105995-06-0Relevant academic research and scientific papers
ON THE ROLE OF THE CF3 GROUP IN DETERMINING THE RELATIVE STABILITY OF E, Z-ISOMERS
Bumgardner, Carl L.,Bunch, John E.,Whangbo, M.-H.
, p. 1883 - 1886 (1986)
Although base-catalyzed addition of PhSH to PhCCCF3 under thermodynamic control gives E-Ph(PhS)C=CH(CF3), Z-Ph(PhO)C=CH(CF3) is the thermodynamically favored product from similar reaction of PhOH with PhCCCF3.The preference for the cis-configuration
