 C₂₃H₁₇N₃O₂ 
• 1059698-74-6 C₂₉H₂₄N₂O₂ 
• 1059698-69-9 (R)-2-(3-(5-chloro-1H-indol-3-yl)-3-phenylpropanoyl)pyridine 1-oxide 

Relevant articles and documents

Chiral bipyridine-annulated bicyclo[3.3.1]nonane N-oxide organocatalysts for stereoselective allylation and hydrosilylation reactions

The synthesis of chiral C2-symmetric bis(bipyridine N,N′-dioxide) and bis(bipyridine N-monooxide) derivatives featuring bipyridine-annulated bicyclo[3.3.1]nonane framework is reported. The new Lewis basic bipyridine N,N′-dioxides exhibited good

Highly Diastereo- and Enantioselective Michael Addition of Nitroalkanes to 2-Enoyl-Pyridine N-Oxides Catalyzed by Scandium(III)/Copper(II) Complexes

A C2-symmetric Schiff-base ligand, derived from tridentate-Schiff-base, was developed and successfully applied to the asymmetric Michael addition of nitroalkanes to 2-enoyl-pyridine N-oxides. With this newly catalytic system, an unprecedented diastereoselectivity was obtained in the asymmetric Michael addition of nitroalkanes to 2-enoyl-pyridine N-oxides. In addition, a switch in enantioselectivity was achieved by using this newly catalytic system and our previous catalyst. After a facile reduction, the optically active adduct was converted to a biologically active dihydro-2H-pyrrol 4a. Furthermore, a connection of two tridentate-Schiff-base subunits proved to be an effective strategy in ligand design. Complex chemistry! A C2-symmetric Schiff-base ligand, derived from tridentate-Schiff-base, was developed and successfully applied to the asymmetric Michael addition of nitroalkanes to 2-enoyl-pyridine N-oxides with unprecedented diastereoselectivity (see scheme).

Highly enantioselective Friedel-Crafts reaction of indoles with 2-enoylpyridine 1-oxides catalyzed by chiral pyridine 2,6-bis(5′,5′- diphenyloxazoline)-Cu(II) complexes

(Chemical Equation Presented) The catalytic enantioselective Friedel-Crafts reaction of indoles with 2-enoylpyridine 1-oxides has been studied in the presence of chiral pyridine 2,6-bis(5′,5′-diphenyloxazoline)-Cu(II) complexes. The reaction furnished alk