105976-34-9Relevant academic research and scientific papers
Planar chiral dialkoxysilane: Introduction of inherent chirality and high reactivity in conventional achiral alkene
Tomooka, Katsuhiko,Miyasaka, Shouji,Motomura, Shougo,Igawa, Kazunobu
supporting information, p. 7598 - 7602 (2014/07/07)
A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).
Rhenium-catalyzed synthesis of naphthalene derivatives via insertion of aldehydes into a C-H bond
Kuninobu, Yoichiro,Nishina, Yuta,Takai, Kazuhiko
, p. 8463 - 8468 (2008/02/09)
A rhenium complex, [ReBr(CO)3(THF)]2, catalyzed reactions of aromatic ketimines and aldehydes with dienophiles, followed by dehydration, to give naphthalene derivatives in good to excellent yields. This reaction proceeds via C-H bond activation, insertion of an aldehyde, intramolecular nucleophilic cyclization, reductive elimination, elimination of aniline and Diels-Alder reaction. After dehydration, naphthalene derivatives were formed.
