Tetrahedron Letters p. 1883 - 1886 (1986)
Update date:2022-08-04
Topics:
Bumgardner, Carl L.
Bunch, John E.
Whangbo, M.-H.
Although base-catalyzed addition of PhSH to PhC<*>CCF3 under thermodynamic control gives E-Ph(PhS)C=CH(CF3), Z-Ph(PhO)C=CH(CF3) is the thermodynamically favored product from similar reaction of PhOH with PhC<*>CCF3.The preference for the cis-configuration
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